Acetyl hexamethyl tetralin (cas 1506-02-1) MSDS

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PFW Aroma Chemicals B.V.
Veemweg 29-31
3771 MT Barneveld
The Netherlands

Telephone: +31 342 407710
Telefax: +31 342 407720

Safety Data Sheet
TONALID? II 263406
CHAPTER 1 PRODUCT INFORMATION
: TONALID? II
Product name
: 263406
Product code
: 7-Acetyl-1,1,3,4,4,6-Hexamethyltetraline
Chemical names

Chemical family : Tetralines
CAS no.(s) : 1506-02-1/ 21145-77-7
: 216-133-4/ 244-240-6
EC no.(s)
EC name(s) : 1-(5,6,7,8-tetrahydro-3,5,5,6,8,8-hexamethyl-2-naphthyl) ethan-1-one;
C18-H26-O

: Fragrance ingredient which may be used in any fragrance compound
Recommended use
according to legal and IFRA rules.

Emergency phone number: PFW Aroma Chemicals B.V. tel. +31-342-407700

CHAPTER 2 COMPOSITION/INFORMATION ON INGREDIENTS
: 97% minimum
Purity

: Label in accordance with EC-Directive 67/548/EEC and amendments.
EC-label

: Xn
Pictograph(s)
N



R-phrase(s) : R22
R50/53




S-phrase(s) : S24/25
S61


Please refer to Chapter 16 for the full text of
the classification when applicable.
CHAPTER 3 HAZARD IDENTIFICATION
Skin contact may cause dermatitis upon exposure to sunlight.
The undiluted product is harmful if swallowed.




date of preparation PDF file : 7 May 2007 The information contained herein, to the best of our knowledge, is true and accurate. Any recommendations or suggestions are made
without warranty or guarantee, since the conditions of use are beyond our control. Nothing contained herein shall be construed to imply
the non-existence of any relevant patents nor so constitute a permission, inducement or recommendation to practice any invention
covered by any patent without authority from the owner of the patent.
PFW Aroma Chemicals B.V.
Veemweg 29-31
3771 MT Barneveld
The Netherlands

Telephone: +31 342 407710
Telefax: +31 342 407720

Safety Data Sheet
TONALID? II 263406


The undiluted product may be irritating to eyes and skin.




See also Chapter 11 (toxicological information) and Chapter 16 (other information).


CHAPTER 4 FIRST AID MEASURES
: Remove contact lenses. Hold eyelids apart. Flush immediately with water
Eye Exposure
for at least 15 minutes. If irritation persists or any sign of tissue damage is
apparent, obtain medical advice.



: Remove any contaminated clothing or shoes. Wash affected areas
Skin Exposure
thoroughly with soap and water for at least 15 minutes. If irritation
persists or any sign of tissue damage is apparent, seek medical
attention.


: Do not induce vomiting. If conscious, rinse mouth with water and give
Ingestion
large quantities of water to drink. Obtain medical advice (and show the
label or datasheet where possible).




: Remove from exposure site to fresh air and keep at rest. Obtain medical
Inhalation
advice (and show the label or datasheet where possible).




CHAPTER 5 FIRE FIGHTING MEASURES
: CO2, dry chemical, foam.
Extinguishing Media

: None special.
Special Fire Fighting
Procedures


: None known.
Unusual Fire & Explosion
Hazards

: Burning may generate CO, CO2 and unidentified organic and anorganic
Hazardous products of
Combustion compounds.



Date of preparation PDF file : 7 May 2007
PFW Aroma Chemicals B.V.
Veemweg 29-31
3771 MT Barneveld
The Netherlands

Telephone: +31 342 407710
Telefax: +31 342 407720

Safety Data Sheet
TONALID? II 263406

CHAPTER 6 ACCIDENTAL RELEASE MEASURES
: Remove ignition sources. Provide adequate ventilation. Avoid inhalation
Personal Precautions
of vapour or dust. Avoid skin and eye contact.


: Do not dispose into the environment. Absorb spills with sand or inert
Disposal
powder.


: Do not dispose into drainage/sewer system, soil or the aquatic
Environmental Precautions
environment.


CHAPTER 7 STORAGE AND HANDLING
: Store in a cool, dry and well ventilated place. Keep away from sources of
Storage Conditions
ignition - No smoking. Keep container tightly closed.
Store separately from oxidizing agents.
The product is easily contaminated by environmental odours. Keep away
from other fragrance/flavour materials.




: None special.
Handling Instructions




: Keep containers closed.
Special Precautions




CHAPTER 8 EXPOSURE CONTROLS / PERSONAL PROTECTION
Exposure Controls
: In accordance with good manufacturing and industrial practices.
Industrial hygiene

: Keep exposure to a minimum.
Engineering Controls
: None established.
Exposure limit values




Date of preparation PDF file : 7 May 2007
PFW Aroma Chemicals B.V.
Veemweg 29-31
3771 MT Barneveld
The Netherlands

Telephone: +31 342 407710
Telefax: +31 342 407720

Safety Data Sheet
TONALID? II 263406

Personal protection
: Take care to prevent material being splashed on the eye. Depending on
Eye Protection
working situation safety glasses, goggles or full face shield are advised.



: Take care to prevent material being splashed on the skin. Depending on
Hand / Skin Protection
working situation protective clothing (e.g. impervious gloves and suitable
overall) is recommended based on the hazard.


