Products
  • Products
  • Encyclopedia
  • Suppliers
  • Buy offers
Current Position: Home > Dictionary EN > A > 75-36-5
 
75-36-5 Properties
Density 1.104
Boiling Point 51℃
Flash Point 4℃
Melting Point -112℃
Appearance colourless to light yellow liquid with a pungent
Vapour 135 mm Hg at 45.5 °F (NTP, 1992)
Refractive Index 1.3876-1.3896
Solubility Highly flammable
Color/Form Colorless fuming liquid
Stability Stability Highly flammable. Reacts violently with DMSO, water, lower alcohols, and amines to generate toxic fumes. May form an explosive mixture with air. Note low flash point. Incompatible with water, alcohols, amines, strong bases, strong oxidizing agents, most common metals.
HS Code 29159080
Storage temp Store at RT
Spectral properties Index of refraction: 1.3898 at 20 deg C/D
MAX ABSORPTION (PETROLEUM ETHER): 220 NM (LOG E= 2.01); SADTLER REF NUMBER: 6030 (IR, PRISM) (GAS)
IR: 6165 (Coblentz Society Spectral Collection)
UV: 420 (Sadtler Research Laboratories Spectral Collection)
NMR: 167 (Varian Associates NMR Spectra Catalogue)
MASS: 97 (Atlas of Mass Spectral Data, John Wiley & Sons, New York)
 
75-36-5 Safety Infomation
Safety Statements S1/2;S9;S16;S26;S45
Risk Statements R11;R14;R34
Hazard Codes C
HazardClass 3
Safety Hazard Codes:F,C
Risk Statements:11-14-34
11:Highly Flammable
14:Reacts violently with water
34:Causes burns
Safety Statements:9-16-26-45-1/2
9:Keep container in a well-ventilated place
16:Keep away from sources of ignition - No smoking
26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible)
1/2:Keep locked up and out of the reach of children
RIDADR:UN 1717 3/PG 2
WGK Germany:1
HazardClass:3
PackingGroup:II
HS Code:29159080
Hazardous Substances Data:75-36-5(Hazardous Substances Data)
Toxicity Vapor irritates mucous membranes. Ingestion of liquid or contact with eyes or skin causes severe irritation.
PackingGroup II
Sensitive Moisture Sensitive
Skin, Eye, and Respiratory Irritations Irritating to skin, eyes, and respiratory system.
A human systemic irritant by inhalation.
Cleanup Methods Cover any spills with sufficient amt of sodium bicarbonate. Remove the mixture in a container such as a fiber drum, plastic bag or carton box for easy disposal in an incinerator, and dispose by burning in a furnace. Wash the spilled spot thoroughly with water.
Transfer or remove slowly by discharging into a plastic or glass vessel containing sodium bicarbonate. Mix thoroughly and transfer slowly to a large vessel containing water while stirring.
Eliminate all ignition sources. Stop or control the leak, if this can be done without undue risk. Approach release from upwind. Control runoff and isolate discharged material for proper disposal.
Environmental considerations: Land spill: Dig a pit, pond, lagoon, holding area to contain liquid or solid material. /SRP: If time permits, pits, ponds, lagoons, soak holes, or holding areas should be sealed with an impermeable flexible membrane liner./ Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete. Absorb bulk liquid with fly ash, cement powder or commercial sorbents. Neutralize with agricultural lime (CaO), crushed limestone (CaCO3) or sodium bicarbonate (NaHCO3). Apply "universal" gelling agent to immobilize spill.
Environmental considerations: Water spill: Neutralize with agricultural lime (CaO), crushed limestone (CaCO3), or sodium bicarbonate (NaHCO3). Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates.
Environmental considerations: Air spill: Apply water spray or mist to knock down vapors. Vapor knockdown water is corrosive or toxic and should be diked for containment.
Transport UN 1717
Fire Fighting Procedures Evacuate surrounding area.
If material on fire or involved in fire: Do not extinguish fire unless flow can be stopped or safely confined. Use dry chemical or carbon dioxide. Do not use water on material itself. If large quantities of combustibles are involved, use water in flooding quantities as spray and fog. Use water spray to knock-down vapors. Cool all affected containers with flooding quantities of water. Apply water from as far a distance as possible.
DO NOT use water or foam directly on spilled material. Violent reaction may result. Use dry chemical or carbon dioxide only. Approach fire from upwind to avoid hazardous vapors and toxic decomposition products. Fight fire from protected location or maximum possible distance.
