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Home> Encyclopedia >   /  Halide ( Except Chloride )  /  Chloride  /  Other Inorganic Chemicals  /  Pharmaceutical Intermediates  /  Inorganic Salts
Barium chloride structure
Barium chloride structure

Barium chloride

Iupac Name:barium(2+) dichloride
CAS No.:10361-37-2
Molecular Weight:208.233
Introduction: Barium dichloride is a white solid, odorless, hygroscopic chemical substance. Bariumdichloride is used in the manufacture of pigments, in the manufacture of other bariumsalts and in fireworks to give a bright green color. It is one of the most common watersolublesalts of barium. Like other barium salts, it is toxic and imparts a yellow-green colorationto a flame. Barium chloride has wide application in the laboratory. View more+
1. Names and Identifiers
1.1 Name
Barium chloride
1.2 Synonyms

Ba 0108E Barium chloride (BaCl2) Barium chloride,anhydrous Barium dichloride NSC 146181

1.3 CAS No.
10361-37-2
1.4 CID
25204
1.5 EINECS(EC#)
233-788-1
1.6 Molecular Formula
BaCl2 (isomer)
1.7 Inchi
InChI=1S/Ba.2ClH/h;2*1H/q+2;;/p-2
1.8 InChkey
WDIHJSXYQDMJHN-UHFFFAOYSA-L
1.9 Canonical Smiles
[Cl-].[Cl-].[Ba+2]
1.10 Isomers Smiles
[Cl-].[Cl-].[Ba+2]
2. Properties
3.1 Density
3.856
3.1 Melting point
960℃
3.1 Boiling point
1560℃
3.1 Flash Point
°C
3.1 Vapour pressure
Low (NIOSH, 2016)
3.1 Precise Quality
207.84300
3.1 PSA
0.00000
3.1 logP
1.37900
3.1 Solubility
H2O: soluble
3.2 Appearance
White Crystalline Powder
3.3 Chemical Properties
It is colorless monoclinic crystal. (Α type) it is soluble in water, slightly soluble in hydrochloric acid, nitric acid, very slightly soluble in alcohol.
3.4 Color/Form
White orthorhombic crystals
White solid.
3.5 Decomposition
When heated to decomp it emits toxic fumes of /chlorine./
3.6 Odor
Odorless
3.7 PH
5-8 (50g/l, H2O, 20℃)
3.8 Water Solubility
Soluble in water
3.9 Stability
Stable.
3.10 StorageTemp
2-8°C
3. Use and Manufacturing
4.1 Fire Hazard
Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. Some are oxidizers and may ignite combustibles (wood, paper, oil, clothing, etc.). Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated.
4.2 General Description
Any of a variety of substances that contain barium. Most are whitish colored crystalline solids. They tend to be soluble in water and denser than water. They may be toxic by inhalation or possibly skin absorption. They are often used to make other chemicals.
4.3 Safety Profile
A poison by ingestion,subcutaneous, intravenous, andintraperitoneal routes. Inhalation absorptionof barium chloride equals 60-80%; oralabsorption equals 10-30%. Experimentalreproductive effects. Mutation datareported. See also BARIUMCOMPOUNDS (soluble). When heated todecomposition it emits toxic fumes of Cl-. Barium chloride Preparation Products And Raw materials Preparation Products
4.4 Storage
Ambient temperatures.
4.5 Usage
(1) Barium chloride is mainly used for heat treatment of metals, barium salt manufacturing, electronic instruments, and used as water softener. (2) It can be used as dehydrating agent and analysis reagents, it is used for machining heat treatment Jing, see other barium chloride dihydrate. (3) Calibration instruments and devices, evaluation methodology, quality assurance/quality control.
4. Safety and Handling
5.1 Hazard Codes
T
5.1 Risk Statements
R20;R25
5.1 Safety Statements
S45
5.1 Packing Group
III
5.1 Other Preventative Measures
If employees' clothing has had any possibility of being contaminated with barium chloride ... or liq containing ... /this/ cmpd, employees should change into uncontaminated clothing before leaving the work premises. ... Clothing contaminated with barium chloride ... should be placed in closed containers for storage until it can be discarded or until provision is made for the removal of contaminant from the clothing. If the clothing is to be laundered or otherwise cleaned to remove the contaminant, the person performing the operation should be informed of contaminant's hazardous properties. ... Non-impervious clothing which becomes contaminated with barium chloride ... should be removed promptly and not reworn until the contaminant is removed from the clothing.
Skin that becomes contaminated with barium chloride ... should be promptly washed or showered to remove any contaminant.
Eating and smoking should not be permitted in areas where solid barium chloride ... or liq containing ... /this/ cmpd are handled, processed, or stored. Employees who handle barium chloride ... or liq containing ... /this/ cmpd should wash their hands thoroughly before eating, smoking, or using toilet facilities.
SRP: Contaminated protective clothing should be segregated in such a manner so that there is no direct personal contact by personnel who handle, dispose, or clean the clothing. Quality assurance to ascertain the completeness of the cleaning procedures should be implemented before the decontaminated protective clothing is returned for reuse by the workers. All contaminated clothing should not be taken home at end of shift, but should remain at employee's place of work for cleaning.
