Petroleum coke (cas 64741-79-3) MSDS

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Material Safety Data Sheet
MSDS ID NO.: 0109MAR019
Revision date: 09/12/2005
1. CHEMICAL PRODUCT AND COMPANY INFORMATION
Product name: Marathon Petroleum Coke
Synonyms: Petroleum Coke, MAPLLC
Chemical Family: Complex hydrocarbon
Formula: Mixture


Manufacturer:
Marathon Petroleum Company LLC
539 South Main Street
Findlay OH 45840


Other information: 419-421-3070
Emergency telephone number: 877-627-5463

2. COMPOSITION/INFORMATION ON INGREDIENTS
Petroleum Coke is a solid carbon material produced from high temperature treatment of heavy petroleum fractions.
Composition varies depending on source of final product. Polycyclic aromatic hydrocarbons (3-7 ring), such as
benzo(a)pyrene, are present in trace concentrations (<0.1%).

Product information
Name CAS Number Weight % ACGIH Exposure OSHA - Vacated Other:
Limits: PELs - Time
Weighted Ave
Marathon Petroleum Coke 64741-79-3 100


Component Information

Name CAS Number Weight % ACGIH Exposure OSHA - Vacated Other:
Limits: PELs - Time
Weighted Ave
Petroleum Coke 64741-79-3 100


Notes: The manufacturer has voluntarily elected to reflect exposure limits contained in
OSHA's 1989 air contaminants standard in its MSDS's, even though certain of those
exposure limits were vacated in 1992.

3. HAZARDS IDENTIFICATION

EMERGENCY OVERVIEW
PETROLEUM COKE IS A CHUNKY, POROUS, BLACK, CARBON MATERIAL. WHEN CALCINED, IT IS CRUSHE AND PULVERIZED INTO A FINE BLACK POWDER. IT IS NEITHER A FLAMMABLE NOR COMBUSTIBLE MATERIAL
BUT COULD BURN IF HEATED TO EXTREMELY HIGH TEMPERATURES.

OSHA WARNING LABEL:

THIS PRODUCT HAS BEEN EVALUATED AND DOES NOT REQUIRE ANY HAZARD WARNING LABEL UNDE THE OSHA HAZARD COMMUNICATION STANDARD.
MSDS ID NO.: 0109MAR019 Product name: Marathon Petroleum Coke CONSUMER WARNING LABEL:

A CONSUMER WARNING LABEL IS NOT APPLICABLE FOR THIS PRODUCT.


Inhalation: Excessive dust from powdered material (>5 mg/kg) may cause mild respiratory
irritation.

Ingestion: Not likely to be toxic by ingestion.

Skin contact: None expected from acute exposure.

Eye contact: Dust may be a mechanical irritant.

Carcinogenic Evaluation:

Product information
Name IARC NTP ACGIH - OSHA - Select
Carcinogens: Carcinogens: Carcinogens: Carcinogens:
Marathon Petroleum Coke NE
64741-79-3


Notes: The International Agency for Research on Cancer (IARC) has not evaluated this
product.

Component Information


4. FIRST AID MEASURES
Inhalation: If affected, move person to fresh air. If breathing is difficult, administer oxygen. If not
breathing or if no heartbeat, give artificial respiration or cardiopulmonary
resuscitation (CPR). Immediately call a physician. If symptoms or irritation occur with
any exposure, call a physician.

Skin contact: Wash with soap and large amounts of water. If symptoms or irritation occur, call a
physician.

Ingestion: Ingestion not likely. If large amounts are swallowed, immediately call a physician.

Eye contact: Flush eyes with large amounts of tepid water for at least 15 minutes. If symptoms or
irritation occur, call a physician.

Medical conditions aggravated by No data available.
exposure:

5. FIRE FIGHTING MEASURES
Suitable extinguishing media: For small fires, Class B fire extinguishing media such as
CO2, dry chemical, foam (AFFF/ATC) or water spray can be
used. For large fires, water spray, fog or foam (AFFT/ATC)
can be used. Fire fighting should be attempted only by those
who are adequately trained and equipped with proper
protective equipment.
Specific hazards: This product is neither a flammable nor combustible
material, but will burn when heated to extremely high
temperatures.




