D-Plenylglycinol

Iupac Name：(2R)-2-amino-2-phenylethanol

Molecular Weight：137.182

Modify Date.: 2023-03-06 10:29

Introduction: As a chiral arylalkylamine used as organocatalysts, D-Plenylglycinol can be used in the synthesis and chiral recognition properties of novel fluorescent chemosensors for amino acid. D-Plenylglycinol Preparation Products And Raw materials Preparation Products View more+

Request For Quotation

1. Names and Identifiers

1.1 Name: D-Plenylglycinol
1.2 Synonyms: (-)-(R)-β-Aminobenzeneethanol (-)-2-Amino-2-phenylethanol (-)-D-α-Phenylglycinol (-)-Phenylglycinol (1R)-2-Hydroxy-1-phenylethanaminium (2R)-2-Amino-2-phenyl-1-ethanol (2R)-2-Amino-2-phenylethan-1-ol (2R)-2-Amino-2-phenylethanol (R)-(-)-2-Amino-2-phenylethanol (R)-(-)-2-Phenyl-2-aminoethanol (R)-(-)-2-Phenylglycinol (R)-(-)-Phenylglycinol (R)-2-Amino-2-phenylethan-1-ol (R)-2-Amino-2-phenylethanol (R)-2-Phenylglycinol (R)-Phenylglycinol (R)-α-Phenylglycinol (βR)-β-Aminobenzeneethanol [(R)-2-Hydroxy-1-phenylethyl]amine BENZENEETHANOL, B-AMINO-, (BR)- Benzeneethanol, β-amino-, (R)- Benzeneethanol, β-amino-, (βR)- Benzenemethanaminium, α-(hydroxymethyl)-, (αR)- D-(-)-2-Amino-2-phenylethanol D-(-)2-AMINO-2-PHENYLETHANOL D(-)-ALPHA-PHENYLGLYCINOL D-(-)-A-PHENYLGLYCINOL D-(-)-α-Phenylglycinol D-PHENYLGLYCINOL D-PHG-OL D-α-Phenylglycinol H-D-PHG-OL

1.3 CAS No.: 56613-80-0

1.4 CID: 2724025

1.5 EINECS(EC#): 260-287-5

1.6 Molecular Formula: C8H11NO (isomer)

1.7 Inchi: InChI=1S/C8H11NO/c9-8(6-10)7-4-2-1-3-5-7/h1-5,8,10H,6,9H2/t8-/m0/s1

1.8 InChkey: IJXJGQCXFSSHNL-QMMMGPOBSA-N

1.9 Canonical Smiles: C1=CC=C(C=C1)C(CO)N

1.10 Isomers Smiles: C1=CC=C(C=C1)[C@H](CO)N

2. Properties

2.1 Density: 1.104

2.1 Melting point: 75-77℃

2.1 Boiling point: 261 °C at 760 mmHg

2.1 Refractive index: -29.5 ° (C=1, EtOH)

2.1 Flash Point: 125.3 °C

2.1 Precise Quality: 137.08400

2.1 PSA: 46.25000

2.1 logP: 1.37900

2.1 Appearance: white to light yellow crystal powde

2.2 Storage: Air Sensitive. Store under Nitrogen. Ambient temperatures.

2.3 Chemical Properties: white to light yellow crystal powde

2.4 Color/Form: White to Yellow Solid

2.5 pKa: 12.51±0.10(Predicted)

2.6 Water Solubility: Slightly soluble in water.

2.7 Stability: Stable under normal temperatures and pressures.

2.8 StorageTemp: Store at 0-5°C

3. Use and Manufacturing

3.1 Usage: As a chiral arylalkylamine used as organocatalysts, D-Plenylglycinol can be used in the synthesis and chiral recognition properties of novel fluorescent chemosensors for amino acid. D-Plenylglycinol Preparation Products And Raw materials Preparation Products