SRP: The scientific literature for the use of contact lenses in industry is conflicting. The benefit or detrimental effects of wearing contact lenses depend not only upon the substance, but also on factors including the form of the substance, characteristics and duration of the exposure, the uses of other eye protection equipment, and the hygiene of the lenses. However, there may be individual substances whose irritating or corrosive properties are such that the wearing of contact lenses would be harmful to the eye. In those specific cases, contact lenses should not be worn. In any event, the usual eye protection equipment should be worn even when contact lenses are in place.
The worker should immediately wash the skin when it becomes contaminated.
Work clothing that becomes wet or significantly contaminated should be removed or replaced.
Workers whose clothing may have become contaminated should change into uncontaminated clothing before leaving the work premises.
If material not on fire and not involved in fire: Keep sparks, flames, and other sources of ignition away. Keep material out of water sources and sewers. Build dikes to contain flow as necessary. Do not use water.
Personnel protection: Avoid breathing vapors. Keep upwind. ... Avoid bodily contact with the material. ... Do not handle broken packages unless wearing appropriate personal protective equipment.
5.2 Hazard Class
6.1
5.2 DisposalMethods
SRP: At the time of review, criteria for land treatment or burial (sanitary landfill) disposal practices are subject to significant revision. Prior to implementing land disposal of waste residue (including waste sludge), consult with environmental regulatory agencies for guidance on acceptable disposal practices.
5.3 RIDADR
UN 1564
5.3 Fire Fighting Procedures
If material on fire or involved in fire: Extinguish fire using agent suitable for type of surrounding fire. (Material itself does not burn or burns with difficulty.) Cool all affected containers with flooding quantities of water. Apply water from as far a distance as possible. Use foam, dry chemical, or carbon dioxide. Keep run-off water out of sewers and water sources.
5.4 Formulations/Preparations
ACS reagent grade
99.999% purity grade; -60 mesh, 99.9% purity grade; ACS reagent crystal grade
Grade: Technical (crystals or powdered), 99% crystals, powdered, chemically pure
5.5 WGK Germany
1
5.5 RTECS
CQ8750000
5.5 Protective Equipment and Clothing
Employees should be provided with and required to use impervious clothing, gloves, face shields (eight inch minimum), and other appropriate protective clothing necessary to prevent repeated or prolonged skin contact with barium chloride ... or liq containing ... /this/ cmpd. ... Employees should be provided with and required to use dust and splash proof safety goggles where barium chloride ... or liq containing ... /this/ cmpd may contact the eyes.
Wear appropriate personal protective clothing to prevent skin contact.
Wear appropriate eye protection to prevent eye contact.
Recommendations for respirator selection. Max concn for use: 5 mg/cu m. Respirator Class(es): Any dust and mist respirator except single-use and quarter-mask respirators. Any supplied-air respirator.
Recommendations for respirator selection. Max concn for use: 12.5 mg/cu m. Respirator Class(es): Any supplied-air respirator operated in a continuous flow mode. Any powered, air-purifying respirator with a dust and mist filter.
Recommendations for respirator selection. Max concn for use: 25 mg/cu m. Respirator Class(es): Any air-purifying, full-facepiece respirator with a high-efficiency particulate filter. Any supplied-air respirator that has a tight-fitting facepiece and is operated in a continuous-flow mode. Any powered, air-purifying respirator with a tight-fitting facepiece and a high-efficiency particulate filter. Any self-contained breathing apparatus with a full facepiece. Any supplied-air respirator with a full facepiece.
Recommendations for respirator selection. Max concn for use: 50 mg/cu m. Respirator Class(es): Any supplied-air respirator that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode.
Recommendations for respirator selection. Condition: Emergency or planned entry into unknown concn or IDLH conditions: Respirator Class(es): Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode. Any supplied-air respirator that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode in combination with an auxiliary self-contained breathing apparatus operated in pressure-demand or other positive-pressure mode.
Recommendations for respirator selection. Condition: Escape from suddenly occurring respiratory hazards: Respirator Class(es): Any air-purifying, full-facepiece respirator with a high-efficiency particulate filter. Any appropriate escape-type, self-contained breathing apparatus.
5.6 Reactivities and Incompatibilities
BROMINE TRIFLUORIDE RAPIDLY ATTACKS BARIUM CHLORIDE.
Acids, oxidizers.
Furan-2-percarboxylic acid explodes when heated to 30 to 40 deg C, or at room temperature upon addition of barium chloride.
5.7 Report