Evacuation: If fire becomes uncontrollable or container is exposed to direct flame - consider evacuation of one-third (1/3) mile radius.
Fire Potential DANGEROUS, WHEN EXPOSED TO HEAT OR FLAME. ...
Formulations/Preparations /Many/ grades of purity: commercial
DOT Emergency Guidelines If ... THERE IS NO FIRE, go directly to the Table of Initial Isolation and Protective Action Distances /(see table below)/ ... to obtain initial isolation and protective action distances. IF THERE IS A FIRE, or IF A FIRE IS INVOLVED, go directly to the appropriate guide /(see guide(s) below)/ and use the evacuation information shown under PUBLIC SAFETY. Table of Isolation and Protective Action Distances for Acetyl chloride (when spilled in water) Small Spills (from a small package or small leak from a large package) -------------------- First ISOLATE in all Directions 30 meters (100 feet) Then PROTECT persons Downwind during DAY: 0.1 kilometers (0.1 miles) Then PROTECT persons Downwind during NIGHT: 0.4 kilometers (0.3 miles) ==================== Large Spills (From a large package or from many small packages) -------------------- First ISOLATE in all Directions 120 meters (400 feet) Then PROTECT persons Downwind during DAY: 1.1 kilometers (0.7 miles) Then PROTECT persons Downwind during NIGHT: 3.5 kilometers (2.2 miles)
Table of Water-Reactive Materials Which Produce Toxic Gases Materials Which Produce Large Amounts of Toxic-by-Inhalation (TIH) Gas(es) When Spilled in Water Name of Material TIH Gas(es) Produced Acetyl chloride Hydrogen chloride (HCl)
/GUIDE 155: SUBSTANCES - TOXIC AND/OR CORROSIVE (FLAMMABLE/WATER-SENSITIVE)/ Fire or Explosion: HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. Vapors form explosive mixtures with air: indoors, outdoors and sewers explosion hazards. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapors may travel to source of ignition and flash back. Those substances designated with a "P" may polymerize explosively when heated or involved in a fire. Substance will react with water (some violently) releasing flammable, toxic or corrosive gases and runoff. Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated or if contaminated with water.
/GUIDE 155: SUBSTANCES - TOXIC AND/OR CORROSIVE (FLAMMABLE/WATER-SENSITIVE)/ Health: TOXIC; inhalation, ingestion or contact (skin, eyes) with vapors, dusts or substance may cause severe injury, burns, or death. ... Reaction with water or moist air will release toxic, corrosive or flammable gases. Reaction with water may generate much heat which will increase the concentration of fumes in the air. Fire will produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution.
/GUIDE 155: SUBSTANCES - TOXIC AND/OR CORROSIVE (FLAMMABLE/WATER-SENSITIVE)/ Public Safety: CALL Emergency Response Telephone Number ... . As an immediate precautionary measure, isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids. Keep unauthorized personnel away. Stay upwind. Keep out of low areas. Ventilate enclosed areas.
/GUIDE 155: SUBSTANCES - TOXIC AND/OR CORROSIVE (FLAMMABLE/WATER-SENSITIVE)/ Protective Clothing: Wear positive pressure self-contained breathing apparatus (SCBA). Wear chemical protective clothing that is specifically recommended by the manufacturer. It may provide little or no thermal protection. Structural firefighters' protective clothing provides limited protection in fire situations ONLY; it is not effective in spill situations where direct contact with the substance is possible.
/GUIDE 155: SUBSTANCES - TOXIC AND/OR CORROSIVE (FLAMMABLE/WATER-SENSITIVE)/ Evacuation: ... Fire: If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions.
/GUIDE 155: SUBSTANCES - TOXIC AND/OR CORROSIVE (FLAMMABLE/WATER-SENSITIVE)/ Fire: Note: Most foams will react with the material and release corrosive/toxic gases. ... Small fires: CO2, dry chemical, dry sand, alcohol-resistant foam. Large fires: Water spray, fog or alcohol-resistant foam. ... Move containers from fire area if you can do it without risk. Use water spray or fog; do not use straight streams. Fire involving tanks or car/trailer loads: Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. Do not get water inside containers. Cool containers with flooding quantities of water until well after fire is out. Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. ALWAYS stay away from tanks engulfed in fire.
