[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) structure

3D Mol Similar

[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)

: Iupac Name：cyclopenta-1,3-dien-1-yl(diphenyl)phosphane;dichloropalladium;iron(2+); CAS No.: 72287-26-4; Molecular Weight：731.7; Modify Date.: 2022-11-22 18:28; Introduction: [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) is used as a catalyst for Suzuki and Stile couplings. View more+

Request For Quotation

1. Names and Identifiers

: 1.1 Name; [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II); 1.2 Synonyms; (dppf)2PdCl2 (II)dichloromethane adduct [1,1-BIS(DICYCLOHEXYLPHOSPHINO)FERROCENE]DICHLORO PALLADIUM( II) [1,1'-Bis(diphenylphosphino)ferrocene]dichloropall [1,1-BIS(DIPHENYLPHOSPHINO)FERROCENE]DICHLOROPALLADI [1,1'-Bis(Diphenylphosphino)Ferrocene]Dichloropalladium [1,1'-bis(diphenylphosphino)ferrocene]dichloropalladium(II) complex [1,1'-bis(di-tert-butylphosphino)ferrocene]palladium(II) dichloride [bis(diphenylphosphino)ferrocene]PdCl2/ dichloromethane [palladium(II)dichloride(1,1'-bis(diphenylphosphanyl)ferrocene)] 1,1'-Bis(diphenylphosphino)ferrocene - dichloropalladium (1:1) 1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE PALLADIUM DICHLORIDE 1,1'-Bis(diphenylphosphino)ferrocene palladium(II)dichloride 1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENEDICHLOROPALLADIUM(II) 1,1-BIS(DIPHENYLPHOSPHINO)FERROCENEDICHLOROPALLADIUM(II) 1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENEPALLADIUM(II) DICHLORIDE 1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride 1,1'-Bis(diphenylphosphino)ferroceneüpalladium(II) chloride, 1:1 complex with dichloromethane dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II) complex Dichloro(1,1'-bis(diphenylphosphino)ferrocene)palladium (II) dichloromethane add dichloro[1,1'-bis(diphenylphosphino)ferrocene]palladium(II) adduct EINECS 460-040-3 MFCD00015757 palladium (II) [1,1'-bis(diphenylphosphanyl)ferrocene] dichloride PDCL2(DPPF); View all

1.3 CAS No.: 72287-26-4

1.4 CID: 71310626

1.5 EINECS(EC#): 615-748-9

1.6 Molecular Formula: C34H28Cl2FeP2Pd (isomer)

1.7 Inchi: InChI=1S/2C17H14P.2ClH.Fe.Pd/c2*1-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;;;;/h2*1-14H;2*1H;;/q2*-1;;;2*+2/p-2

