3D Mol Similar

Hydrazine sulfate

: Iupac Name：hydrazine;sulfuric acid; CAS No.: 10034-93-2; Molecular Weight：130.12364; Modify Date.: 2022-11-22 18:48; Introduction: 1. It can be used as analytical reagent and reducing agent, it can also be used for the purification of rare metals. 2. It can be used as raw material for the manufacture of pharmaceutical. It can be used as raw material for azobisisobutyronitrile and other products in organic industry. It can be used as reducing agent on the plating. It can be used as insecticide, sterilizing agent in agriculture. It can be used as blowing agents in plastics and rubber. 3. It can be used for weight determination of nickel, cobalt and cadmium, purification of rare metals, reducing agents, organic synthesis, separation of polonium and tellurium, determination of hypochlorite, hypochlorous acid and carboxyl compounds, thymol turbidity is prepared in liver function tests. It can be used for isoniazid, nitrofurazone, 100 Health hydrazine, anhydrous hydrazine, pesticides and fungicides, for rocket fuel processing, anti-rust products, manufacture of ADC foaming agent. It is widely used in medicine, organic synthesis, pesticides, plastics, rubber and other industries. View more+

Request For Quotation

1. Names and Identifiers

: 1.1 Name; Hydrazine sulfate; 1.2 Synonyms; diamidogensulfate Diamine sulfate Diamine sulfate hydrazine sulfate EINECS 233-110-4 hydrazine disulfate HYDRAZINE MONOSULFATE Hydrazine sulfate (1:1) Hydrazine sulfate, reagent grade, ACS Hydrazine sulphate Hydrazine, sulfate (1:1) HydrazineSulphateGr hydrazinium hydrogensulfate Hydrazinium sulfate HYDRAZINIUM SULFATE GR FOR ANALYSIS ACS hydrazinium sulphate hydrazoniumsulfate idrazinasolfato MFCD00044873 monohydrazine sulfate siranhydrazinu; View all

1.3 CAS No.: 10034-93-2

1.4 CID: 24842

1.5 EINECS(EC#): 233-110-4

1.6 Molecular Formula: H6N2O4S (isomer)

1.7 Inchi: InChI=1S/H4N2.H2O4S/c1-2;1-5(2,3)4/h1-2H2;(H2,1,2,3,4)

1.8 InChIkey: ZGCHATBSUIJLRL-UHFFFAOYSA-N

1.9 Canonical Smiles: NN.OS(=O)(=O)O

1.10 Isomers Smiles: NN.OS(=O)(=O)O

2. Properties

2.1 Density: 1.37

2.1 Melting point: 254℃

2.1 Boiling point: 330°Cat760mmHg

2.1 Flash Point: °C

2.1 Precise Quality: 130.00500

2.1 PSA: 135.02000

2.1 logP: 0.64740

2.1 Solubility: 30g/l

2.2 Appearance: White Crystalline Powder

2.3 Storage: Ambient temperatures.

2.4 Carcinogenicity: Hydrazine and hydrazine sulfate are reasonably anticipated to be human carcinogens based on sufficient evidence of carcinogenicity from studies in experimental animals.

2.5 Chemical Properties: It is colorless scaly crystal or orthorhombic crystal. It is tasteless. It is slightly soluble in water, soluble in water, acidic aqueous solution. It is insoluble in alcohol.

2.6 Color/Form: Orthorhombic crystals; glass like plates or prisms
White crystalline powder

2.7 Decomposition: When heated to decomposition it emits very toxic fumes of /sulfur oxides and nitrogen oxides/.

2.8 Odor: Odorless

2.9 PH: 1.3 (0.2 Molar aq soln)

2.10 pKa: Exists as zwitterion, macroscopic pKa = 6.7 /Estimated/

2.11 Water Solubility: H2O: 30 g/L (20 oC)

2.12 Stability: Stable. Incompatible with nitrites, strong oxidizing agents.

2.13 StorageTemp: Keep in dark place,Sealed in dry,Room Temperature

3. Use and Manufacturing

3.1 Methods of Manufacturing: In the urea method, urea, sodium hypochlorite, and liquid alkali are reacted in the presence of potassium permanganate, distilled, and then neutralized with sulfuric acid. The product is cooled and crystallized, filtered, and dried to obtain a finished product of hydrazine sulfate.?Its NaOCI+NH2CONH2+2NaOH[KMnO4]→N2H4?H2O+NaCl+Na2CO3N2H4?H2O+H2SO4→N2H4?H2SO4+H2O

