Formic acid (cas 64-18-6) Molecular Structure

CAS No. 64-18-6 (Formic acid )

Molecular Formula: CH2O2Molecular Formula: 46.02

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References of Formic acid cas 64-18-6

} Toxicity

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
dog LD50 oral 4gm/kg (4000mg/kg) ? AMA Archives of Industrial Health. Vol. 20, Pg. 517, 1959.
dog LDLo intravenous 3gm/kg (3000mg/kg) ? "Handbook of Toxicology," 4 vols., Philadelphia, W.B. Saunders Co., 1956-59Vol. 1, Pg. 146, 1955.
man TCLo inhalation 7300ug/m3/8H (7.3mg/m3) KIDNEY, URETER, AND BLADDER: OTHER CHANGES IN URINE COMPOSITION Archives of Toxicology. Vol. 66, Pg. 522, 1992.
mouse LC50 inhalation 6200mg/m3/15M (6200mg/m3) BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)

LUNGS, THORAX, OR RESPIRATION: DYSPNEA
Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 23(12), Pg. 49, 1979.
mouse LD50 intraperitoneal 940mg/kg (940mg/kg) ? Igiena. Vol. 11, Pg. 507, 1962.
mouse LD50 intravenous 145mg/kg (145mg/kg) ? Zeitschrift fuer Ernaehrungswissenschaft. Vol. 9, Pg. 332, 1969.
mouse LD50 oral 700mg/kg (700mg/kg) BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)

LUNGS, THORAX, OR RESPIRATION: DYSPNEA
Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 23(12), Pg. 49, 1979.
rabbit LDLo intravenous 239mg/kg (239mg/kg) ? "Handbook of Toxicology," 4 vols., Philadelphia, W.B. Saunders Co., 1956-59Vol. 1, Pg. 146, 1955.
rat LC50 inhalation 15gm/m3/15M (15000mg/m3) BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)

LUNGS, THORAX, OR RESPIRATION: DYSPNEA
Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 23(12), Pg. 49, 1979.
rat LD50 oral 1100mg/kg (1100mg/kg) BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)

LUNGS, THORAX, OR RESPIRATION: DYSPNEA
Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 23(12), Pg. 49, 1979.
women LDLo oral 2440ug/kg (2.44mg/kg) VASCULAR: SHOCK

BLOOD: OTHER HEMOLYSIS WITH OR WITHOUT ANEMIA
American Journal of Emergency Medicine. Vol. 7, Pg. 286, 1989.
women TDLo oral 2200mg/kg (2200mg/kg) LUNGS, THORAX, OR RESPIRATION: SPUTUM

KIDNEY, URETER, AND BLADDER: HEMATURIA
Journal of Toxicology, Clinical Toxicology. Vol. 32, Pg. 199, 1994.

Safety

?Poison by inhalation, intravenous, and intraperitoneal routes. Moderately toxic by ingestion. Mutation data reported. Corrosive. A skin and severe eye irritant. A substance migrating to food from packaging materials. Combustible liquid when exposed to heat or flame; can react vigorously with oxidizing materials. Explosive reaction with furfuryl alcohol, H2O2, Tl(NO3)3?3H2O, nitromethane, P2O5. To fight fire, use CO2, dry chemical, alcohol foam. When heated to decomposition it emits acrid smoke and irritating fumes.
Hazard Codes:?TC,Xi
Risk Statements: 23/24/25-34-40-43-35-36/38
R23/24/25: Toxic by inhalation, in contact with skin and if swallowed.?
R34: Causes burns.?
R40: Limited evidence of a carcinogenic effect.?
R43: May cause sensitization by skin contact.?
R35: Causes severe burns.?
R36/38: Irritating to eyes and skin.
Safety Statements: 36/37-45-26-23-36/37/39
S36/37: Wear suitable protective clothing and gloves.?
S45: In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)?
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.?
S23: Do not breathe vapour.?
S36/37/39: Wear suitable protective clothing, gloves and eye/face protection.
RIDADR: UN 1198 3/PG 3
WGK Germany: 2
RTECS: LP8925000
F: 10
HazardClass: 8
PackingGroup: II