MSDS ID NO.: 0109MAR019 Product name: Marathon Petroleum Coke Special protective equipment for firefighters: Avoid using straight water streams. Water spray and foam
(AFFF/ATC) must be applied carefully to avoid frothing and
from as far a distance as possible. Keep surrounding area
cool with water spray from a distance and prevent further
ignition of combustible material. Avoid excessive water
spray application. Keep run-off water out of sewers and
water sources.

Flash point: >200 F
Autoignition temperature: No data available.
Flammable limits in air - lower (%): No data available.
Flammable limits in air - upper (%): No data available.

NFPA rating: HMIS classification:
Health: 1 Health: 1
Flammability: 1 Flammability: 1
Reactivity: 1 Reactivity: 1
Other: - Special: *See Section 8 for guidance in selection of
personal protective equipment.

6. ACCIDENTAL RELEASE MEASURES
Personal precautions: No special procedures. Advise authorities and National Response Center (800-424-
8802) if substance has entered a watercourse or sewer. Notify local health and
pollution control agencies, if appropriate.

7. HANDLING AND STORAGE
Handling:
Comply with all applicable EPA, OSHA, NFPA and consistent state and local requirements. Use appropriate grounding
and bonding practices. Store in properly closed containers that are appropriately labeled and in a cool well-ventilated
area. Do not expose to heat, open flames, strong oxidizers or other sources of ignition.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION
PERSONAL PROTECTIVE EQUIPMENT

Engineering measures: Local or general exhaust required in an enclosed area or when there is inadequate
ventilation.

Respiratory protection: Not required under normal conditions and adequate ventilation. Use dust/ fume
respirator if use generates excessive dust/fume or concentrations exceed
permissible limits.

Skin and body protection: Gloves.

Eye protection: Dust goggles if use produces excessive dust/fume concentrations.



9. PHYSICAL AND CHEMICAL PROPERTIES:
Appearance: Black Porous Chunks or Powder
Physical state (Solid/Liquid/Gas): Solid
Substance type (Pure/Mixture): Mixture
Color: Black
Odor: Slight Hydrocarbon
Molecular weight: Not determined.
MSDS ID NO.: 0109MAR019 Product name: Marathon Petroleum Coke pH: Neutral
Boiling point/range (5-95%): 7600 F
Melting point/range: 6300 F
Decomposition temperature: Not applicable.
Specific gravity: 0.8-1.0
Density: No data available.
Bulk density: No data available.
Vapor density: No data available.
Vapor pressure: Negligible
Evaporation rate: No data available.
Solubility: Not determined
Solubility in other solvents: No data available.
Partition coefficient (n-octanol/water): No data available.
VOC content(%): No data available.
Viscosity: No data available.

10. STABILITY AND REACTIVITY
Stability: The material is stable at 70 F, 760 mm pressure.

Polymerization: Will not occur.

Hazardous decomposition products: Carbon monoxide and carbon dioxide, hydrocarbons.

Materials to avoid: None known.

Conditions to avoid: Dust can form flammable mixtures in air.

11. TOXICOLOGICAL INFORMATION


Acute toxicity:

Product information
Name CAS Number Inhalation: Dermal: Oral:
Marathon Petroleum Coke 64741-79-3 No data available No data available No data available


Non-carcinogenic in mice in chronic skin painting studies with coke dust. Petroleum coke was found not to be
carcinogenic in monkeys and rats in a two-year inhalation study at concentrations up to 30 mg/m3. Chronic inflammatory
changes similar to those produced by non-specific respiratory irritants were observed in some rats at the highest
exposure level. Chronic skin painting studies of coke dust in mice did not produce evidence of carcinogenicity. Petroleum
coke (delayed process and fluid process) was found not to be mutagenic in a rat in vivo bone marrow cytogenetic test, a
mouse lymphoma assay and an Ames mutagenicity assay.