3.2 Purification Methods: Its solubility in H2O is 3% at room temperature, but is very soluble in hot H2O. It is a suspected carcinogen. [Adams & Brown Org Synth Coll Vol I 309 1941, Audrieth & Nickles Inorg Synth I 90 1939.] Hydrazine sulfate Preparation Products And Raw materials Preparation Products

3.3 Usage: 1. It can be used as analytical reagent and reducing agent, it can also be used for the purification of rare metals. 2. It can be used as raw material for the manufacture of pharmaceutical. It can be used as raw material for azobisisobutyronitrile and other products in organic industry. It can be used as reducing agent on the plating. It can be used as insecticide, sterilizing agent in agriculture. It can be used as blowing agents in plastics and rubber. 3. It can be used for weight determination of nickel, cobalt and cadmium, purification of rare metals, reducing agents, organic synthesis, separation of polonium and tellurium, determination of hypochlorite, hypochlorous acid and carboxyl compounds, thymol turbidity is prepared in liver function tests. It can be used for isoniazid, nitrofurazone, 100 Health hydrazine, anhydrous hydrazine, pesticides and fungicides, for rocket fuel processing, anti-rust products, manufacture of ADC foaming agent. It is widely used in medicine, organic synthesis, pesticides, plastics, rubber and other industries.; View all

4. Safety and Handling

4.1 Symbol: GHS05, GHS06, GHS08, GHS09

4.1 Hazard Codes: T; N

4.1 Signal Word: Danger

4.1 Risk Statements: R23/24/25;R43;R45;R50/53

4.1 Safety Statements: S45;S53;S60;S61

4.1 Packing Group: II

4.1 Other Preventative Measures: Inhalation of salt dusts should be avoided. /Hydrazine & derivatives/
Engineering controls, such as process enclosure or local exhaust ventilation, shall be used when needed to keep concentrations of airborne hydrazines within acceptable levels. Ventilation systems shall be designed to prevent accumulation or recirculation of airborne hydrazines in the workplace environment and to remove hydrazines from the breathing zone of workers.
SRP: The scientific literature for the use of contact lenses in industry is conflicting. The benefit or detrimental effects of wearing contact lenses depend not only upon the substance, but also on factors including the form of the substance, characteristics and duration of the exposure, the uses of other eye protection equipment, and the hygiene of the lenses. However, there may be individual substances whose irritating or corrosive properties are such that the wearing of contact lenses would be harmful to the eye. In those specific cases, contact lenses should not be worn. In any event, the usual eye protection equipment should be worn even when contact lenses are in place.; View all

4.2 Hazard Class: 8

4.2 Hazard Declaration: H301 + H311 + H331-H314-H317-H350-H410

4.2 DisposalMethods: SRP: The most favorable course of action is to use an alternative chemical product with less inherent propensity for occupational exposure or environmental contamination. Recycle any unused portion of the material for its approved use or return it to the manufacturer or supplier. Ultimate disposal of the chemical must consider: the material's impact on air quality; potential migration in soil or water; effects on animal, aquatic, and plant life; and conformance with environmental and public health regulations.
Incineration: The best disposal methods are incineration and burial. Incinerate in a unit with effluent gas scrubbing.

4.3 RIDADR: UN 2923

4.3 Caution Statement: P201-P261-P273-P280-P301 + P310-P305 + P351 + P338

4.3 WGK Germany: 3

4.3 RTECS: MV9625000

4.3 Protective Equipment and Clothing: Vapors are very irritating to the mucous membranes, nose, throat, and upper respiratory tract. /Hydrazine/

4.4 Skin, Eye, and Respiratory Irritations: Vapors are very irritating to the mucous membranes, nose, throat, and upper respiratory tract. /Hydrazine/

4.5 Toxicity: Hydrazine sulfate is moderately toxic. Symptoms of ingestion are paresthesia, somnolence, nausea, and vomiting. It also is an irritant to the eye. It is a confirmed carcinogen and an experimental teratogen.