Reported in EPA TSCA Inventory.?Barium chloride (CAS NO.10361-37-2) and its compounds are on the Community Right-To-Know List. EPA Genetic Toxicology Program.

5.8 Safety

Hazard Codes?of Barium chloride (CAS NO.10361-37-2):?ToxicT,IrritantXi,Xn
Risk Statements: 22-25-20-36/37/38?
R22: Harmful if swallowed.?
R25: Toxic if swallowed.?
R20: Harmful by inhalation.?
R36/37/38: Irritating to eyes, respiratory system and skin.
Safety Statements: 45-26-36/37/39?
S45: In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)?
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.?
S36/37/39: Wear suitable protective clothing, gloves and eye/face protection.
RIDADR: UN 3264 8/PG 3
WGK Germany: 1
RTECS: CQ8750000
HazardClass: 6.1
PackingGroup: III
A poison by ingestion, subcutaneous, intravenous, and intraperitoneal routes. Inhalation absorption of barium chloride equals 60–80%; oral absorption equals 10–30%. Experimental reproductive effects. Mutation data reported. See also BARIUM COMPOUNDS (soluble). When heated to decomposition it emits toxic fumes of Cl?.

5.9 Sensitive
Hygroscopic
5.10 Toxicity

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
cat LDLo intravenous 40mg/kg (40mg/kg) ? Environmental Quality and Safety, Supplement. Vol. 1, Pg. 1, 1975.
cat LDLo subcutaneous 18mg/kg (18mg/kg) ? Environmental Quality and Safety, Supplement. Vol. 1, Pg. 1, 1975.
dog LD50 unreported 90mg/kg (90mg/kg) ? New Zealand Veterinary Journal. Vol. 47, Pg. 150, 1999.
dog LDLo oral 90mg/kg (90mg/kg) ? "Drug Dosages in Laboratory Animals - A Handbook," Rev. ed., Barnes, C.D., and L.G. Eltherington, Berkeley, Univ. of California Press, 1973Vol. -, Pg. 53, 1973.
dog LDLo subcutaneous 10mg/kg (10mg/kg) ? Environmental Quality and Safety, Supplement. Vol. 1, Pg. 1, 1975.
domestic animals - goat/sheep LDLo parenteral 7mg/kg (7mg/kg) PERIPHERAL NERVE AND SENSATION: SPASTIC PARALYSIS WITH OR WITHOUT SENSORY CHANGE