/GUIDE 155: SUBSTANCES - TOXIC AND/OR CORROSIVE (FLAMMABLE/WATER-SENSITIVE)/ Spill or Leak: ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). All equipment used when handling the product must be grounded. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Stop leak if you can do it without risk. A vapor suppressing foam may be used to reduce vapors. ... DO NOT GET WATER on spilled substance or inside containers. Use water spray to reduce vapors or divert vapor cloud drift. Avoid allowing water runoff to contact spilled material. Prevent entry into waterways, sewers, basements or confined areas. Small spills: Cover with DRY earth, DRY sand or other non-combustible material followed with plastic sheet to minimize spreading or contact with rain. Use clean non-sparking tools to collect material and place it into loosely covered plastic containers for later disposal.
/GUIDE 155: SUBSTANCES - TOXIC AND/OR CORROSIVE (FLAMMABLE/WATER-SENSITIVE)/ First Aid: Move victim to fresh air. Call 911 or emergency medical service. Give artificial respiration if victim is not breathing. Do not use mouth-to-mouth method if victim ingested or inhaled the substance; give artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Administer oxygen if breathing is difficult. Remove and isolate contaminated clothing and shoes. In case of contact with substance, immediately flush skin or eyes with running water for at least 20 minutes. For minor skin contact, avoid spreading material on unaffected skin. Keep victim warm and quiet. Effects of exposure (inhalation, ingestion or skin contact) to substance may be delayed. Ensure that medical personnel are aware of the material(s) involved and take precautions to protect themselves.
Reactivities and Incompatibilities Water reactive. Violent exothermic decomposition with water produces corrosive hydrochloric and acetic acids. Reacts violently with alcohols, alkalies, amines, and strong oxidizing materials.
VIOLENT HYDROLYSIS REACTION WITH WATER OR STEAM PRODUCES HEAT, ACETIC ACID, HYDROCHLORIC ACID (HCL), AND OTHER CORROSIVE CHLORIDES. ALSO INCOMPATIBLE WITH PCL3.
Decomposed violently by water or alcohol.
Use of a free flame instead of a heating bath to distill acetyl chloride produced from acetic acid and phosphorus trichloride caused the residual phosphonic (phosphorous) acid to decompose violently to give spontaneously flammable phosphine. Two later explosions in the same preparative system after reflux but before distillation from a water bath may have been due to ingress of air into the cooling flask and ignition of traces of phosphine.
EXPLOSION HAZARD: BY SPONTANEOUS CHEMICAL REACTION, ON CONTACT WITH WATER, DIMETHYL SULFOXIDE OR ETHANOL.
Other Preventative Measures SRP: The scientific literature for the use of contact lenses in industry is conflicting. The benefit or detrimental effects of wearing contact lenses depend not only upon the substance, but also on factors including the form of the substance, characteristics and duration of the exposure, the uses of other eye protection equipment, and the hygiene of the lenses. However, there may be individual substances whose irritating or corrosive properties are such that the wearing of contact lenses would be harmful to the eye. In those specific cases, contact lenses should not be worn. In any event, the usual eye protection equipment should be worn even when contact lenses are in place.
If material not on fire and not involved in fire: Keep sparks, flames, and other sources of ignition away. Keep material out of water sources and sewers. Build dikes to contain flow as necessary. Attempt to stop leak if without undue personnel hazard. Use water spray to knock-down vapors. Do not use water on material itself. Neutralize spilled material with crushed limestone, soda ash, or lime.
Personnel protection: Avoid breathing vapors. Keep upwind. ... Avoid bodily contact with the material. ... Do not handle broken packages unless wearing appropriate personal protective equipment. Wash away any material which may have contacted the body with copious amounts of water or soap and water.
Evacuation: If material leaking (not on fire) consider evacuation from downwind area based on amount of material spilled, location and weather conditions.
PROTECT FROM WATER.
Protective Equipment and Clothing Personnel protection: ... Wear positive pressure self-contained breathing apparatus. ... Wear appropriate chemical protective clothing.
Safety goggles; rubber gloves; self-contained breathing apparatus
SRP: Local exhaust ventilation should be applied wherever there is an incidence of point source emmissions or dispersion of regulated contaminants in the work area. Ventilation control of the contaminant as close to its point of generation is both the most economical and safest method to minimize personnel exposure to airborne contaminants.
Specification
colourless to light yellow liquid with a pungent
Safety Statements:9-16-26-45-1/2
9:Keep container in a well-ventilated place
16:Keep away from sources of ignition - No smoking
26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible)
1/2:Keep locked up and out of the reach of children
Disposal Methods Generators of waste (equal to or greater than 100 kg/mo) containing this contaminant, EPA hazardous waste number U006, must conform with USEPA regulations in storage, transportation, treatment and disposal of waste.