5. MSDS

2.Hazard identification

2.1 Classification of the substance or mixture

Acute toxicity - Oral, Category 3

Acute toxicity - Dermal, Category 3

Skin corrosion, Category 1A

Skin sensitization, Category 1

Acute toxicity - Inhalation, Category 3

Carcinogenicity, Category 1B

Hazardous to the aquatic environment, short-term (Acute) - Category Acute 1

Hazardous to the aquatic environment, long-term (Chronic) - Category Chronic 1

2.2 GHS label elements, including precautionary statements

Pictogram(s)
Signal word	Danger
Hazard statement(s)	H301+H311+H331 Toxic if swallowed, in contact with skin or if inhaled H314 Causes severe skin burns and eye damage H317 May cause an allergic skin reaction H350 May cause cancer H410 Very toxic to aquatic life with long lasting effects
Precautionary statement(s)
Prevention	P264 Wash ... thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P280 Wear protective gloves/protective clothing/eye protection/face protection. P260 Do not breathe dust/fume/gas/mist/vapours/spray. P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P272 Contaminated work clothing should not be allowed out of the workplace. P271 Use only outdoors or in a well-ventilated area. P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P273 Avoid release to the environment.
Response	P301+P310 IF SWALLOWED: Immediately call a POISON CENTER/doctor/\u2026 P321 Specific treatment (see ... on this label). P330 Rinse mouth. P302+P352 IF ON SKIN: Wash with plenty of water/... P312 Call a POISON CENTER/doctor/\u2026if you feel unwell. P361+P364 Take off immediately all contaminated clothing and wash it before reuse. P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower]. P363 Wash contaminated clothing before reuse. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P310 Immediately call a POISON CENTER/doctor/\u2026 P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P333+P313 If skin irritation or rash occurs: Get medical advice/attention. P362+P364 Take off contaminated clothing and wash it before reuse. P311 Call a POISON CENTER/doctor/\u2026 P308+P313 IF exposed or concerned: Get medical advice/ attention. P391 Collect spillage.
Storage	P405 Store locked up. P403+P233 Store in a well-ventilated place. Keep container tightly closed.
Disposal	P501 Dispose of contents/container to ...

2.3 Other hazards which do not result in classification

none

View all

6. NMR Spectrum

IR : KBr disc

IR : nujol mull

7. Synthesis Route

10034-93-2Total: 5 Synthesis Route

556-88-7 45 Suppliers

7664-41-7 248 Suppliers

10034-93-2 174 Suppliers

Literatures:
Thiele, J. Liebigs Annalen der Chemie, 1892 , vol. 270, p. 31 Full Text Show Details Gmelin Handbook: N: MVol.2, 1.6, page 307 - 310 Full Text Show Details Badische Anilin- & Sodafabrik Patent: DE59241 , 1891 ;
Yield: null

7664-93-9

10034-93-2 174 Suppliers

Literatures:
Journal of the Chemical Society, , vol. 95, p. 237
Yield: null

3787-09-5

10034-93-2 174 Suppliers

7727-37-9 82 Suppliers

Literatures:
Journal fuer Praktische Chemie (Leipzig), , vol. 39, p. 27 - 31 N: MVol.2, 1.6, page 307 - 310 DE47600 , ;
Yield: null

View all

8. Precursor and Product

precursor:

3787-09-5

556-88-7

7803-63-6

7664-41-7

product :

7553-56-2

916329-38-9

227934-45-4

121073-74-3

7664-41-7

7681-11-0

563-41-7

13730-91-1

15456-86-7

9. Other Information

9.0 Usage: Hydrazine sulfate is used in analytical chemistry for the gravimetric estimation of nickel, cobalt and cadmium. It is also used in the refining of rare metals as well as in the separation of polonium from tellurium. It finds application in the synthesis of chemical intermediate and organic compounds. Further, it acts as an antioxidant in soldering flux for light metals and as a precursor to hydrazine.