BEHAVIORAL: MUSCLE WEAKNESS
New Zealand Veterinary Journal. Vol. 47, Pg. 150, 1999.
frog LDLo subcutaneous 910mg/kg (910mg/kg) ? "Abdernalden's Handbuch der Biologischen Arbeitsmethoden." Vol. 4, Pg. 1289, 1935.
guinea pig LD50 oral 76mg/kg (76mg/kg) ? Food Research. Vol. 7, Pg. 313, 1942.
guinea pig LDLo subcutaneous 55mg/kg (55mg/kg) ? "Drug Dosages in Laboratory Animals - A Handbook," Rev. ed., Barnes, C.D., and L.G. Eltherington, Berkeley, Univ. of California Press, 1973Vol. -, Pg. 53, 1973.
horse/donkey LD50 unreported 800mg/kg (800mg/kg) ? New Zealand Veterinary Journal. Vol. 47, Pg. 150, 1999.
mammal (species unspecified) LD50 oral 398mg/kg (398mg/kg) AUTONOMIC NERVOUS SYSTEM: OTHER (DIRECT) PARASYMPATHOMIMETIC

BEHAVIORAL: MUSCLE WEAKNESS

GASTROINTESTINAL: NAUSEA OR VOMITING
Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 28(6), Pg. 45, 1984.
mouse LD50 intraperitoneal 39mg/kg (39mg/kg) ? Farmakologiya i Toksikologiya Vol. 10, Pg. 107, 1975.
mouse LD50 intravenous 12mg/kg (12mg/kg) ? Toxicology and Applied Pharmacology. Vol. 22, Pg. 150, 1972.
mouse LD50 unreported 7mg/kg (7mg/kg) ? New Zealand Veterinary Journal. Vol. 47, Pg. 150, 1999.
mouse LDLo oral 70mg/kg (70mg/kg) ? Environmental Quality and Safety, Supplement. Vol. 1, Pg. 1, 1975.
mouse LDLo subcutaneous 10mg/kg (10mg/kg) ? National Technical Information Service. Vol. AEC-TR-6710,
rabbit LD50 unreported 170mg/kg (170mg/kg) ? New Zealand Veterinary Journal. Vol. 47, Pg. 150, 1999.
rabbit LDLo intravenous 15mg/kg (15mg/kg) ? Environmental Quality and Safety, Supplement. Vol. 1, Pg. 1, 1975.
rabbit LDLo oral 170mg/kg (170mg/kg) ? "Drug Dosages in Laboratory Animals - A Handbook," Rev. ed., Barnes, C.D., and L.G. Eltherington, Berkeley, Univ. of California Press, 1973Vol. -, Pg. 53, 1973.
rabbit LDLo parenteral 20mg/kg (20mg/kg) GASTROINTESTINAL: "HYPERMOTILITY, DIARRHEA"

KIDNEY, URETER, AND BLADDER: URINE VOLUME INCREASED
Medicina del Lavoro. Industrial Medicine. Vol. 30, Pg. 44, 1939.
rabbit LDLo subcutaneous 40mg/kg (40mg/kg) ? Environmental Quality and Safety, Supplement. Vol. 1, Pg. 1, 1975.
rat LD50 oral 118mg/kg (118mg/kg) ? Food Research. Vol. 7, Pg. 313, 1942.
rat LD50 subcutaneous 178mg/kg (178mg/kg) ? "Drug Dosages in Laboratory Animals - A Handbook," Rev. ed., Barnes, C.D., and L.G. Eltherington, Berkeley, Univ. of California Press, 1973Vol. -, Pg. 53, 1973.
rat LD50 unreported 150mg/kg (150mg/kg) ? New Zealand Veterinary Journal. Vol. 47, Pg. 150, 1999.
rat LDLo intravenous 20mg/kg (20mg/kg) BEHAVIORAL: MUSCLE CONTRACTION OR SPASTICITY)

LUNGS, THORAX, OR RESPIRATION: OTHER CHANGES
Journal of Laboratory and Clinical Medicine. Vol. 15, Pg. 35, 1929.

