N-[3-(Trimethoxysilyl)propyl]ethylenediamine

Iupac Name：N'-(3-trimethoxysilylpropyl)ethane-1,2-diamine

Molecular Weight：222.36

Modify Date.: 2022-11-25 02:13

Introduction: This substance is used in the following products: adhesives and sealants, coating products and finger paints. Other release to the environment of this substance is likely to occur from: indoor use and outdoor use resulting in inclusion into or onto a materials (e.g. binding agent in paints and coatings or adhesives). View more+

Request For Quotation

1. Names and Identifiers

1.1 Name: N-[3-(Trimethoxysilyl)propyl]ethylenediamine
1.2 Synonyms: [3-(2-Aminoethylamino)propyl]trimethoxysilane 1,2-Ethanediamine, N-[3-(trimethoxysilyl)propyl]- 3-(2-Aminoethylamino)propyltrimethoxysilane EINECS 217-164-6 MFCD00008173 N-(2-Aminoethyl)-3-(trimethoxysilyl)propylamine N-(2-Aminoethyl)-3-aminopropyltrimethoxysilane N-(2-aminoethyl)-3-amino-propyltrimethoxysilane N-(2-aminoethyl)-3-aminopropyl-trimethoxysilane N'-(3-trimethoxysilylpropyl)ethane-1,2-diamine N-(3-Trimethoxysilylpropyl)ethylenediamine N-[3-(Trimethoxysilyl)propyl]-1,2-ethanediamine N-[3-(Trimethoxysilyl)propyl]ethane-1,2-diamine N1-(3-(Trimethoxysilyl)propyl)ethane-1,2-diamine Petrarch A0700 Petrarch A0701 Prosil 3128 prosil3128 sh6020 Silane, (3-(2-aminoethyl)aminopropyl)trimethoxy- Silane, trimethoxy-[3[N-(2-aminoethyl)]aminopropyl]- Silicone A-1120

1.3 CAS No.: 1760-24-3

1.4 CID: 15659

1.5 EINECS(EC#): 217-164-6

1.6 Molecular Formula: C8H22N2O3Si (isomer)

1.7 Inchi: InChI=1S/C8H22N2O3Si/c1-11-14(12-2,13-3)8-4-6-10-7-5-9/h10H,4-9H2,1-3H3

1.8 InChkey: PHQOGHDTIVQXHL-UHFFFAOYSA-N

1.9 Canonical Smiles: CO[Si](CCCNCCN)(OC)OC

1.10 Isomers Smiles: CO[Si](CCCNCCN)(OC)OC

2. Properties

2.1 Density: 1.028 g/mL at 25 °C(lit.)

2.1 Melting point: 0°C

2.1 Boiling point: 146 °C15 mm Hg(lit.)

2.1 Refractive index: n20/D 1.444(lit.)

2.1 Flash Point: 220 °F

2.1 Precise Quality: 222.14000

2.1 PSA: 65.74000

2.1 logP: 0.89410

2.1 Solubility: Miscible with toluene.

2.2 Appearance: DryPowder; Liquid; OtherSolid

2.3 Storage: Moisture Sensitive. Air Sensitive. Ambient temperatures.

2.4 Chemical Properties: Colorless transparent liquid

2.5 Color/Form: Clear colorless to light yellow

2.6 Contact Allergens: This amine-functional methoxysilane, referenced asaminoethyl aminopropyltrimethoxysilane, was impli-cated in the production of glass filaments. N-[3-(Trimethoxysilyl)propyl]ethylenediamineSupplier

2.7 PH: 10 (10g/l, H2O, 20℃)

2.8 pKa: 10.11±0.19(Predicted)

2.9 Water Solubility: Solubility in water: reaction

2.10 Stability: Stable under normal shipping and handling conditions.

2.11 StorageTemp: Store below +30°C.

3. Use and Manufacturing

3.1 Usage: This substance is used in the following products: adhesives and sealants, coating products and finger paints. Other release to the environment of this substance is likely to occur from: indoor use and outdoor use resulting in inclusion into or onto a materials (e.g. binding agent in paints and coatings or adhesives).