1.8 InChIkey: NXQGGXCHGDYOHB-UHFFFAOYSA-L

1.9 Canonical Smiles: [CH-]1C=CC=C1P(C2=CC=CC=C2)C3=CC=CC=C3.[CH-]1C=CC=C1P(C2=CC=CC=C2)C3=CC=CC=C3.Cl[Pd]Cl.[Fe+2]

1.10 Isomers Smiles: [CH-]1C=CC=C1P(C2=CC=CC=C2)C3=CC=CC=C3.[CH-]1C=CC=C1P(C2=CC=CC=C2)C3=CC=CC=C3.Cl[Pd]Cl.[Fe+2]

2. Properties

2.1 Melting point: 275-280℃

2.1 Precise Quality: 729.94275

2.1 PSA: 27.18000

2.1 logP: 7.76790

2.1 Solubility: Soluble in dichloromethane.

2.2 Appearance: Solid

2.3 Storage: Ambient temperatures.

2.4 Chemical Properties: [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) is Red solid

2.5 Color/Form: red to very dark red

2.6 Water Solubility: Soluble in dichloromethane.

2.7 StorageTemp: Keep in dark place,Inert atmosphere,Room temperature

3. Use and Manufacturing

3.1 Usage: [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) is used as a catalyst for Suzuki and Stile couplings.

4. Safety and Handling

4.1 Symbol: GHS07

4.1 Hazard Codes: Xn

4.1 Signal Word: Warning

4.1 Risk Statements: R20/21/22

4.1 Safety Statements: S36/37

4.1 Hazard Class: IRRITANT

4.1 Hazard Declaration: H315-H319-H335

4.1 RIDADR: NONH for all modes of transport

4.1 Caution Statement: P261-P305 + P351 + P338

4.1 WGK Germany: 3

4.1 Safety: Hazard Codes:?XnXi
Risk Statements: 20/21/22-36/37/38-40?
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed
R36/37/38:Irritating to eyes, respiratory system and skin
Safety Statements: 23-24/25-26-36/37?
S23:Do not breathe vapour
S24/25:Avoid contact with skin and eyes
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
S36/37:Wear suitable protective clothing and gloves
Hazard Note: Irritant

4.2 Specification: ?[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) (CAS NO.72287-26-4) is also called as1,1-Bis(diphenylphosphino)ferrocenedichloropalladium(ii) ; 1,1'-Bis(diphenylphosphino)ferrocene palladium dichloride ; 1,1'-Bis(diphenylphosphino)ferrocenepalladium(ii) dichloride ; Pdcl2(dppf);dichloro(1,1'-bis(diphenylphosphino)ferrocene)palladium (ii) dichloromethane add ; [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium ; (ii)Dichloromethane adduct .

5. MSDS

2.Hazard identification

2.1 Classification of the substance or mixture

Skin irritation, Category 2

Eye irritation, Category 2

Specific target organ toxicity \u2013 single exposure, Category 3

2.2 GHS label elements, including precautionary statements

Pictogram(s)
Signal word	Warning
Hazard statement(s)	H315 Causes skin irritation H319 Causes serious eye irritation H335 May cause respiratory irritation
Precautionary statement(s)
Prevention	P264 Wash ... thoroughly after handling. P280 Wear protective gloves/protective clothing/eye protection/face protection. P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P271 Use only outdoors or in a well-ventilated area.
Response	P302+P352 IF ON SKIN: Wash with plenty of water/... P321 Specific treatment (see ... on this label). P332+P313 If skin irritation occurs: Get medical advice/attention. P362+P364 Take off contaminated clothing and wash it before reuse. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337+P313 If eye irritation persists: Get medical advice/attention. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P312 Call a POISON CENTER/doctor/\u2026if you feel unwell.
Storage	P403+P233 Store in a well-ventilated place. Keep container tightly closed. P405 Store locked up.
Disposal	P501 Dispose of contents/container to ...

2.3 Other hazards which do not result in classification

none

View all

6. Synthesis Route

72287-26-4Total: 10 Synthesis Route

66-27-3 54 Suppliers

590420-33-0

72287-26-4 249 Suppliers

646068-10-2

Literatures:
Organometallics, , vol. 22, # 26 p. 5468 - 5472
Yield: ~1%

12150-46-8 256 Suppliers

12317-46-3 22 Suppliers

72287-26-4 249 Suppliers

Literatures:
Colacot, Thomas J.; Qian, Hu; Cea-Olivares, Raymundo; Hernandez-Ortega, Simon Journal of Organometallic Chemistry, 2001 , vol. 637-639, p. 691 - 697
Yield: ~98%

12150-46-8 256 Suppliers

15617-18-2

72287-26-4 249 Suppliers

Literatures:
Gusev, Oleg V.; Peganova, Tat'yana A.; Kalsin, Alexander M.; Vologdin, Nikolai V.; Petrovskii, Pavel V.; Lyssenko, Konstantin A.; Tsvetkov, Aleksey V.; Beletskaya, Irina P. Organometallics, 2006 , vol. 25, # 11 p. 2750 - 2760
Yield: ~97%