4. Safety and Handling

4.1 Hazard Codes: T; C

4.1 Risk Statements: R34

4.1 Safety Statements: S24/25

4.1 RIDADR: OTH

4.1 WGK Germany: 3

4.1 Safety: Hazard Codes:?C,T
Risk Statements: 34-36/37/38-23/24/25
R34:Causes burns.?
R36/37/38:Irritating to eyes, respiratory system and skin.?
R23/24/25:Toxic by inhalation, in contact with skin and if swallowed.
Safety Statements: 22-24/25-45-36/37/39-26
S22:Do not breathe dust.?
S24/25:Avoid contact with skin and eyes.?
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)?
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection.?
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
WGK Germany: 3
F: 2-10
HS Code: 29221980

4.2 Sensitive: Air Sensitive

4.3 Specification: ?D-Plenylglycinol , with CAS number of 56613-80-0, can be called Benzeneethanol,b-amino-, (R)- ; (-)-(R)-b-Aminobenzeneethanol ; (2R)-2-Amino-2-phenyl-1-ethanol ; (R)-(-)-2-Amino-2-phenylethanol ; (R)-Phenylglycinol ; (bR)-b-Aminobenzeneethanol ; D-(-)-2-Amino-2-phenylethanol ; [(R)-2-Hydroxy-1-phenylethyl]amine . It is a?white to light yellow crystal powde.

5. MSDS

2.Hazard identification

2.1 Classification of the substance or mixture

Skin irritation, Category 2

Eye irritation, Category 2

Specific target organ toxicity \u2013 single exposure, Category 3

2.2 GHS label elements, including precautionary statements

Pictogram(s)
Signal word	Warning
Hazard statement(s)	H315 Causes skin irritation H319 Causes serious eye irritation H335 May cause respiratory irritation
Precautionary statement(s)
Prevention	P264 Wash ... thoroughly after handling. P280 Wear protective gloves/protective clothing/eye protection/face protection. P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P271 Use only outdoors or in a well-ventilated area.
Response	P302+P352 IF ON SKIN: Wash with plenty of water/... P321 Specific treatment (see ... on this label). P332+P313 If skin irritation occurs: Get medical advice/attention. P362+P364 Take off contaminated clothing and wash it before reuse. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337+P313 If eye irritation persists: Get medical advice/attention. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P312 Call a POISON CENTER/doctor/\u2026if you feel unwell.
Storage	P403+P233 Store in a well-ventilated place. Keep container tightly closed. P405 Store locked up.
Disposal	P501 Dispose of contents/container to ...

2.3 Other hazards which do not result in classification

none

View all

6. Synthesis Route

56613-80-0Total: 44 Synthesis Route

875-74-1 240 Suppliers

56613-80-0 337 Suppliers

Literatures:
Shi, Xin; He, Wei; Li, Hua; Zhang, Xu; Zhang, Shengyong Tetrahedron Letters, 2011 , vol. 52, # 25 p. 3204 - 3207
Yield: ~92%

591-51-5 36 Suppliers

56613-80-0 337 Suppliers

Literatures:
Tetrahedron Letters, , vol. 30, # 34 p. 4539 - 4542
Yield: null

103-01-5 105 Suppliers

56613-80-0 337 Suppliers

Literatures:
US6399643 B1, ;
Yield: null

View all

7. Precursor and Product

precursor:

20989-17-7

6097-58-1

875-74-1

20780-53-4

25779-13-9

4427-92-3

2935-35-5

78761-26-9

126568-42-1

67341-01-9

100-46-9

591-51-5

126568-41-0

14231-57-3

87319-83-3

39251-40-6

87319-82-2

24461-61-8

582-24-1

87319-85-5

87319-84-4

103-01-5

3082-69-7

126003-97-2

View all

product :

88056-98-8

110199-18-3

3886-69-9

84773-28-4

875-74-1

141096-35-7

174636-94-3

121269-46-3

64715-85-1

130332-27-3

33911-77-2

78761-26-9

194156-25-7

121269-45-2

88056-94-4

1499-00-9

90319-52-1

88056-92-2

128249-70-7

112211-92-4

119878-90-9

138713-44-7

137284-11-8

View all

8. Other Information

8.0 Usage: Amino alcohol used to prepare a chiral imine or oxazolidine from ethyl trifluoropyruvate. These intermediates were then employed in a synthesis of both enantiomers of α-trifluoromethylproline. Chiral β-amino alcohol used as a synthetic building block.