4. Safety and Handling

4.1 Symbol: GHS05, GHS07

4.1 Hazard Codes: Xn,Xi

4.1 Signal Word: Danger

4.1 Risk Statements: 38-41-43-52/53-42/43-37/38

4.1 Safety Statements: 26-39-61-37/39-24-36/37/39-23

4.1 Packing Group: III

4.1 Hazard Class: 8

4.1 Hazard Declaration: H315-H317-H318

4.1 RIDADR: UN 3267 8/PG 2

4.1 Caution Statement: P280-P305 + P351 + P338

4.1 WGK Germany: 3

4.1 RTECS: KV7400000

4.1 Report: Reported in EPA TSCA Inventory.

4.2 Safety: Poison by intravenous route. Mildly toxic by ingestion and skin contact. A skin and severe eye irritant. When heated to decomposition it emits toxic fumes of NO_x.
Hazard Codes:?Xn,Xi
Risk Statements: 38-41-43-52/53-42/43-37/38?
R38:Irritating to skin.?
R41:Risk of serious damage to the eyes.?
R43:May cause sensitization by skin contact.?
R52/53:Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.?
R42/43:May cause sensitization by inhalation and skin contact.?
R37/38:Irritating to respiratory system and skin.
Safety Statements: 26-39-61-37/39-24-36/37/39-23?
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.?
S39:Wear eye / face protection.?
S61:Avoid release to the environment. Refer to special instructions / safety data sheets.?
S37/39:Wear suitable gloves and eye/face protection.?
S24:Avoid contact with skin.?
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection.?
S23:Do not breathe vapour.
RIDADR: UN 3267 8/PG 2
WGK Germany: 3
RTECS: KV7400000
F: 1-10
TSCA: Yes
HazardClass: 8
PackingGroup of Z 6020 (CAS NO.1760-24-3): III

4.3 Sensitive: Air & Moisture Sensitive

4.4 Specification: ?Z 6020 (CAS NO.1760-24-3), its Synonyms are AAS-M ; AP 132 ; Dow corning Z-6020 silane ; N-(3-Trimethoxysilylpropyl)-ethylenediamine ; 1,2-Ethanediamine, N-(3-(trimethoxysilyl)propyl)- ; 1,2-Ethanediamine, N1-(3-(trimethoxysilyl)propyl)- ; Ethylenediamine, N-(3-(trimethoxysilyl)propyl)- ; N-(3-(Trimethoxysilyl)propyl)-1,2-ethanediamine ; Silane, (3-(2-aminoethyl)aminopropyl)trimethoxy- . It is colorless transparent liquid.

4.5 Toxicity

Organism	Test Type	Route	Reported Dose (Normalized Dose)	Effect	Source
mouse	LD50	intravenous	180mg/kg (180mg/kg)	?	U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. Vol. NX#03517,
rabbit	LDLo	skin	16mL/kg (16mL/kg)	?	Union Carbide Data Sheet. Vol. 4/2/1971,
rat	LD50	oral	7460uL/kg (7.46mL/kg)	?	Union Carbide Data Sheet. Vol. 4/2/1971,

View all

5. MSDS

2.Hazard identification

2.1 Classification of the substance or mixture

Skin sensitization, Category 1

Serious eye damage, Category 1

2.2 GHS label elements, including precautionary statements

Pictogram(s)
Signal word	Danger
Hazard statement(s)	H317 May cause an allergic skin reaction H318 Causes serious eye damage
Precautionary statement(s)
Prevention	P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P272 Contaminated work clothing should not be allowed out of the workplace. P280 Wear protective gloves/protective clothing/eye protection/face protection.
Response	P302+P352 IF ON SKIN: Wash with plenty of water/... P333+P313 If skin irritation or rash occurs: Get medical advice/attention. P321 Specific treatment (see ... on this label). P362+P364 Take off contaminated clothing and wash it before reuse. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTER/doctor/\u2026
Storage	none
Disposal	P501 Dispose of contents/container to ...

2.3 Other hazards which do not result in classification

none

View all

6. NMR Spectrum

13C NMR : in CDCl3

13C NMR : Predict

1H NMR : 90 MHz in CDCl3

1H NMR : Predict

Predict 1H proton NMR

IR : CCl4 solution

IR : liquid film

Mass

Mass spectrum (electron ionization)

7. Synthesis Route

1760-24-3Total: 2 Synthesis Route

2530-87-2 186 Suppliers

1760-24-3 240 Suppliers

Literatures:
US5446181 A1, ;
Yield: ~71%

107-15-3

2530-87-2 186 Suppliers

1760-24-3 240 Suppliers

Literatures:
Journal of Organometallic Chemistry, , vol. 521, # 1-2 p. 29 - 31
Yield: ~90%

8. Precursor and Product

precursor:

2530-87-2

product :

68400-08-8

444315-16-6

9. Other Information

9.0 Usage: 3-(2-Aminoethylamino) propyltrimethoxysilane acts as a silane coupling agent. It is useful for chemical research. It is also employed as an adhesives and sealant chemical. Further, it is used as a paint additive and coating additive. In addition to this, it plays an important role in the production of petroleum.

