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Home> Encyclopedia >   /  Agrochemicals & Pesticides  /  Insecticide  /  Organic Intermediate  /  Agrochemicals & Pesticides Products  /  Agrochemical Intermediates
Acetamiprid structure
Acetamiprid structure

Acetamiprid

Iupac Name:N-[(6-chloropyridin-3-yl)methyl]-N'-cyano-N-methylethanimidamide
CAS No.:135410-20-7
Molecular Weight:222.67400
Introduction: 1. Acetamiprid belongs to the same series with imidacloprid. But its nsecticidal spectruma is broader than imidacloprid. It mainly has a better effect on cucumbers aphids, apples aphids, citrus aphids and tobacco aphids. Since the mechanism of acetamiprid is unique, it have a good effect on pests that can cause resistance to organophosphorus, carbamates and pyrethroids pesticides.2. Efficient, broad-spectrum chlorinated insecticides.
1. Names and Identifiers
1.1 Name
Acetamiprid
1.2 Synonyms

(1E)-N-[(6-Chloro-3-pyridinyl)methyl]-N'-cyano-N-methylethanimidamide (E)-N1-[(6-chloro-3-pyridyl)methyl]-N2-cyano-N1-methylacetamidine acetamiprid (iso) ADA 06200 Ethanimidamide, N-(6-chloro-3-pyridinyl)methyl-N-cyano-N-methyl-, (1E)- NFK 17 Piorun

1.3 CAS No.
135410-20-7
1.4 CID
213021
1.5 EINECS(EC#)
603-921-1
1.6 Molecular Formula
C10H11ClN4 (isomer)
1.7 Inchi
InChI=1S/C10H11ClN4/c1-8(14-7-12)15(2)6-9-3-4-10(11)13-5-9/h3-5H,6H2,1-2H3
1.8 InChkey
WCXDHFDTOYPNIE-UHFFFAOYSA-N
1.9 Canonical Smiles
CC(=NC#N)N(C)CC1=CN=C(C=C1)Cl
1.10 Isomers Smiles
CC(=NC#N)N(C)CC1=CN=C(C=C1)Cl
2. Properties
3.1 Density
1.17
3.2 Melting Point
101-103ºC
3.3 Boiling Point
352.4ºC at 760 mmHg
3.4 Vapour
3.85E-05mmHg at 25°C
3.5 Refractive Index
1.57
3.6 Flash Point
166.9ºC
3.7 Appearance
white powder
3.8 Chemical Properties
Pale Yellow Solid
3.9 Color/Form
White crystals
White fine powder
3.10 Odor
Odorless
3.11 pKa
-0.44±0.10(Predicted)
3.12 Solubility
4200 mg l-1 (25 °C)
3.13 StorageTemp
0-6°C
3.14 Water Solubility
In water, 4.25X10+3 mg/L at 25 deg C
Soluble in acetone, methanol, ethanol, dichloromethane, chloroform, acetonitrile, and tetrahydrofuran
In water at 25 deg C: 3.48X10+3 mg/L @ pH5; 2.95X10+3 mg/L @ pH 7, 3.96X10+3 mg/L @ pH 9
3. Use and Manufacturing
4.1 Agricultural Uses
Insecticide: This class of pesticides are chemically related to nicotine and used on corn and soybean seeds and are used to control sucking and chewing insects, and soil insects includingaphids, beetles, fruit moth, leaf-hoppers and-miners, thrips,whiteflies [83] . Also used to control fleas on domestic animals.
4.2 Definition
ChEBI: The (E)-stereoisomer of acetamiprid.
4.3 Usage
1. Acetamiprid belongs to the same series with imidacloprid. But its nsecticidal spectruma is broader than imidacloprid. It mainly has a better effect on cucumbers aphids, apples aphids, citrus aphids and tobacco aphids. Since the mechanism of acetamiprid is unique, it have a good effect on pests that can cause resistance to organophosphorus, carbamates and pyrethroids pesticides.2. Efficient, broad-spectrum chlorinated insecticides.
4. Safety and Handling
5.1 Hazard Codes
T
5.1 Risk Statements
R23/25; R57
5.2 Safety Statements
S45
5.3 HazardClass
6.1(b)
5.4 PackingGroup
III
5.5 Transport
UN 2811
5.6 DisposalMethods
SRP: The most favorable course of action is to use an alternative chemical product with less inherent propensity for occupational exposure or environmental contamination. Recycle any unused portion of the material for its approved use or return it to the manufacturer or supplier. Ultimate disposal of the chemical must consider: the material's impact on air quality; potential migration in soil or water; effects on animal, aquatic, and plant life; and conformance with environmental and public health regulations.
5.7 Formulations/Preparations
Trade names: Cezar, Hekplan, Mospildate, Shark, Tenaz, Vapcomore, Mortal, Profil, Assail, Intruder, Tri-star.
Soluble powder, granule.
Types of Formulations: 99.5% technical product, 70% WP end-use product, 70% /water soluble packets/ (WSP) end use product, 0.006% /ready to use/ (RTU) end use product.
5.8 Octanol/Water Partition Coefficient
log Kow = 0.80 at 25 deg C
5. MSDS

2.Hazard identification

2.1 Classification of the substance or mixture

Acute toxicity - Oral, Category 4

Hazardous to the aquatic environment, long-term (Chronic) - Category Chronic 3

2.2 GHS label elements, including precautionary statements

Pictogram(s)
Signal word

Warning

Hazard statement(s)

H302 Harmful if swallowed

H412 Harmful to aquatic life with long lasting effects

Precautionary statement(s)
Prevention

P264 Wash ... thoroughly after handling.

P270 Do not eat, drink or smoke when using this product.

P273 Avoid release to the environment.

Response

P301+P312 IF SWALLOWED: Call a POISON CENTER/doctor/\u2026if you feel unwell.

P330 Rinse mouth.

Storage

none

Disposal

P501 Dispose of contents/container to ...

2.3 Other hazards which do not result in classification

none

7. Computational chemical data
  • Molecular Weight:222.67400g/mol
  • Molecular Formula:C10H11ClN4
  • Compound Is Canonicalized:True
  • XLogP3-AA:1.4
  • Exact Mass:222.0672241
  • Monoisotopic Mass:222.0672241
  • Complexity:280
  • Rotatable Bond Count:3
  • Hydrogen Bond Donor Count:0
  • Hydrogen Bond Acceptor Count:3
  • Topological Polar Surface Area:52.3
  • Heavy Atom Count:15
  • Defined Atom Stereocenter Count:0
  • Undefined Atom Stereocenter Count:0
  • Defined Bond Stereocenter Count:0
  • Undefined Bond Stereocenter Count:0
  • Isotope Atom Count:0
  • Covalently-Bonded Unit Count:1
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