Pyrethrins (cas 8003-34-7) MSDS

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AGROPHARM LIMITE MATERIAL SAFETY DATA SHEET
PYBLAST




1. Identification of Substance or Preparation

Name of Product: PYBLAST
Product Code: FP419 HSE No. 7485

2. Information on Ingredients

Hazardous Ingredient CAS Number Risk Phrases Approx. Concentration

pyrethrins 8003-34-7 20/21/22, 50/53 3% w/w
Piperonyl Butoxide 51-3-6 51/53 15%
alcohol Ethoxylate 36/38 40%


3. Hazards Identification

Primary Risk Irritant
This product is classified as IRRITANT under the Chemicals (Hazard Information and Packaging)
Regulations 1996

4. First Aid Measures

Inhalation Remove to fresh air. Get medical help if symptoms persist.
Skin Wash exposed skin with soap and water. For persistent irritation seek
medical advice.
Eyes Flush out with clean water for at least 15 minutes. Get medical attention if
irritation persists.
Ingestion Do not induce vomiting. Get medical attention. Give small amounts of milk
or water and seek medical attention Show container, label, or this safety
sheet to doctor.


5. Fire Fighting Measures

This product is not flammable. However, toxic fumes (oxides of carbon) may be evolved in the
event of a fire. Treat fires with dry chemical, foam or water spray. Wear protective clothing and
self contained breathing apparatus.

6. Accidental Release Measures

Clean up excess with absorbent material and dispose in an approved manner. Product should not
enter drainage system. Dispose of via an authorised waste disposal contractor.



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AGROPHARM LIMITE MATERIAL SAFETY DATA SHEET

7. Storage and Handling

If splashing is likely to occur wear eye protection.
If skin contact is likely to occur wear rubber gloves and suitable protective clothing.
Use in a well ventilated area
Store in original container, in a safe place with a secure lid at ambient temperatures.
Keep out of reach of children
Wash hands and exposed skin after using and before eating and drinking.

8. Exposure Controls and Personal Protection

Always consult the label before use.
Respirators: Recommended if spray mists are likely, or for use in confined spaces
Gloves: Recommended
Eye Protection: Recommended
Protective Clothing: Recommended

9. Physical and Chemical Properties

Appearance: Yellow/golden liquid Solubility in water Miscible
Odour: Faint detergent Turbidity 0 ?? 20
SG: 0.98 ?? 0.99 Active content 3.0% w/w pyrethrins
pH 6.6 (undiluted) pH 7.4 (diluted 1:40 tap water)

10. Stability and Reactivity

Product is stable under normal conditions, Avoid mixing with other chemicals : strong
acids/alkalis

11. Toxicological Information

OES/LTEL Pyrethrins 5mg/m3
Ingredient:
Pyrethrins: LD50 rat (oral) 900-2000mg/kg. LD50 rat (dermal) >1500mg/kg
Piperonyl Butoxide: LD50 rat (oral) 7500mg/kg
Alcohol Ethoxylate LD50 (oral) ~ 2000mg/kg

Inhalation: Mist may cause irritation to respiratory tract
Skin Contact May cause some irritation. Prolonged contact may cause skin dryness which
may result in dermatitis if left untreated.
Eye Contact Likely to cause irritation and reddening.
Ingestion: May cause irritation to throat and stomach



12. Ecological Information

This product must not enter water discharge systems. Inform appropriate authority if large spillage
enters drains.



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13. Disposal considerations

This material must be disposed of via an Authorised Waste/Disposal Company in accordance with
Local and or National Waste Disposal Regulations. Dispose of empty container by landfill.

14. Transport Information

Name Environmentally hazardous substance, liquid, N.O.S. (contains pyrethrins 3%)
UN Number 3082 Class 9
Packing Group III Marine Pollutant No
ADR/RID Not dangerous for transport
ICAO/IATA Class 9 CAS RN 51-03-6


15. Regulatory Information

Supply Carriage




Risk Phrases
R22 Harmful if swallowed
R36/38 Irritating to eyes and skin
R51 Toxic to aquatic organisms
R57 Toxic to bees



Safety Phrases
S2 Keep out of reach of children.
S20 When using do not eat or drink
24/25 Avoid contact with eyes and skin
26 In case of contact with eyes, rinse immediately with plenty of water and seek
medical advice.
28 After contact with skin, wash immediately with plenty of soap and water.
36/37/38 Wear suitable protective clothing, gloves and eye/face protection
61 Avoid release to the environment. Refer to special instructions/safety data sheet.




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16. Other Information

The information given in this document has been compiled on the basis of best available knowledge
in accordance with the requirements of the Chemical Hazards Information and Packaging
Regulations 1993 and EEC Directive 91/155/EEC. It does not imply that the information is
complete or accurate in all cases. It is the user's responsibility to satisfy him/herself as to the
application of the information and/or the recommendations given for his/her own use.

AGROPHARM LIMITED Revision Number: 1
Buckingham House Revision Date: 23/09/2002
Church Road date Printed: 11/10/2002
Penn
High Wycombe Telephone: 01494 816575
Bucks. HP10 8LN Fax: 01494 816578




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