Hexanoic acid,2-ethyl-, cobalt(2+) salt (2:1) (cas 136-52-7) MSDS

Download
Download
1.
1.1
IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
Product identifiers
Product name
Product Number
Brand
:
:
:
Cobalt(II) 2-ethylhexanoate solution
444545
1.2
Relevant identified uses of the substance or mixture and uses advised against
Identified uses
:
Laboratory chemicals, Manufacture of substances
2.
2.1
2.2
HAZARDS IDENTIFICATION
Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008 [EU-GHS/CLP]
Flammable liquids (Category 3)
Acute toxicity, Oral (Category 4)
Acute toxicity, Inhalation (Category 2)
Acute toxicity, Dermal (Category 4)
Skin irritation (Category 2)
Eye irritation (Category 2)
Reproductive toxicity (Category 2)
Specific target organ toxicity - single exposure (Category 3)
Classification according to EU Directives 67/548/EEC or 1999/45/EC
Flammable. Harmful by inhalation, in contact with skin and if swallowed. Possible risk of harm to the
unborn child. Irritating to eyes, respiratory system and skin.
Label elements
Labelling according Regulation (EC) No 1272/2008 [CLP]
Pictogram
Signal word
Hazard statement(s)
H226
H302
H312
H315
H319
Danger
Flammable liquid and vapour.
Harmful if swallowed.
Harmful in contact with skin.
Causes skin irritation.
Causes serious eye irritation.
H330
H335
H361
Precautionary statement(s)
P260
P280
P284
P305 + P351 + P338
P310
Supplemental Hazard
Fatal if inhaled.
May cause respiratory irritation.
Suspected of damaging fertility or the unborn child.
Do not breathe dust/ fume/ gas/ mist/ vapours/ spray.
Wear protective gloves/ protective clothing.
Wear respiratory protection.
IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
Immediately call a POISON CENTER or doctor/ physician.
none
Statements
According to European Directive 67/548/EEC as amended.
Hazard symbol(s)
R-phrase(s)
R10
R20/21/22
R36/37/38
R63
S-phrase(s)
S26
S36/37
Flammable.
Harmful by inhalation, in contact with skin and if swallowed.
Irritating to eyes, respiratory system and skin.
Possible risk of harm to the unborn child.
In case of contact with eyes, rinse immediately with plenty of water and
seek medical advice.
Wear suitable protective clothing and gloves.
2.3
3.
3.2
Other hazards - none
COMPOSITION/INFORMATION ON INGREDIENTS
Mixtures
Formula
Molecular Weight
:
:
C16H30CoO4
345,34 g/mol
Component
Cobalt(II) 2-ethylhexanoate
Classification
Concentration
CAS-No.
EC-No.
136-52-7
205-250-6
Acute Tox. 4; Acute Tox. 3;
Acute Tox. 4; Repr. 2; H302,
50 - 100 %
H312, H331, H361
Xn, R20/21/22 - R63
Alkanes, C10-13-iso-
CAS-No.
EC-No.
68551-17-7
271-366-9
Flam. Liq. 3; Skin Irrit. 2; Eye
Irrit. 2; STOT SE 3; H226,
25 - 50 %
H315, H319, H335
Xi, R36/37/38
For the full text of the H-Statements and R-Phrases mentioned in this Section, see Section 16
4.
4.1
FIRST AID MEASURES
Description of first aid measures
General advice
Consult a physician. Show this safety data sheet to the doctor in attendance.
If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
In case of skin contact
Wash off with soap and plenty of water. Take victim immediately to hospital. Consult a physician.
In case of eye contact
Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
If swallowed
Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with
water. Consult a physician.
4.2
4.3
5.
5.1
5.2
5.3
5.4
6.
6.1
6.2
6.3
6.4
7.
7.1
7.2
7.3
Most important symptoms and effects, both acute and delayed
Central nervous system depression, Headache, Dizziness, May cause irritation of the:, nose, Throat.,
sensation of heat, Exposure can cause damage to the:, Kidney, Lungs
Indication of any immediate medical attention and special treatment needed
no data available
FIREFIGHTING MEASURES
Extinguishing media
Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Special hazards arising from the substance or mixture
Carbon oxides, Cobalt/cobalt oxides
Advice for firefighters
Wear self contained breathing apparatus for fire fighting if necessary.
Further information
Use water spray to cool unopened containers.
ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Wear respiratory protection. Avoid breathing vapors, mist or gas. Ensure adequate ventilation. Remove
all sources of ignition. Evacuate personnel to safe areas. Beware of vapours accumulating to form
explosive concentrations. Vapours can accumulate in low areas.
Environmental precautions
Prevent further leakage or spillage if safe to do so. Do not let product enter drains.
Methods and materials for containment and cleaning up
Contain spillage, and then collect with an electrically protected vacuum cleaner or by wet-brushing and
place in container for disposal according to local regulations (see section 13).
Reference to other sections
For disposal see section 13.
HANDLING AND STORAGE
Precautions for safe handling
Avoid contact with skin and eyes. Avoid inhalation of vapour or mist.
Keep away from sources of ignition - No smoking.Take measures to prevent the build up of electrostatic
charge.
Conditions for safe storage, including any incompatibilities
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are
opened must be carefully resealed and kept upright to prevent leakage.
Specific end uses
no data available
8.
8.1
8.2
9.
9.1
EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters
Components with workplace control parameters
Exposure controls
Appropriate engineering controls
Avoid contact with skin, eyes and clothing. Wash hands before breaks and immediately after handling
the product.
Personal protective equipment
Eye/face protection
Face shield and safety glasses Use equipment for eye protection tested and approved under
appropriate government standards such as NIOSH (US) or EN 166(EU).
