Propanoic acid,3-ethoxy-, ethyl ester (cas 763-69-9) MSDS

Download
Download
1.
1.1
IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
Product identifiers
Product name
Product Number
Brand
CAS-No.
:
:
:
:
Ethyl 3-ethoxypropionate
537586
-
763-69-9
1.2
Relevant identified uses of the substance or mixture and uses advised against
Identified uses
:
Laboratory chemicals, Manufacture of substances
2.
2.1
2.2
HAZARDS IDENTIFICATION
Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008 [EU-GHS/CLP]
Flammable liquids (Category 3)
Classification according to EU Directives 67/548/EEC or 1999/45/EC
May form explosive peroxides. Harmful to aquatic organisms.
Label elements
Labelling according Regulation (EC) No 1272/2008 [CLP]
Pictogram
Signal word
Hazard statement(s)
H226
Precautionary statement(s)
Supplemental Hazard
Warning
Flammable liquid and vapour.
none
none
Statements
According to European Directive 67/548/EEC as amended.
Hazard symbol(s)
R-phrase(s)
R19
R52
- - 537586
none
May form explosive peroxides.
Harmful to aquatic organisms.
S-phrase(s)
S16
Keep away from sources of ignition - No smoking.
2.3
3.
3.2
Other hazards
May form explosive peroxides.
COMPOSITION/INFORMATION ON INGREDIENTS
Mixtures
Synonyms
Formula
Molecular Weight
:
:
:
EEP Solvent
C7H14O3
146,18 g/mol
Component
Ethyl 3-ethoxypropionate
Classification
Concentration
CAS-No.
EC-No.
763-69-9
212-112-9
Flam. Liq. 3; H226
-
For the full text of the H-Statements and R-Phrases mentioned in this Section, see Section 16
4.
4.1
4.2
4.3
5.
5.1
5.2
5.3
5.4
FIRST AID MEASURES
Description of first aid measures
General advice
Consult a physician. Show this safety data sheet to the doctor in attendance.
If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
In case of skin contact
Wash off with soap and plenty of water. Consult a physician.
In case of eye contact
Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
If swallowed
Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with
water. Consult a physician.
Most important symptoms and effects, both acute and delayed
Nausea, Headache, Vomiting, Central nervous system depression, Dizziness
Indication of any immediate medical attention and special treatment needed
no data available
FIREFIGHTING MEASURES
Extinguishing media
Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Special hazards arising from the substance or mixture
no data available
Advice for firefighters
Wear self contained breathing apparatus for fire fighting if necessary.
Further information
Use water spray to cool unopened containers.
- - 537586
6.
6.1
6.2
6.3
6.4
7.
7.1
7.2
7.3
8.
8.1
8.2
ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. Avoid breathing vapors, mist or gas. Ensure adequate ventilation.
Remove all sources of ignition. Beware of vapours accumulating to form explosive concentrations.
Vapours can accumulate in low areas.
Environmental precautions
Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the
environment must be avoided.
Methods and materials for containment and cleaning up
Contain spillage, and then collect with an electrically protected vacuum cleaner or by wet-brushing and
place in container for disposal according to local regulations (see section 13).
Reference to other sections
For disposal see section 13.
HANDLING AND STORAGE
Precautions for safe handling
Avoid contact with skin and eyes. Avoid inhalation of vapour or mist.
Keep away from sources of ignition - No smoking.Take measures to prevent the build up of electrostatic
charge.
Conditions for safe storage, including any incompatibilities
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are
opened must be carefully resealed and kept upright to prevent leakage.
Specific end uses
no data available
EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters
Components with workplace control parameters
Exposure controls
Appropriate engineering controls
Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and
at the end of workday.
Personal protective equipment
Eye/face protection
Face shield and safety glasses Use equipment for eye protection tested and approved under
appropriate government standards such as NIOSH (US) or EN 166(EU).
Skin protection
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique
(without touching glove's outer surface) to avoid skin contact with this product. Dispose of
contaminated gloves after use in accordance with applicable laws and good laboratory practices.
Wash and dry hands.
The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and
the standard EN 374 derived from it.
Body Protection
impervious clothing, Flame retardant antistatic protective clothing, The type of protective
equipment must be selected according to the concentration and amount of the dangerous
substance at the specific workplace.
Respiratory protection
Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator
with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup
to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air
- - 537586
respirator. Use respirators and components tested and approved under appropriate government
standards such as NIOSH (US) or CEN (EU).
9.
9.1
PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
a)
b)
c)
d)
e)
f)
g)
h)
Appearance
Odour
Odour Threshold
pH
Melting point/freezing
point
Initial boiling point and
boiling range
Flash point
Evaporation rate
Form: clear
no data available
no data available
no data available
Melting point/range: < -50 °C
166 °C - lit.