View all

7. Precursor and Product

precursor:

14323-43-4

12150-46-8

75-09-2

12107-56-1

75-05-8

865-49-6

21264-30-2

15617-18-2

112220-68-5

532-31-0

124268-93-5

1042309-62-5

12317-46-3

6214-20-6

532-32-1

590420-33-0

66-27-3

View all

product :

129013-83-8

123102-32-9

8. Other Information

8.0 Uses: [1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II), is a palladium catalyst used in chemical synthesis of various compounds.Is used in preparation of Nucleosides as Ectonucleotidase inhibitors.

8.1 Chemical Properties: [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) is Red solid

8.2 Uses: [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) is used as a catalyst for Suzuki and Stile couplings.

8.3 Uses: Catalyst for C-C and C-N coupling reaction.

8.4 Usage: Used as a catalyst for Suzuki and Stile couplings.

9. Computational chemical data

Molecular Weight: 731.7g/mol
Molecular Formula: C₃₄H₂₈Cl₂FeP₂Pd
Compound Is Canonicalized: True
XLogP3-AA:
Exact Mass: 729.94275
Monoisotopic Mass: 729.94275
Complexity: 217
Rotatable Bond Count: 6
Hydrogen Bond Donor Count: 0
Hydrogen Bond Acceptor Count: 2
Topological Polar Surface Area: 0
Heavy Atom Count: 40
Defined Atom Stereocenter Count: 0
Undefined Atom Stereocenter Count: 0
Defined Bond Stereocenter Count: 0
Undefined Bond Stereocenter Count: 0
Isotope Atom Count: 0
Covalently-Bonded Unit Count: 4
CACTVS Substructure Key Fingerprint: AAADceB8AAMGAAAgAAgAAAAAAAAAAYMAAAAwYMGAAAAAAAABVAAAGAgAAAAACACAEAAwAIAAACCAACBCAAACAAAgAAAIiAAAAIgIICKAERCAIAAggAAIiAcAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAA==

10. Question & Answer

What is [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)? Aug 25 2021
[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) is a palladium complex of the iron-containing ligand dppf. It is a commercially available reagent commonly used in palladium-catalyzed coupl..

11. Recommended Suppliers

Global243SuppliersView all >>

Wuhan Fortuna Chemical Co., Ltd. Diamond member

10YRS

Products:API,fine chemical&its intermediates,biological chemistry
Tel:0086-27-59207850
Email:info@fortunachem.com

Dichloropalladium CAS 72287-26-4

Purity:99%Packing: 200kg/bag FOB
Price: 10 USD/kg
Time: 2023/09/28

Inquire

Henan Bao Enluo International Trade Co. Ltd Diamond member

1YR

Products:Pharmaceutical intermediates
Tel:173-31933971-17331933971
Email:deasea125996@gmail.com

[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) Cas 72287-26-4

Purity:99%Packing: 200kg/bag FOB
Price: 20 USD/kg
Time: 2023/09/28

Inquire

Henan Ruijiu Biotechnology Co., Ltd. Diamond member

1YR

Products:BMK,PMK,BDO,HGH, Pharmaceutical Intermediates, polypeptide, Steroid,animal feed additive,
Tel:86-371-15175993110
Email:info1@hnruijiu.cn

CAS 72287-26-4 [1, 1′ -Bis (diphenylphosphino) Ferrocene]Dichloropalladium (II)

Purity:99%Packing: 200kg/bag FOB
Price: 15 USD/kg
Time: 2023/09/27

Inquire

Qiaoxi Shengyou Chemical Co., LTD Diamond member

1YR

Products:pharmaceutical intermediates Organic raw materialsAnimal and plant extracts1.4BDO, Eutylone,4MMC, JWH ,SGT Peptide, Steroids, Benzos,Dissociatives
Tel:86-311-18931626169
Email:accountmanager1@yeah.net

1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)