9.1 Usage: Reagent for determination of C-terminal amino acidsHydrazine sulfate is used in analytical chemistry for the gravimetric estimation of nickel, cobalt and cadmium. It is also used in the refining of rare metals as well as in the separation of polonium from tellurium. It finds application in the synthesis of chemical intermediate and organic compounds. Further, it acts as an antioxidant in soldering flux for light metals and as a precursor to hydrazine.

9.2 Storage Conditions: In the urea method, urea, sodium hypochlorite, and liquid alkali are reacted in the presence of potassium permanganate, distilled, and then neutralized with sulfuric acid. The product is cooled and crystallized, filtered, and dried to obtain a finished product of hydrazine sulfate.?Its NaOCI+NH2CONH2+2NaOH[KMnO4]→N2H4?H2O+NaCl+Na2CO3N2H4?H2O+H2SO4→N2H4?H2SO4+H2O

9.3 Merck: 14,4772

9.4 BRN: 8778859

9.5 Chemical properties: It is colorless scaly crystal or orthorhombic crystal. It is tasteless. It is slightly soluble in water, soluble in water, acidic aqueous solution. It is insoluble in alcohol.

9.6 Uses: 1. It can be used as analytical reagent and reducing agent, it can also be used for the purification of rare metals.
2. It can be used as raw material for the manufacture of pharmaceutical. It can be used as raw material for azobisisobutyronitrile and other products in organic industry. It can be used as reducing agent on the plating. It can be used as insecticide, sterilizing agent in agriculture. It can be used as blowing agents in plastics and rubber.
3. It can be used for weight determination of nickel, cobalt and cadmium, purification of rare metals, reducing agents, organic synthesis, separation of polonium and tellurium, determination of hypochlorite, hypochlorous acid and carboxyl compounds, thymol turbidity is prepared in liver function tests. It can be used for isoniazid, nitrofurazone, 100 Health hydrazine, anhydrous hydrazine, pesticides and fungicides, for rocket fuel processing, anti-rust products, manufacture of ADC foaming agent. It is widely used in medicine, organic synthesis, pesticides, plastics, rubber and other industries.; View all

9.7 Chemical Properties: colourless crystals or white powder

9.8 Uses: In the gravimetric estimation of nickel, cobalt and cadmium; in the refining of rare metals; as antioxidant in soldering flux for light metals; as reducing agent in the analysis of minerals and slags; in separating polonium from tellurium; in tests for blood; for destroying fungi and molds; in the preparation of hydrazine hydrate.

9.9 Hazard: A carcinogen (OSHA).

9.10 Purification Methods: Its solubility in H2O is 3% at room temperature, but is very soluble in hot H2O. It is a suspected carcinogen. [Adams & Brown Org Synth Coll Vol I 309 1941, Audrieth & Nickles Inorg Synth I 90 1939.]

9.11 Uses: 1. It can be used as analytical reagent and reducing agent, it can also be used for the purification of rare metals.
2. It can be used as raw material for the manufacture of pharmaceutical. It can be used as raw material for azobisisobutyronitrile and other products in organic industry. It can be used as reducing agent on the plating. It can be used as insecticide, sterilizing agent in agriculture. It can be used as blowing agents in plastics and rubber.
3. It can be used for weight determination of nickel, cobalt and cadmium, purification of rare metals, reducing agents, organic synthesis, separation of polonium and tellurium, determination of hypochlorite, hypochlorous acid and carboxyl compounds, thymol turbidity is prepared in liver function tests. It can be used for isoniazid, nitrofurazone, 100 Health hydrazine, anhydrous hydrazine, pesticides and fungicides, for rocket fuel processing, anti-rust products, manufacture of ADC foaming agent. It is widely used in medicine, organic synthesis, pesticides, plastics, rubber and other industries.; View all

9.12 Production method: Urea method: Urea, sodium hypochlorite, caustic soda, in the presence of potassium permanganate can react, by distillation, and then reacts with sulfuric acid for neutralization, the resultant passes through cooling and crystallization, filtration, drying to obtain hydrazine sulfate products.
NaOCI + NH2CONH2 + 2NaOH [KMnO4] → N2H4·H2O + NaCl + Na2CO3
N2H4·H2O + H2SO4 → N2H4·H2SO4 + H2O

9.13 Physical properties: Colorless orthorhombic crystal; density 1.378 g/cm3; melts at 254°C; sparingly soluble in cold water 1.64% at 0°C and 3.41% at 25°C; more soluble inhot water; practically insoluble in alcohol (0.04% at 25°C).