12. ECOLOGICAL INFORMATION
Ecotoxicity effects: This product is not expected to cause any acute or chronic toxicity to aquatic
organisms due to its extremely low water solubility.

13. DISPOSAL CONSIDERATIONS
Cleanup Considerations: This product as produced is not specifically listed as an EPA
RCRA hazardous waste according to federal regulations (40
CFR 260-271). However, when discarded, spilled or
disposed of, it can become an EPA RCRA hazardous waste.
It is the responsibility of the user to determine if disposal
material is hazardous according to federal, state and local
regulations.
MSDS ID NO.: 0109MAR019 Product name: Marathon Petroleum Coke 14. TRANSPORT INFORMATION
49 CFR 172.101:

DOT:
Transport Information: This material when transported via US commerce is NOT REGULATED by DOT
regulations.

DOT reportable quantity (lbs): Not applicable.


TDG (Canada):
Regulated substances: Not applicable.

15. REGULATORY INFORMATION
Federal Regulatory Information:

US TSCA Chemical Inventory Section 8(b): This product and/or its components are listed on the TSCA
Chemical Inventory.

OSHA Hazard Communication Standard: This product has been evaluated and determined not to be
hazardous as defined in OSHA's Hazard Communication
Standard.

EPA Superfund Amendment & Reauthorization Act (SARA):

SARA Section 302: This product contains the following component(s) that have been listed on EPA's
Extremely Hazardous Substance (EHS) List:
Name CERCLA/SARA - Section 302 Extremely Hazardous Substances and TPQs
Petroleum Coke NA




SARA Section 304: This product contains the following component(s) identified either as an EHS or a
CERCLA Hazardous substance which in case of a spill or release may be subject to
SARA reporting requirements:
Name CERCLA/SARA - Hazardous Substances and their Reportable Quantities
Petroleum Coke NA


SARA Section 311/312: The following EPA hazard categories apply to this product:

None

SARA Section 313: This product contains the following component(s) that may be subject to reporting on
the Toxic Release Inventory (TRI) From R:
Name CERCLA/SARA 313 Emission reporting:
Petroleum Coke None


State and Community Right-To-Know Regulations:
The following component(s) of this material are identified on the regulatory lists below:

Petroleum Coke
Louisiana Right-To-Know: Not Listed
California Proposition 65: Not Listed
New Jersey Right-To-Know: Not Listed.
Pennsylvania Right-To-Know: Not Listed.
Massachusetts Right-To Know: Not Listed.
MSDS ID NO.: 0109MAR019 Product name: Marathon Petroleum Coke Florida substance List: Not Listed.
Rhode Island Right-To-Know: Not Listed
Michigan critical materials register list: Not Listed.
Massachusetts Extraordinarily Hazardous Not Listed
Substances:
California - Regulated Carcinogens: Not Listed
Pennsylvania RTK - Special Hazardous Not Listed
Substances:
New Jersey - Special Hazardous Substances: Not Listed
New Jersey - Environmental Hazardous Not Listed
Substances List:
Illinois - Toxic Air Contaminants Not Listed
New York - Reporting of Releases Part 597 - Not Listed
List of Hazardous Substances:

Canadian Regulatory Information:

Canada DSL/NDSL Inventory: This product and/or its components are listed either on the Domestic Substances List
(DSL) or the Non Domestic Substance List (NDSL).


16. OTHER INFORMATION
Additional Information: No data available.

Prepared by: Craig M. Parker Manager, Toxicology and Product Safety

The information and recommendations contained herein are based upon tests believed to be reliable. However,
Marathon Petroleum Company LLC (MPC) does not guarantee their accuracy or completeness nor shall any of this
information constitute a warranty, whether expressed or implied, as to the safety of the goods, the merchantability of the
goods, or the fitness of the goods for a particular purpose. Adjustment to conform to actual conditions of usage maybe
required. MPC assumes no responsibility for results obtained or for incidental or consequential damages, including lost
profits arising from the use of these data. No warranty against infringement of any patent, copyright or trademark is made
or implied.

End of Safety Data Sheet




MSDS ID NO.: 0109MAR019 Product name: Marathon Petroleum Coke