9.1 Mesh Entry Terms: (trimethoxysilylpropyl)ethylenediamine

9.2 Production: 1,000,000 - 10,000,000 lb

9.3 Manufacturing Info: Adhesive manufacturing|1,2-Ethanediamine, N1-[3-(trimethoxysilyl)propyl]-: ACTIVE

9.4 BRN: 636230

9.5 Introduction

N-[3-(Trimethoxysilyl)propyl]ethylenediamine (equal to A-1120, GF 91, KBM603) is a clear, colorless, strongly alkaline liquid with smell being very sensitive to hydrolysis. The chloride content ranges in the lower ppm-level.
N-[3-(Trimethoxysilyl)propyl]ethylenediamine is used as adhesion promoter at organic/inorganic interfaces, for modification of surfaces (corrosion prevention, component of primers) or silicone-polymers or as crosslinker (moisture crosslinking of polymers). The application as "coupling agent" leads in general to an improvement of mechanical and electrical product properties above all under exposure to heat and/or moisture. Applications:

N-[3-(Trimethoxysilyl)propyl]ethylenediamine may be used as an effective coupling agent for clay reinforced elastomers such as natural and nitrile rubber, to improve physical and dynamic properties.
Used as an effective coupling agent for mineral reinforced nylon 6, nylon 6/6 and polybutyleneterephthalate, to increase the flexural and tensile strength of the thermoplastic composite.
Used as a fiberglass finish or a resinous additive for fiberglass reinforced phenolic, melamine and expoxy thermoset composites.
Used as a mineral binders in in foundry and abrasive composite applications, to improve adhesion, increase composite strength.
Used as a glass and metal primer, to improve the adhesion of many coatings (urethanes, epoxies, phenolics and others) to glass and metal surfaces.
Used as an adhesion promoters in polysulfide, polyvinyl chloride plastisol, silicone two part urethane and epoxy adhesives and sealants.

View all

9.6 Chemical Properties: Colorless transparent liquid

9.7 Contact allergens: This amine-functional methoxysilane, referenced as aminoethyl aminopropyltrimethoxysilane, was impli- cated in the production of glass filaments.

9.8 Uses: This substance is used in the following products: adhesives and sealants, coating products and finger paints. Other release to the environment of this substance is likely to occur from: indoor use and outdoor use resulting in inclusion into or onto a materials (e.g. binding agent in paints and coatings or adhesives).

9.9 service life: Other release to the environment of this substance is likely to occur from: outdoor use in long-life materials with low release rate (e.g. metal, wooden and plastic construction and building materials) and indoor use in long-life materials with low release rate (e.g. flooring, furniture, toys, construction materials, curtains, foot-wear, leather products, paper and cardboard products, electronic equipment).

9.10 Introduction

N-[3-(Trimethoxysilyl)propyl]ethylenediamine may be used as an effective coupling agent for clay reinforced elastomers such as natural and nitrile rubber, to improve physical and dynamic properties.
Used as an effective coupling agent for mineral reinforced nylon 6, nylon 6/6 and polybutyleneterephthalate, to increase the flexural and tensile strength of the thermoplastic composite.
Used as a fiberglass finish or a resinous additive for fiberglass reinforced phenolic, melamine and expoxy thermoset composites.
Used as a mineral binders in in foundry and abrasive composite applications, to improve adhesion, increase composite strength.
Used as a glass and metal primer, to improve the adhesion of many coatings (urethanes, epoxies, phenolics and others) to glass and metal surfaces.
Used as an adhesion promoters in polysulfide, polyvinyl chloride plastisol, silicone two part urethane and epoxy adhesives and sealants.

View all

9.11 Uses: N-[3-(Trimethoxysilyl)propyl]ethylenediamine has also been used as an organic ligand for the surface modification of silica gel to uptake heavy metal ions. It can react with fluorinated carbon nanotubes (F-CNT) to form aminoalkylalkoxysilane functionalized carbon nanotubes.