: Maintain adequate ventilation in working area. Avoid inhalation of vapours
Respiratory Protection
or dust. Self-contained breathing apparatus should be worn, where there
is a risk of exposure to excessive vapour or dust concentration.




CHAPTER 9 PHYSICAL AND CHEMICAL PROPERTIES
Appearance : Off-white solid
Odour : Musky


: Insoluble
Solubility in water
: >100 ??C (Closed Cup)
Flashpoint
: 180 ??C (15 mbar) (measured)
Boiling point
: >52 ??C (measured)
Melting point
Log Pow : 5.7 (measured)
Vapour pressure : 0.682 * 10-3 mbar (25 ??C) (measured)




CHAPTER 10 STABILITY AND REACTIVITY
Stability Considerations : Stable in most media.

: Strong oxidizing agents and direct sunlight.
Conditions to avoid

Thermal Decomposition : None known.
Hazardous Decomposition : Burning may generate CO, CO2 and unidentified hazardous organic and
anorganic compounds.
: Not expected to occur.
Hazardous Polymerization

Date of preparation PDF file : 7 May 2007
PFW Aroma Chemicals B.V.
Veemweg 29-31
3771 MT Barneveld
The Netherlands

Telephone: +31 342 407710
Telefax: +31 342 407720

Safety Data Sheet
TONALID? II 263406

CHAPTER 11 TOXICOLOGICAL INFORMATION
LD50 Oral Rat : 964 mg/kg
: 7940 mg/kg
LD50 Dermal Rat
: NOAEL
90-days Chronic toxicity (rat) : 15 mg/kg/day
: Ames test : Negative
Mutagenicity
Irritation/sensitization effects Concentration in solvent
Human skin irritation 10% Ethanol/DEP : No irritation
rabbit skin irritation 50% DEP : No irritation
HRIPT Human 10% Ethanol/DEP : No sensitization
Human maximisation test 2% petrolatum : No sensitization
Human photosensitization 10% Ethanol/DEP : No photosensitization
Guinea pig photosensitization 2% Ethanol : No photosensitization
Human phototoxicity 10% Ethanol/DEP : No phototoxic effects
Rabbit phototoxicity 2% Ethanol : Phototoxic effects
Rabbit eye irritation 100% Not applicable : No irritation

: Test data PFW Aroma Chemicals B.V. and Research Institute for Fragrance
Reference(s)
Materials (RIFM).


Remarks : Results rated according to the EC-standards.




CHAPTER 12 ECOLOGICAL INFORMATION




Date of preparation PDF file : 7 May 2007
PFW Aroma Chemicals B.V.
Veemweg 29-31
3771 MT Barneveld
The Netherlands

Telephone: +31 342 407710
Telefax: +31 342 407720

Safety Data Sheet
TONALID? II 263406
Sort test Acute and chronic results
: Prolonged tox. test 21 d. LC50 : 0,314 mg/L : 0,089 mg/L
fish test NOEC
: FELS toxicity test : 0,035 mg/L
Fish test NOEC
21 d. EC50 : 0,244 mg/L : 0,196 mg/L
Daphnia test : Reproductive capacity NOEC
: Algae inhibition test : 0,8 mg/L : 0,4 mg/L
Algae test 72 h. IC50 NOEC

: Test data PFW Aroma Chemicals B.V. and Research Institute for Fragrance
Reference(s)
Materials (RIFM).
See also: Toxicology Letters Volume 111 NOS. 1-2 (1999)




CHAPTER 13 DISPOSAL CONSIDERATION
Disposal : Small spills may be flushed away with copious water. Absorb spills with
sand or inert powder. Dispose of in accordance with current laws and
regulations.


: Do not dispose into drainage/sewer system, soil or the aquatic
Environmental Precautions
environment.

CHAPTER 14 TRANSPORT INFORMATION
Sub. Risk : -
ADR/RID : 9 III
: 9 III UN nr. : 3077
IATA/ICAO
: 9 III IMDG MP : P
IMDG
: Environmentally hazardous substance, solid, n.o.s.
Proper shipping name
(7-Acetyl-1,1,3,4,4,6-Hexamethyltetraline)


CHAPTER 15 REGULATORY INFORMATION
: Label in accordance with EC-Directive 67/548/EEC and amendments.
EC-label


: Xn
Pictograph(s)
N



R-phrase(s) : R22
R50/53




Date of preparation PDF file : 7 May 2007
PFW Aroma Chemicals B.V.
Veemweg 29-31
3771 MT Barneveld
The Netherlands

Telephone: +31 342 407710
Telefax: +31 342 407720

Safety Data Sheet
TONALID? II 263406

S-phrase(s) : S24/25
S61




EINECS : Yes
TSCA : Yes
IFRA Restrictions : Not limited.
Other : The product complies with EC-Directive 76/768/EEC and amendments
(Cosmetic Directive).

CHAPTER 16 OTHER INFORMATION
This Safety Data Sheet is drawn up in accordance with EC-Directive 91/155/EEC and amendments.
The user of this product must decide what safety measures are necessary to safely use this product,
either alone or in combination with other products, and determine the environmental regulatory
compliance obligations under any applicable federal or state laws.



Harmful. Dangerous for the environment.

Harmful if swallowed. Very toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.

Avoid contact with skin and eyes. Avoid release to the environment. Refer to special instructions/safety
data sheets.




Date of preparation : 7 May 2007 Date of preparation PDF file: 7 May 2007
: 4.2 Replaces Version : 4.1; 31 October 2003
Version



Date of preparation PDF file : 7 May 2007