5. MSDS

2.Hazard identification

2.1 Classification of the substance or mixture

Acute toxicity - Oral, Category 3

Acute toxicity - Inhalation, Category 4

2.2 GHS label elements, including precautionary statements

Pictogram(s)
Signal word

Danger

Hazard statement(s)

H301 Toxic if swallowed

H332 Harmful if inhaled

Precautionary statement(s)
Prevention

P264 Wash ... thoroughly after handling.

P270 Do not eat, drink or smoke when using this product.

P261 Avoid breathing dust/fume/gas/mist/vapours/spray.

P271 Use only outdoors or in a well-ventilated area.

Response

P301+P310 IF SWALLOWED: Immediately call a POISON CENTER/doctor/\u2026

P321 Specific treatment (see ... on this label).

P330 Rinse mouth.

P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.

P312 Call a POISON CENTER/doctor/\u2026if you feel unwell.

Storage

P405 Store locked up.

Disposal

P501 Dispose of contents/container to ...

2.3 Other hazards which do not result in classification

none

6. Other Information
6.0 Usage
Barium chloride is used in manufacture of pigments, fire works, other barium salts, fireworks , hardening of steel, heat treatment salts, purification of brine solution in caustic chlorine plants, lubrication oil additive, textile dye, pigments, white leather, aluminum refining, boiling water treatment and porcelain enamels for sheet steel. It is also used to remove sulfate ion in some electrolytic plants, caustic soda, magnesium metal or sodium metal. It is also used as a component in a flux used to prevent oxidation of molten magnesium.
6.1 Usage
In industry, barium chloride is mainly used in the purification of brine solution in caustic chlorine plants and also in the manufacture of heat treatment salts, case hardening of steel, in the manufacture of pigments, and in the manufacture of other barium salts. BaCl2 is also used in fireworks to give a bright green color. It is commonly used as a test for sulfate ion.
6.2 Merck
14,971
6.3 Chemical properties
It is colorless monoclinic crystal. (Α type) it is soluble in water, slightly soluble in hydrochloric acid, nitric acid, very slightly soluble in alcohol.
6.4 Uses
(1) Barium chloride is mainly used for heat treatment of metals, barium salt manufacturing, electronic instruments, and used as water softener.
(2) It can be used as dehydrating agent and analysis reagents, it is used for machining heat treatment Jing, see other barium chloride dihydrate.
(3) Calibration instruments and devices, evaluation methodology, quality assurance/quality control.
6.5 Hazardous characteristics
Barium chloride is noncombustible. It is highly toxic. When contacts boron trifluoride, violent reaction can occur. Swallowed or inhaled can cause poisoning, it is mainly through the respiratory tract and digestive tract to invade the human body, it will cause drooling and burning esophagus, stomach pain, cramps, nausea, vomiting, diarrhea, high blood pressure, no law firm pulse, cramps, a lot of cold sweat, weak muscle strength, gait, vision and speech problems, difficulty breathing, dizziness, tinnitus, consciousness usually clear. In severe cases, it can cause sudden death. Barium ions can cause muscle stimulant, then gradually transforms into paralysis. Rat oral LD50150mg/kg, mouse peritoneal LD5054mg/kg, rats are intravenously LD5020mg/kg, orally in dog LD5090mg/kg.
6.6 First-aid measure
When skin contacts it, rinsing with water, then thoroughly washing with soap. When eye contacts, flushing with water. So that patients inhaled dust should leave from the contaminated area, move to fresh air place, rest and keep warm, if necessary, artificial respiration should be taken, seek medical attention. When swallowed, immediately rinse the mouth, gastric lavage should be taken with warm water or 5% sodium hydrosulfite for catharsis. Even swallows more than 6h, gastric lavage is also necessary. Intravenous infusion is slowly taken with 1% sodium sulfate of 500ml~1 000ml, intravenous injection can also be taken with 10% sodium thiosulfate of 10ml~20ml. Potassium and symptomatic treatment should be carried out.