9. Computational chemical data

Molecular Weight: 137.182g/mol
Molecular Formula: C₈H₁₁NO
Compound Is Canonicalized: True
XLogP3-AA: 0.1
Exact Mass: 137.084063974
Monoisotopic Mass: 137.084063974
Complexity: 89.3
Rotatable Bond Count: 2
Hydrogen Bond Donor Count: 2
Hydrogen Bond Acceptor Count: 2
Topological Polar Surface Area: 46.2
Heavy Atom Count: 10
Defined Atom Stereocenter Count: 1
Undefined Atom Stereocenter Count: 0
Defined Bond Stereocenter Count: 0
Undefined Bond Stereocenter Count: 0
Isotope Atom Count: 0
Covalently-Bonded Unit Count: 1
CACTVS Substructure Key Fingerprint: AAADccByIAAAAAAAAAAAAAAAAAAAAAAAAAAwAAAAAAAAAAABAAAAHgAQCAAADCjhmAYwAIBAAgCAAiBCAACCAAAgAAAIiIAABIgKMCKAkRGAYABk0AEIiAeQwKAOAAAAAAAAAAAAAAAAAAAAAAAAAAAAAA==

10. Recommended Suppliers

Global328SuppliersView all >>

Hebei Ruiyao Biotechnology Co., Ltd Diamond member

-121YR

Products:Cosmetic Grade Chemical Raw Materical,Chemicals Raw Materials,API,Pharmaceutical Intermediates,Organic Chemicals
Tel:0311-88180881-19932787653
Email:sale06@ruiyaobio.com

Top sale D-Plenylglycinol Cas 56613-80-0 from China suppier

Purity:99%Packing: 200kg/bag FOB
Price: 30 USD/kg
Time: 2023/06/06

Inquire

Hebei Crovell Biotech Co. Ltd Diamond member

-120YR

Products:Cosmetic Raw Materials,solvents,etc.
Tel:86-311-66562153
Email:breeduan@crovellbio.com

(R)-(-)-2-Phenylglycinol Cas 56613-80-0 from China

Purity:99%Packing: 200kg/bag FOB
Price: 10 USD/kilogram
Time: 2023/06/06

Inquire

Hebei Yanxi Chemical Co.,Ltd Diamond member

-118YR

Products:Division I, the main production Lead acetate phenylacetamide Cyromazine quality is very good!
Tel:86-185-31123677
Email:xing@yan-xi.com

D-Plenylglycinol

Purity:99%Packing: 200kg/bag FOB
Price: 1 USD/kilogram
Time: 2023/05/11

Inquire

Amitychem Corporation Diamond member

-120YR

Products:Manufacture & Supply Biopharm Chemical, Specialty Chemical, PetroChemical.
Tel:86-592-8883942
Email:sale@amitychem.com

Factory Supply (R)-β-aminophenethyl alcohol

Purity:99%Packing: 200kg/bag FOB
Price: 0.1 USD/kilogram
Time: 2023/03/01

Inquire

Dayang Chem (Hangzhou) Co., Ltd. Diamond member

-111YR

Products:Chemical products
Tel:86-571-88938639
Email:sales-gc@dycnchem.com

D(-)-alpha-Phenylglycinol

Purity:99%Packing: 200kg/bag FOB
Price: 1 USD/kilogram
Time: 2023/06/02

Inquire

Recently Updated : 1176716-05-4 1629877-27-5 1630025-26-1 1630095-90-7 1630103-83-1 1630328-21-0 1630528-58-3 88898-79-7 2787482-26-0 1453188-67-4