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Ether (cas 60-29-7) Molecular Structure

Ether(CAS No. 60-29-7)

  • Molecular Formula: C4H10O
  • Molecular Weight:

Identification of 60-29-7

  • Name:Ether
  • EINECS:200-467-2
  • Molecular Formula:C4H10O
  • CAS Registry Number:60-29-7
  • Synonyms: 1,1'-Oxybisethane; Diethyl ether; DIETHYL ETHER (ETHYL ETHER); Diethyl Oxide; Ethoxyethane; Ethyl ether; Ethyl Ether? ethyl oxide; pronarcol;
  • Molecular Structure:Ether C4H10O (cas 60-29-7) Molecular Structure

Chemical Properties

  • Density:0.714
  • Water solubility:69 g/L (20 ºC)
  • Boiling Point:34.6℃
  • Melting Point:-116℃
  • Flash Point:-45℃
  • Refractive index:1.351-1.353
  • Solubility:69 g/L (20 oC)
  • Appearance:colourless liquid

Safety Data of 60-29-7

Material Safety Data Sheet(MSDS)

MSDS Documents
Sources
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1.Sigma-Aldrich
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2.Science Lab
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3.J.T.Baker
www.jtbaker.com/msds/englishhtml/e2340.htm
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References of Ether

Toxicity

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
dog LCLo inhalation 76000ppm (76000ppm) ? "Abdernalden's Handbuch der Biologischen Arbeitsmethoden." Vol. 4, Pg. 1294, 1935.
frog LDLo subcutaneous 24gm/kg (24000mg/kg) ? "Abdernalden's Handbuch der Biologischen Arbeitsmethoden." Vol. 4, Pg. 1295, 1935.
guinea pig LDLo intraperitoneal 2gm/kg (2000mg/kg) ? American Industrial Hygiene Association Journal. Vol. 35, Pg. 21, 1974.
human TCLo inhalation 200ppm (200ppm) SENSE ORGANS AND SPECIAL SENSES: OTHER CHANGES: OLFACTION Journal of Industrial Hygiene and Toxicology. Vol. 25, Pg. 282, 1943.
man LDLo oral 260mg/kg (260mg/kg) ? "Poisoning; Toxicology, Symptoms, Treatments," 2nd ed., Arena, J.M., Springfield, IL, C.C. Thomas, 1970Vol. 2, Pg. 73, 1970.
mouse LC50 inhalation 31000ppm/30M (31000ppm) BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD Experimental Animals. Jikken Dobutso Iho. Vol. 34, Pg. 379, 1985.
mouse LD50 intraperitoneal 2420mg/kg (2420mg/kg) ? Proceedings of the Western Pharmacology Society. Vol. 27, Pg. 511, 1984.
mouse LD50 intravenous 996mg/kg (996mg/kg) ? Journal of Pharmaceutical Sciences. Vol. 67, Pg. 566, 1978.
mouse LDLo subcutaneous 8mg/kg (8mg/kg) ? "Abdernalden's Handbuch der Biologischen Arbeitsmethoden." Vol. 4, Pg. 1295, 1935.
rabbit LCLo inhalation 106000ppm (106000ppm) ? "Abdernalden's Handbuch der Biologischen Arbeitsmethoden." Vol. 4, Pg. 1294, 1935.
rabbit LD50 skin > 20mL/kg (20mL/kg) ? American Industrial Hygiene Association Journal. Vol. 23, Pg. 95, 1962.
rat LCLo inhalation 32000ppm/4H (32000ppm) ? American Industrial Hygiene Association Journal. Vol. 23, Pg. 95, 1962.
rat LD50 oral 1215mg/kg (1215mg/kg) ? Toxicology and Applied Pharmacology. Vol. 19, Pg. 699, 1971.

Safety

Hazard Codes of Ethyl ether (CAS NO.60-29-7):?F+,Xn,T
Risk Statements: 12-19-22-66-67-39-23/24/25?
R12: Extremely flammable.?
R19: May form explosive peroxides.?
R22: Harmful if swallowed.?
R66: Repeated exposure may cause skin dryness or cracking.?
R67: Vapours may cause drowsiness and dizziness.?
R39: Danger of very serious irreversible effects.?
R23/24/25: Toxic by inhalation, in contact with skin and if swallowed.
Safety Statements: 9-16-29-33-45-36/37?
S9: Keep container in a well-ventilated place.?
S16: Keep away from sources of ignition.?
S29: Do not empty into drains.?
S33: Take precautionary measures against static discharges.?
S45: In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)?
S36/37: Wear suitable protective clothing and gloves.
RIDADR: UN 1155 3/PG 1
WGK Germany: 1
RTECS: KI5775000
F: 10
HazardClass: 3
PackingGroup: I
Moderately toxic to humans by ingestion. Poison experimentally by subcutaneous route. Moderately toxic by intraperitoneal and intravenous routes. Mildly toxic by inhalation. Human systemic effects by inhalation: olfactory changes. Mutation data reported. A severe eye and moderate skin irritant. Ethyl ether is not corrosive or dangerously reactive. It must not be considered safe for individuals to inhale or ingest. It is a depressant of the central nervous system and is capable of producing intoxication, drowsiness, stupor, and unconsciousness. Death due to respiratory failure may result from severe and continued exposure.

?

A very dangerous fire and explosion hazard when exposed to heat or flame. A storage hazard. It auto-oxidizes to form explosive polymeric 1-oxy-peroxides. Explosive reaction with boron triazide, bromine trifluoride, bromine pentafluoride, perchloric acid, uranyl nitrate + light, wood pulp extracts + heat. Violent reaction or ignition on contact with halogens (e.g., bromine, chlorine), interhalogens (e.g., iodine heptafluoride), oxidants (e.g., silver perchlorate, nitrosyl perchlorate, nitryl perchlorate, chromyl chloride, fluorine nitrate, permanganic acid, nitric acid, hydrogen peroxide, peroxodisulfuric acid, iodine(VII) oxide, sodium peroxide, ozone, and liquid air), sulfur and sulfur compounds (e.g., sulfur when dried with peroxidized ether, sulfuryl chloride). Can react vigorously with acetyl peroxide, air, bromoazide, ClF3, CrO3, Cr(OCl)2, LiAlH2, NOClO4, O2, NClO2, (H2SO4 + permanganates), K2O2, [(C2H5)3Al + air], [(CH3)3Al + air]. To fight fire, use alcohol foam, CO2, dry chemical. Used in production of drugs of abuse. When heated to decomposition it emits acrid smoke and irritating fumes. See also ETHERS.