Skin protection
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique
(without touching glove's outer surface) to avoid skin contact with this product. Dispose of
contaminated gloves after use in accordance with applicable laws and good laboratory practices.
Wash and dry hands.
The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and
the standard EN 374 derived from it.
Body Protection
Complete suit protecting against chemicals, Flame retardant antistatic protective clothing, The type
of protective equipment must be selected according to the concentration and amount of the
dangerous substance at the specific workplace.
Respiratory protection
Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator
with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup
to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air
respirator. Use respirators and components tested and approved under appropriate government
standards such as NIOSH (US) or CEN (EU).
PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
a)
b)
c)
d)
e)
f)
g)
h)
Appearance
Odour
Odour Threshold
pH
Melting point/freezing
point
Initial boiling point and
boiling range
Flash point
Evaporation rate
Form: liquid
Colour: purple
no data available
no data available
no data available
no data available
179 - 210 °C at 1.013 hPa
40 °C - closed cup
no data available
i)
Flammability (solid, gas) no data available
j)
k)
l)
Upper/lower
flammability or
explosive limits
Vapour pressure
Vapour density
no data available
no data available
no data available
m) Relative density
0,978 - 1,037 g/cm3
n)
o)
p)
q)
r)
s)
t)
Water solubility
Partition coefficient: n-
octanol/water
Autoignition
temperature
Decomposition
temperature
Viscosity
Explosive properties
Oxidizing properties
no data available
no data available
no data available
no data available
no data available
no data available
no data available
9.2
10.
10.1
10.2
10.3
10.4
10.5
10.6
11.
11.1
Other safety information
no data available
STABILITY AND REACTIVITY
Reactivity
no data available
Chemical stability
no data available
Possibility of hazardous reactions
no data available
Conditions to avoid
Heat, flames and sparks.
Incompatible materials
Strong oxidizing agents
Hazardous decomposition products
Other decomposition products - no data available
TOXICOLOGICAL INFORMATION
Information on toxicological effects
Acute toxicity
no data available
Skin corrosion/irritation
no data available
Serious eye damage/eye irritation
no data available
Respiratory or skin sensitization
no data available
Germ cell mutagenicity
no data available
Carcinogenicity
IARC:
2B - Group 2B: Possibly carcinogenic to humans (Cobalt(II) 2-ethylhexanoate)
Reproductive toxicity
no data available
Specific target organ toxicity - single exposure
no data available
Specific target organ toxicity - repeated exposure
no data available
Aspiration hazard
no data available
Potential health effects
Inhalation
Ingestion
Skin
Eyes
May be fatal if inhaled. Causes respiratory tract irritation.
Harmful if swallowed.
Harmful if absorbed through skin. Causes skin irritation.
Causes serious eye irritation.
Signs and Symptoms of Exposure
Central nervous system depression, Headache, Dizziness, May cause irritation of the:, nose, Throat.,
sensation of heat, Exposure can cause damage to the:, Kidney, Lungs
Additional Information
RTECS: Not available
12.
12.1
12.2
12.3
12.4
12.5
12.6
13.
13.1
14.
14.1
ECOLOGICAL INFORMATION
Toxicity
no data available
Persistence and degradability
no data available
Bioaccumulative potential
no data available
Mobility in soil
no data available
Results of PBT and vPvB assessment
no data available
Other adverse effects
no data available
DISPOSAL CONSIDERATIONS
Waste treatment methods
Product
Burn in a chemical incinerator equipped with an afterburner and scrubber but exert extra care in igniting
as this material is highly flammable. Offer surplus and non-recyclable solutions to a licensed disposal
company.
Contaminated packaging
Dispose of as unused product.
TRANSPORT INFORMATION
UN number
14.2
ADR/RID: 1268
UN proper shipping name
IMDG: 1268
IATA: 1268
ADR/RID:
IMDG:
IATA:
PETROLEUM DISTILLATES, N.O.S.
PETROLEUM DISTILLATES, N.O.S.
Petroleum distillates, n.o.s.
14.3
Transport hazard class(es)
ADR/RID: 3
14.4
Packaging group
ADR/RID: III
14.5
Environmental hazards
ADR/RID: no
14.6
Special precautions for user
no data available
IMDG: 3
IMDG: III
IMDG Marine pollutant: no
IATA: 3
IATA: III
IATA: no
15.
15.1
15.2
16.
REGULATORY INFORMATION
This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.
Safety, health and environmental regulations/legislation specific for the substance or mixture
no data available
Chemical Safety Assessment
no data available
OTHER INFORMATION
Text of H-code(s) and R-phrase(s) mentioned in Section 3
Acute Tox.
Eye Irrit.
Flam. Liq.
H226
H302
H312
H315
H319
H331
H335
H361
Repr.
Skin Irrit.
STOT SE
Xi
R20/21/22
R36/37/38
R63
Xn
Acute toxicity
Eye irritation
Flammable liquids
Flammable liquid and vapour.
Harmful if swallowed.
Harmful in contact with skin.
Causes skin irritation.
Causes serious eye irritation.
Toxic if inhaled.
May cause respiratory irritation.
Suspected of damaging fertility or the unborn child.
Reproductive toxicity
Skin irritation
Specific target organ toxicity - single exposure
Irritant
Harmful by inhalation, in contact with skin and if swallowed.
Irritating to eyes, respiratory system and skin.
Possible risk of harm to the unborn child.
Harmful
Further information
The above information is believed to be correct but does not purport to be all inclusive and
shall be used only as a guide. The information this document is based on the resent state
of our knowledge and is applicable to the product with regard to appropriate safety precautions.
It does not represent any guarantee of the properties of the product. guidechem shall not be
held liable for any damage resulting from handling or from contact with the above product.
See reverse side of invoice or packing slip for additional terms and conditions of sale.