CAS No. 100-63-0 (phenyl hydrazine )
Molecular Formula: C6H8N2Molecular Weight: 108.14
Identification of 100-63-0
- Name:
- phenyl hydrazine (Related Reference)
- EINECS:
- 202-873-5
- Molecular Formula:
- C6H8N2
- CAS Registry Number:
- 100-63-0
- Synonyms:
- Hydrazinobenzene; Monophenylhydrazine; AI3-15399; BRN 0606080; CCRIS 511; Fenilidrazina; Fenilidrazina [Italian]; Fenylhydrazine; Fenylhydrazine [Dutch]; HSDB 1117; Hydrazine, phenyl-; Hydrazine-benzene; Hydrazobenzene; Phenylhydrazin; Phenylhydrazin [German]; Phenylhydrazine [UN2572] [Poison]; Phenylhydrazine and its salts; UN2572;
- InChI:
- InChI=1/C6H8N2/c7-8-6-4-2-1-3-5-6/h1-5,8H,7H2
- Molecular Structure:
- This structure is also available as a 2d Mol file
Chemical Properties
- Appearance:
- yellow to pale brown oily liquid
- Molecular Weight:
- 108.14
- Density:
- 1.099
- Boiling Point:
- 238-241℃
- Melting Point:
- 19℃
- Flash Point:
- 89℃
- Storage Temperature:
- Store at RT.
- Refractive index:
- 1.604-1.609
- Solubility:
- sparingly soluble SOLVENT
- Stability:
- Stable, but may decompose in sunlight. May be air or light sensitive. Incompatible with strong oxidizing agents, metal oxides.
- Usage:
- An aryl hydrazine used in the preparation of various dyes and pharmaceutical compounds. It is used in the investigation of oligosaccharides as well as the structure of photosystem II.
Safety Data of 100-63-0
- Risk Codes:
- R23/24/25;R36/38;R43;R45;R48/23/24/25;R50;R68
- Safety Statements:
- S45;S53;S61
- Hazard Symbols:
-
T:Toxic
N:Dangerousfortheenvironment
HazardClass:6.1
- MSDS infomation:
- phenyl hydrazine (100-63-0).msds
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References of phenyl hydrazine cas 100-63-0
| Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
|---|---|---|---|---|---|
| dog | LDLo | intravenous | 120mg/kg (120mg/kg) | ? | U.S. Public Health Service, Public Health Bulletin. Vol. 271, Pg. 159, 1941. |
| dog | LDLo | oral | 200mg/kg (200mg/kg) | ? | U.S. Public Health Service, Public Health Bulletin. Vol. 271, Pg. 159, 1941. |
| frog | LDLo | unreported | 300mg/kg (300mg/kg) | ? | U.S. Public Health Service, Public Health Bulletin. Vol. 271, Pg. 159, 1941. |
| guinea pig | LD50 | oral | 80mg/kg (80mg/kg) | BEHAVIORAL: EXCITEMENT BEHAVIORAL: MUSCLE CONTRACTION OR SPASTICITY) |
Hygiene and Sanitation Vol. 30(7-9), Pg. 191, 1965. |
| mouse | LC50 | inhalation | 2120mg/m3 (2120mg/m3) | ? | Trudy Leningradskogo Sanitarno-Gigienicheskogo Meditsinskogo Instituta. Vol. 115, Pg. 59, 1977. |
| mouse | LD50 | intraperitoneal | 170mg/kg (170mg/kg) | ? | Cancer Research. Vol. 41, Pg. 1469, 1981. |
| mouse | LD50 | oral | 175mg/kg (175mg/kg) | BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD BEHAVIORAL: CHANGES IN MOTOR ACTIVITY (SPECIFIC ASSAY) |
Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 30(8), Pg. 21, 1965. |
| mouse | LDLo | subcutaneous | 170mg/kg (170mg/kg) | LUNGS, THORAX, OR RESPIRATION: DYSPNEA LUNGS, THORAX, OR RESPIRATION: OTHER CHANGES LUNGS, THORAX, OR RESPIRATION: CYANOSIS |
Journal of Industrial Hygiene and Toxicology. Vol. 18, Pg. 1, 1936. |
| rabbit | LD50 | oral | 80mg/kg (80mg/kg) | BEHAVIORAL: EXCITEMENT BEHAVIORAL: MUSCLE CONTRACTION OR SPASTICITY) |
Hygiene and Sanitation Vol. 30(7-9), Pg. 191, 1965. |
| rabbit | LDLo | skin | 90mg/kg (90mg/kg) | LUNGS, THORAX, OR RESPIRATION: CYANOSIS LUNGS, THORAX, OR RESPIRATION: RESPIRATORY STIMULATION KIDNEY, URETER, AND BLADDER: HEMATURIA |
National Technical Information Service. Vol. OTS0546542, |
| rat | LC50 | inhalation | 2610mg/m3 (2610mg/m3) | ? | Trudy Leningradskogo Sanitarno-Gigienicheskogo Meditsinskogo Instituta. Vol. 115, Pg. 59, 1977. |
| rat | LD50 | oral | 188mg/kg (188mg/kg) | BEHAVIORAL: EXCITEMENT BEHAVIORAL: MUSCLE CONTRACTION OR SPASTICITY) |
Hygiene and Sanitation Vol. 30(7-9), Pg. 191, 1965. |
Hazard Codes of Phenylhydrazine (CAS NO.100-63-0):?T,N
Risk Statements: 45-23/24/25-36/38-43-48-50-68?
R45: May cause cancer.?
R23/24/25: Toxic by inhalation, in contact with skin and if swallowed.?
R36/38: Irritating to eyes and skin.?
R43: May cause sensitization by skin contact.?
R48: Danger of serious damage to health by prolonged exposure.?
R50: Very toxic to aquatic organisms.?
R68: Possible risk of irreversible effects.
Safety Statements: 53-45-61?
S53: Avoid exposure - obtain special instructions before use.?
S45: In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)?
S61: Avoid release to the environment. Refer to special instructions / safety data sheets.
RIDADR: UN 2572 6.1/PG 2
WGK Germany: 3
RTECS: MV8925000
F: 8-10-23
HazardClass: 6.1
PackingGroup: II
Confirmed carcinogen with experimental carcinogenic data. Poison by ingestion, subcutaneous, and intravenous routes. Experimental reproductive effects. Mutation data reported. Ingestion or subcutaneous injection can cause hemolysis of red blood cells. Other effects are damage to the spleen, liver, kidneys, and bone marrow. The most common effect of occupational exposure is the development of dermatitis, which, in sensitized persons, may be quite severe. Systemic effects include anemia and general weakness, gastrointestinal disturbances, and injury to the kidneys. Flammable when exposed to heat, flame, or oxidizers. To fight fire, use alcohol foam. Violent reaction with 2-phenylamino-3-phenyloxazirane. Reacts with perchloryl fluoride to form an explosive product. Vigorous reaction with lead(IV) oxide. Used as a chemical reagent, in organic synthesis, and in the manufacture of dyes and drugs. Dangerous; when heated to decomposition it emits highly toxic fumes of NOx; can react with oxidizing materials.
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