Acetyl chloride is a waste chemical stream constituent which may be subjected to ultimate disposal by controlled incineration.
A potential candidate for liquid injection incineration at a temperture range of 650 to 1,600 deg C and a residence time 0.1 to 2 seconds. A potential candidate for rotary kiln incineration at a temperature range of 820 to 1,600 deg C and residence times of seconds for liquids and gases, and hours for solids. A potential candidate for fluidized bed incineration at a temperature range of 450 to 980 deg C and residence times of seconds for liquids and gases, and longer for solids.
 
 
 
Supplier Country Business Type Minimum order quantity FOB Price  
1YR Hebei Crovell Biotech Co. Ltd China Manufacturer 1/Metric Ton 1 USD/Metric Ton Contact Supplier
1YR Hebei Crovell Biotech Co. Ltd China Manufacturer 1/Metric Ton 100 USD/Metric Ton Contact Supplier
1YR Hebei Yingong New Material Technology Co.,Ltd. China Manufacturer 1/Kilogram 200 USD/Kilogram Contact Supplier
9YRS Wuhan Fortuna Chemical Co., Ltd. China Manufacturer 200/Kilogram 4.5 USD/Kilogram Contact Supplier
2YRS HANGZHOU CLAP TECHNOLOGY CO.,LTD China Manufacturer 1kg/Kilogram 1 USD/Gram Contact Supplier
10YRS Nanjing Chemlin Chemical Co., Ltd. China Manufacturer / / Contact Supplier
1YR Hebei Crovell Biotech Co. Ltd China Manufacturer 200/Kilogram 1.5 USD/Kilogram Contact Supplier
1YR Hebei Yingong New Material Technology Co.,Ltd. China Manufacturer 10/Gram 100 USD/Kilogram Contact Supplier
9YRS Wuhan Fortuna Chemical Co., Ltd. China Manufacturer 200/Kilogram 6.5 USD/Kilogram Contact Supplier
1YR Hebei Crovell Biotech Co. Ltd China Manufacturer 1/Kilogram 1.1 USD/Kilogram Contact Supplier
1YR Hebei Yingong New Material Technology Co.,Ltd. China Manufacturer 10/Gram 50 USD/Gram Contact Supplier
9YRS Wuhan Fortuna Chemical Co., Ltd. China Manufacturer 0/ / Contact Supplier
1YR Hebei Crovell Biotech Co. Ltd China Manufacturer 1/Kilogram 0.8 USD/Kilogram Contact Supplier
HuBei Ipure Biology co.,ltd China Manufacturer 1kg/Kilogram 1 USD/Gram Contact Supplier
Hubei XinRunde Chemical Co., Ltd China Manufacturer 1/Kilogram 1 USD/Kilogram Contact Supplier
Hangzhou Utanpharma biology co,.Ltd China Trading Company 1/Kilogram 0 USD/Kilogram Contact Supplier
Nine Continent Company China Manufacturer 1/Metric Ton / Contact Supplier
Henan Sinotech Import&Export Corporation China Manufacturer 5/Metric Ton 1 USD/Metric Ton Contact Supplier
Hui Chem Company Limited China Manufacturer 1/Gram 1 USD/Gram Contact Supplier
JinTan Hengxin institute of chemistry China Manufacturer 1/Kilogram 0 USD/Kilogram Contact Supplier
HUTONG GLOBAL CO.,LTD China Manufacturer 1/Metric Ton / Contact Supplier
ETHYLENE OXIDECAS No:75-21-8
acetylCAS No:3170-69-2
AcetaldehydeCAS No:75-07-0
Ethyl acetateCAS No:141-78-6
acetic acid,chloro-hydroxy-dimethylsilaneCAS No:6904-57-0
S-TERT-BUTYL THIOACETATECAS No:999-90-6
Methanesulfenic acid chlorideCAS No:5813-48-9
Ethylium,1-oxo-,tetrafluoroborate(1-)CAS No:2261-02-1
2-AcetamidophenolCAS No:614-80-2
DIACETYLDITHIOLCAS No:592-22-3
ACETIC ACID-DCAS No:758-12-3
2,2,2-TRICHLOROETHYL ACETATECAS No:625-24-1
4'-ChloroacetophenoneCAS No:99-91-2
3-AcetylindoleCAS No:703-80-0
ACETYL IODIDECAS No:507-02-8
ACETYL FLUORIDECAS No:557-99-3