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Home> Products > Organic Intermediates > Organic Intermediate > CAS DataBase Listed 5 > CAS 56553-60-7
56553-60-7 structure 3D

CAS 56553-60-7 F5860-3319 products price,suppliers
  • Sodium Triacetoxyborohydride(STAB) is a hydride reagent used in stereoselective reductive amination. It is able to replace toxic sodium cyanoborohydride under most conditions. It is selective in reducing aldehydes to alcohols in the presence of ketones. STAB is also stable in anhydrous acids, which enables reductive amination of aldehydes and ketones. It? used in reductive amination of ketones and aldehydes and reductive amination/lactamization of carbonyl compounds with amines.Reagent for the reductive amination of aryl aldehydes.The advantage of STAB compared to sodium cyanoborohydride is evident. STAB, being non-toxic, is easier to handle and forms no toxic by-products, making the treatment of process waste after the reaction simple and less costly.Selective reducing agent in organic synthesis.Sodium triacetoxyborohydride is especially suitable for reductive aminations. Since the reaction rate for the reduction of iminium ions is much faster than for ketones or even aldehydes, the reductive amination can be carried out as a one-pot procedure by introducing the reducing agent into a mixture of the amine and carbonyl compound. The presence of a stoichiometric amount of acetic acid, which catalyzes the imine formation and provides the iminium ion, doesn't present any problem under these conditions.Reductive amination (simplified)
  • Name: F5860-3319
  • Molecular Weight: 210.932
  • Formula: C15H20N4OS
  • Synonyms: Borate(1-), tris(acetato-κO)hydro-, sodium (1:1); MFCD00012211; Sodium triacetoborohydride; Sodium triacetohydroborate, Triacetohydroborate sodium salt; Sodium Triacetoxyborohyride; SODIUM TRIACETOXYHYDROBORATE;
Properties Safety and Handling MSDS Synthesis Route Precursor and Product Computational chemical data
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Identification
Safety Data
  • [Risk Codes]
  • R14/15:Reacts violently with water, liberating extremely flammable gases
  • R34:Causes burns
  • [Safety Statements]
  • S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
  • S36/37/39:Wear suitable protective clothing, gloves and eye/face protection
  • S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible)
  • S7/8:Keep container tightly closed and dry
  • Hazard Symbols:
  • HazardClass:4.3
Properties
  • Molecular Weight:
  • 210.932
  • Melting Point:
  • 114-118℃
  • Storage Temperature:
  • Inert atmosphere,Room Temperature
  • Solubility:
  • reacts
  • Stability:
  • Reacts violently with water.
  • More Properties>>
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C6H9BNaO6 Sodium Triacetoxyborohydride CAS 56553-60-7 Triacetohydroborate sodium salt
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  • Description:Name: Sodium triacetoxyborohydride Synonyms: Sodium Triacetoxyborohydride (STAB);Sodium triacetoxyborohyride;Sodium triacetoborohydride;Sodium Triacetoxysborobydride; CAS Registry number: 56553-60-7 Molecular Formula: C 6 H 10 BNaO 6 Water：reacts Appearance: ...
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