10. Computational chemical data

Molecular Weight: 222.36g/mol
Molecular Formula: C₈H₂₂N₂O₃Si
Compound Is Canonicalized: True
XLogP3-AA: null
Exact Mass: 222.13996910
Monoisotopic Mass: 222.13996910
Complexity: 126
Rotatable Bond Count: 9
Hydrogen Bond Donor Count: 2
Hydrogen Bond Acceptor Count: 5
Topological Polar Surface Area: 65.7
Heavy Atom Count: 14
Defined Atom Stereocenter Count: 0
Undefined Atom Stereocenter Count: 0
Defined Bond Stereocenter Count: 0
Undefined Bond Stereocenter Count: 0
Isotope Atom Count: 0
Covalently-Bonded Unit Count: 1
CACTVS Substructure Key Fingerprint: AAADceBzMAgAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAHhAQAEAACADBIAZCAALAAAAAAAAAAAAAAAAAAAAAAIAIAAAAQAAAAAAUAAAAEACAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAA==

11. Recommended Suppliers

Global234SuppliersView all >>

Hebei Crovell Biotech Co. Ltd Diamond member

3YRS

Products:Cosmetic Raw Materials,solvents,etc.
Tel:86-311-66562153
Email:breeduan@crovellbio.com

Silane Coupling Agent KH-603 CAS 1760-24-3 With Good Price

Purity:99%Packing: 200kg/bag FOB
Price: 1 USD/kilogram
Time: 2023/05/30

Inquire

Shanghai Worldyang Chemical Co.,Ltd. Diamond member

1YR

Products:API,intermediate,hormone
Tel:+86-21-56791066
Email:sales001@worldyachem.com

N-(3-Trimethoxysilylpropyl)ethylenediamine

Purity:99%Packing: 200kg/bag FOB
Price: 40 USD/kg
Time: 2023/05/30

Inquire

Qiaoxi Shengyou Chemical Co., LTD Diamond member

1YR

Products:pharmaceutical intermediates Organic raw materialsAnimal and plant extracts1.4BDO, Eutylone,4MMC, JWH ,SGT Peptide, Steroids, Benzos,Dissociatives
Tel:86-311-18931626169
Email:accountmanager1@yeah.net

N-[3-(Trimethoxysilyl)propyl]ethylenediamine

Purity:99%Packing: 200kg/bag FOB
Price: 1 USD/kg
Time: 2023/05/30

Inquire

Iota Silicone Oil (Anhui) Co., Ltd Diamond member

1YR

Products:Phenyl silicone, diffusion pump oil, Methyl silicone oil, Hydroxy silicone oil, Vinyl silicone oil, Organic polysilazane, Inorganic polysilazane, Hexamethyldisilazane.
Tel:181-1973-3779
Email:sales07@siliconeoil.net

N-(2-aminoethyl)-3-aminopropyltrimethoxysilane IOTA-792

Purity:99%Packing: 200kg/bag FOB
Price: 5.32 USD/kg
Time: 2022/09/19

Inquire

Shanghai CRM New Material Technology Co., Ltd. Diamond member

1YR

Products:Pharmaceutical Intermediates,Chemical Raw Materials,Iodine,Lidocaine,Procaine,Benzocaine,20320-59-6,5449-12-7,28578-16-7,Ks0037
Tel:86-21-17621170008
Email:lizanne@shanghaicrm.com

High Purity CAS 1760-24-3 N-[3-(Trimethoxysilyl)propyl]ethylenediamine

Purity:99%Packing: 200kg/bag FOB
Price: 100 USD/kg
Time: 2023/04/25

Inquire

12. Realated Product Infomation

42965-91-3 N-benzyl-N'-[3-(trimethoxysilyl)propyl]ethylenediamine monohydrochloride

128850-89-5 N-[(3-TRIMETHOXYSILYL)PROPYL]ETHYLENEDIAMINE TRIACETIC ACID TRISODIUM SALT

84962-99-2 N,N'-bis[2-[[3-(trimethoxysilyl)propyl]amino]ethyl]ethylenediamine dihydrochloride

23843-64-3 1-[3-(Trimethoxysilyl)propyl]urea

3068-76-6 N-[3-(TRIMETHOXYSILYL)PROPYL]ANILINE

31024-56-3 N-(3-(Trimethoxysilyl)propyl)butylamine

23432-62-4 METHYL [3-(TRIMETHOXYSILYL)PROPYL]CARBAMATE

Recently Updated : 1824562-11-9 149505-86-2 1824189-94-7 114554-08-4 79583-58-7 1368226-38-3 1314933-74-8 3694-84-6 1097789-12-2 172649-59-1