Soluble barium salts of barium chloride is rapidly absorbed, so the symptoms develop rapidly, at any time cardiac arrest or respiratory muscle paralysis can cause death. Therefore, first aid must be against the clock.
6.7 Toxicity
See barium chloride dihydrate.
6.8 Hazards & Safety Information
Category: toxic substances.
Toxicity grading: highly toxic.
Acute oral toxicity-rat LD50: 118 mg/kg; Oral-Mouse LD50: 150 mg/kg
Flammability hazard characteristics: It is non-combustible; fire and toxic chloride fumes containing barium compounds.
Storage characteristics: Treasury ventilation low-temperature drying; it should be stored separately with food additives.
Extinguishing agent: Water, carbon dioxide, dry, sandy soil.
Professional Standards: TLV-TWA 0.5 mg (barium)/cubic meter; STEL 1.5 mg (barium)/cubic meter.
6.9 Description
Barium dichloride is a white solid, odorless, hygroscopic chemical substance. Barium dichloride is used in the manufacture of pigments, in the manufacture of other barium salts and in fireworks to give a bright green color. It is one of the most common watersoluble salts of barium. Like other barium salts, it is toxic and imparts a yellow-green coloration to a flame. Barium chloride has wide application in the laboratory.
6.10 Chemical Properties
Barium chloride,BaCI2, is a colorless toxic salt with a melting point of 963°C. It is soluble in water. Barium chloride is used in metal surface treatment and as a rat poison.
6.11 Uses
Chemicals (artificial barium sulfate, other bar- ium salts), reagents, lubrication oil additives, boiler compounds, textile dyeing, pigments, manufacture of white leather.
6.12 Definition
ChEBI: The inorganic dichloride salt of barium.
6.13 General Description
Any of a variety of substances that contain barium. Most are whitish colored crystalline solids. They tend to be soluble in water and denser than water. They may be toxic by inhalation or possibly skin absorption. They are often used to make other chemicals.
6.14 Air & Water Reactions
Water soluble.
6.15 Reactivity Profile
BARIUM CHLORIDE may react violently with BrF3 and 2-furan percarboxylic acid in its anhydrous form.
6.16 Hazard
Ingestion of 0.8 g may be fatal.
6.17 Fire Hazard
Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. Some are oxidizers and may ignite combustibles (wood, paper, oil, clothing, etc.). Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated.
6.18 Safety Profile
A poison by ingestion, subcutaneous, intravenous, and intraperitoneal routes. Inhalation absorption of barium chloride equals 60-80%; oral absorption equals 10-30%. Experimental reproductive effects. Mutation data reported. See also BARIUM COMPOUNDS (soluble). When heated to decomposition it emits toxic fumes of Cl-.
7. Computational chemical data
  • Molecular Weight:208.233g/mol
  • Molecular Formula:BaCl2
  • Compound Is Canonicalized:True
  • XLogP3-AA:
  • Exact Mass:207.842952
  • Monoisotopic Mass:207.842952
  • Complexity:2.8
  • Rotatable Bond Count:0
  • Hydrogen Bond Donor Count:0
  • Hydrogen Bond Acceptor Count:2
  • Topological Polar Surface Area:0
  • Heavy Atom Count:3
  • Defined Atom Stereocenter Count:0
  • Undefined Atom Stereocenter Count:0
  • Defined Bond Stereocenter Count:0
  • Undefined Bond Stereocenter Count:0
  • Isotope Atom Count:0
  • Covalently-Bonded Unit Count:3
8. Question & Answer
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