9.14 Uses: Hydrazine sulfate is used in the gravimetric estimation of nickel, cobalt and cadmium; in the refining of rare metals; as an antioxidant in soldering flux for light metals; as a reducing agent in the analysis of minerals and slags; in separating polonium from tellurium; in tests for blood; for destroying fungi and molds; in the preparation of hydrazine hydrate; press ure stabilizer in cutting oils.

9.15 General Description: Hydrazine sulfate salt is a potential anticachexia agent for treating cancer patients.

10. Computational chemical data

Molecular Weight: 130.12364g/mol
Molecular Formula: H₆N₂O₄S
Compound Is Canonicalized: True
XLogP3-AA: null
Exact Mass: 130.00482785
Monoisotopic Mass: 130.00482785
Complexity: 81.3
Rotatable Bond Count: 0
Hydrogen Bond Donor Count: 4
Hydrogen Bond Acceptor Count: 6
Topological Polar Surface Area: 135
Heavy Atom Count: 7
Defined Atom Stereocenter Count: 0
Undefined Atom Stereocenter Count: 0
Defined Bond Stereocenter Count: 0
Undefined Bond Stereocenter Count: 0
Isotope Atom Count: 0
Covalently-Bonded Unit Count: 2
CACTVS Substructure Key Fingerprint: AAADcYADOABAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAYCAAAAAAAAAAAAAACAIAAAAAAADAAAAAAAAIAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAA==

11. Question & Answer

How to Prepare Hydrazine Sulfate with High Purity and Easy Separation? Apr 05 2023
Background Technology Hydrazine sulfate (N2H4·H2SO4), also known as sulfamic acid, is a toxic compound. It is a colorless flake or orthorhombic crystal, tasteless, soluble in hot water and less solubl..
What is Hydrazine sulfate? Jul 15 2020
Hydrazine Sulfate is a salt of the cation hydrazinium and the anion bisulfate (hydrogen sulfate), with the formula [N2H5+] [HSO4−] or N2H6SO4. It is a white, water-soluble solid at room tempera..
What is Hydrazine Sulfate and its Uses? Jan 14 2020
Hydrazine Sulfate, a salt composed of the cation hydrazinium and the anion bisulfate, is a white, water-soluble solid at room temperature [1]. It is derived from ammonia and sulfuric acid, resulting ..

12. Recommended Suppliers

Global166SuppliersView all >>

Shanghai Worldyang Chemical Co.,Ltd. Diamond member

1YR

Products:API,intermediate,hormone
Tel:+86-21-56791066
Email:sales001@worldyachem.com

Hydrazine sulfate CAS 10034-93-2

Purity:99%Packing: 200kg/bag FOB
Price: 20 USD/kg
Time: 2023/09/21

Inquire

Xiamen wonderful Biotechnology Co., Ltd. Diamond member

1YR

Products:Top quality and high purity with safe transportation and low price
Tel:+86187-59294010-18759294010
Email:Beata@xmwonderfulbio.com

High Quality Hydrazine sulfate 99% Purity CAS 10034-93-2 With Good Price

Purity:99%Packing: 200kg/bag FOB
Price: 120 USD/g
Time: 2023/09/21

Inquire

Wuhan Pharmchem Co., LTD. Diamond member

2YRS

Products:Pharma &Food Intermediates Water Treatment Chemicals Industrial Specialties Fine Chemicals
Tel:86-27-85835203
Email:steven@cspharmchem.com

98% Hydrazine sulfate EINECS 233-110-4