59 °C
no data available
i)
Flammability (solid, gas) no data available
j)
k)
l)
Upper/lower
flammability or
explosive limits
Vapour pressure
Vapour density
Lower explosion limit: 1,05 %(V)
2,0 hPa at 25 °C
5,03
m) Relative density
0,95 g/mL at 25 °C
n)
o)
p)
q)
r)
s)
t)
Water solubility
Partition coefficient: n-
octanol/water
Autoignition
temperature
Decomposition
temperature
Viscosity
Explosive properties
Oxidizing properties
25 g/l
log Pow: 1,35
377 °C
no data available
no data available
no data available
no data available
9.2
10.
10.1
10.2
10.3
10.4
Other safety information
no data available
STABILITY AND REACTIVITY
Reactivity
no data available
Chemical stability
no data available
Contains the following stabiliser(s):
formaldehyde (<=0,03 %)
bht (<=0,01 %)
Possibility of hazardous reactions
no data available
Conditions to avoid
Heat, flames and sparks.
- - 537586
10.5
10.6
11.
11.1
Incompatible materials
Strong oxidizing agents, Strong bases
Hazardous decomposition products
Other decomposition products - no data available
TOXICOLOGICAL INFORMATION
Information on toxicological effects
Acute toxicity
LD50 Oral - rat - 5.000 mg/kg
LC50 Inhalation - rat - 6 h - > 1000 ppm
LD50 Dermal - rabbit - 9.500 mg/kg
Skin corrosion/irritation
Skin - rabbit - Mild skin irritation - 24 h
Serious eye damage/eye irritation
Eyes - rabbit - Mild eye irritation - 24 h
Respiratory or skin sensitization
no data available
Germ cell mutagenicity
no data available
Carcinogenicity
IARC:
No component of this product present at levels greater than or equal to 0.1% is identified as
probable, possible or confirmed human carcinogen by IARC.
Reproductive toxicity
Specific target organ toxicity - single exposure
no data available
Specific target organ toxicity - repeated exposure
no data available
Aspiration hazard
no data available
Potential health effects
Inhalation
Ingestion
Skin
Eyes
May be harmful if inhaled. May cause respiratory tract irritation.
May be harmful if swallowed.
May be harmful if absorbed through skin. May cause skin irritation.
Causes eye irritation.
Signs and Symptoms of Exposure
Nausea, Headache, Vomiting, Central nervous system depression, Dizziness
Additional Information
RTECS: UF3325000
12.
12.1
ECOLOGICAL INFORMATION
Toxicity
Toxicity to fish
Toxicity to daphnia and
other aquatic
invertebrates
Toxicity to algae
LC50 - Pimephales promelas (fathead minnow) - 50 mg/l - 96 h
EC50 - Daphnia magna (Water flea) - > 480 mg/l - 48 h
EC50 - Algae - > 115 mg/l - 72 h
12.2
Persistence and degradability
no data available
- - 537586
12.3
12.4
12.5
12.6
13.
13.1
14.
14.1
Bioaccumulative potential
no data available
Mobility in soil
no data available
Results of PBT and vPvB assessment
no data available
Other adverse effects
Harmful to aquatic life.
Harmful to aquatic life.
DISPOSAL CONSIDERATIONS
Waste treatment methods
Product
Burn in a chemical incinerator equipped with an afterburner and scrubber but exert extra care in igniting
as this material is highly flammable. Offer surplus and non-recyclable solutions to a licensed disposal
company.
Contaminated packaging
Dispose of as unused product.
TRANSPORT INFORMATION
UN number
14.2
ADR/RID: 3272
UN proper shipping name
IMDG: 3272
IATA: 3272
ADR/RID:
IMDG:
IATA:
ESTERS, N.O.S. (Ethyl 3-ethoxypropionate)
ESTERS, N.O.S. (Ethyl 3-ethoxypropionate)
Esters, n.o.s. (Ethyl 3-ethoxypropionate)
14.3
Transport hazard class(es)
14.4
14.5
14.6
15.
ADR/RID: 3
Packaging group
ADR/RID: III
Environmental hazards
ADR/RID: no
Special precautions for user
no data available
REGULATORY INFORMATION
IMDG: 3
IMDG: III
IMDG Marine pollutant: no
IATA: 3
IATA: III
IATA: no
This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.
15.1
15.2
16.
Safety, health and environmental regulations/legislation specific for the substance or mixture
no data available
Chemical Safety Assessment
no data available
OTHER INFORMATION
Text of H-code(s) and R-phrase(s) mentioned in Section 3
Flam. Liq.
H226
R19
R52
Flammable liquids
Flammable liquid and vapour.
May form explosive peroxides.
Harmful to aquatic organisms.
Further information
The above information is believed to be correct but does not purport to be all inclusive and
shall be used only as a guide. The information this document is based on the resent state
of our knowledge and is applicable to the product with regard to appropriate safety precautions.
It does not represent any guarantee of the properties of the product. guidechem shall not be
held liable for any damage resulting from handling or from contact with the above product.
See reverse side of invoice or packing slip for additional terms and conditions of sale.

The above information is believed to be correct but does not purport to be all inclusive and shall be
used only as a guide. The information in this document is based on the present state of our knowledge
- - 537586