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Potassium tetrafluoroborate structure
Potassium tetrafluoroborate structure

Potassium tetrafluoroborate

Iupac Name:potassium;tetrafluoroborate
CAS No.: 14075-53-7
Molecular Weight:125.902
Modify Date.: 2022-11-25 02:23
Introduction: Has been proposed as a flux for soldering and brazing; filler in resin-bonded grinding wheels. View more+
1. Names and Identifiers
1.1 Name
Potassium tetrafluoroborate
1.2 Synonyms

Avogadrite benzyl alcohol xanthate potassium salt Borate (1-), tetrafluoro-, potassium Borate(1-), tetrafluoro-, potassium Borate(1-), tetrafluoro-, potassium (1:1) Boron potassium fluoride (KBF4) CARBONIC ACID,DITHIO-,O-BENZYL ESTER,POTASSIUM SALT dithiocarbonic acid O-benzyl ester,potassium-salt Dithiokohlensaeure-O-benzylester,Kalium-Salz EINECS 237-928-2 MFCD00011395 NSC 168351 potassium benzyl dithiocarbonate potassium benzylxanthate Potassium boride fluoride Potassium boride fluoride (KBF4) Potassium borofluoride Potassium borofluoride (KBF4) POTASSIUM BOROFULUORIDE Potassium boron fluoride Potassium fluoborate Potassium fluoborate (KBF4) Potassium Fluorborate (KBF4) Potassium fluoroborae Potassium fluoroborate Potassium fluoroborate (KBF4) Potassium fluorohydroborate Potassium Hexafluoroposphate Potassium hydrofluoroborate Potassium O-benzyl dithiocarbonate Potassium O-benzyl xanthate Potassium tetrafluoroborate (KBF4) Potassium tetrafluoroborate(1-) potassiumm benzyldithiocarbonate Spec 101 Spec 102 Spec 104 Xanthic acid,benzyl-,potassium salt

1.3 CAS No.
14075-53-7
1.4 CID
518872
1.5 EINECS(EC#)
237-928-2
1.6 Molecular Formula
BF4K (isomer)
1.7 Inchi
InChI=1S/BF4.K/c2-1(3,4)5;/q-1;+1
1.8 InChkey
AKEBROIVCDHVSD-UHFFFAOYSA-N
1.9 Canonical Smiles
[B-](F)(F)(F)F.[K+]
1.10 Isomers Smiles
[B-](F)(F)(F)F.[K+]
2. Properties
2.1 Density
2.5
2.1 Melting point
530℃
2.1 Boiling point
960.85 (310 torr)
2.1 Refractive index
1.3245
2.1 Precise Quality
125.96700
2.1 PSA
0.00000
2.1 logP
1.30000
2.1 Solubility
4.4 g/L (20 ºC)
2.2 Appearance
DryPowder; OtherSolid; PelletsLargeCrystals
2.3 Storage
Hygroscopic. Ambient temperatures.
2.4 Chemical Properties
It appears as white powder or gelatinous crystals. It has hygroscopicity with bitter taste. It is slightly soluble in water and hot ethanol, insoluble in cold ethanol.
2.5 Color/Form
White to light gray
2.6 Water Solubility
H2O: 4.4 g/L (20 oC)
2.7 Stability
Stable. May decompose on exposure to water or moisture. Incompatible with metals.
2.8 StorageTemp
Sealed in dry,Room Temperature
3. Use and Manufacturing
3.1 GHS Classification
Signal: Danger
GHS Hazard Statements
Aggregated GHS information provided by 54 companies from 5 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Reported as not meeting GHS hazard criteria by 32 of 54 companies. For more detailed information, please visit ECHA C&L website

Of the 4 notification(s) provided by 22 of 54 companies with hazard statement code(s):

H314 (13.64%): Causes severe skin burns and eye damage [Danger Skin corrosion/irritation]
H319 (13.64%): Causes serious eye irritation [Warning Serious eye damage/eye irritation]
H335 (13.64%): May cause respiratory irritation [Warning Specific target organ toxicity, single exposure; Respiratory tract irritation]
H413 (77.27%): May cause long lasting harmful effects to aquatic life [Hazardous to the aquatic environment, long-term hazard]

Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown.

Precautionary Statement Codes
P260, P261, P264, P271, P273, P280, P301+P330+P331, P303+P361+P353, P304+P340, P305+P351+P338, P310, P312, P321, P337+P313, P363, P403+P233, P405, and P501
3.2 Purification Methods
Crystallise it from H2O (solubility% (temperature): 0.3 (3o), 0.45 (20o), 1.4 (40o), 6.27 (100o), and dry it under vacuum. It is a non-hygroscopic salt. A 10% solution is transparent blue at 100o, green at 90o and yellow at 60o. [V.rlander et al. Chem Ber 65 535 1932, Kwasnik in Handbook of Preparative Inorganic Chemistry (Ed. Brauer) Academic Press Vol I p 223 1963.] Potassium tetrafluoroborate Preparation Products And Raw materials Raw materials
3.3 Usage
Has been proposed as a flux for soldering and brazing; filler in resin-bonded grinding wheels.
4. Safety and Handling
4.1 Hazard Codes
C
4.1 Risk Statements
R34
4.1 Safety Statements
S26;S36/37/39;S45
4.1 Packing Group
I; II; III
4.1 Hazard Declaration
H319
4.1 RIDADR
UN3260
4.1 Safety Profile
Poison byintraperitoneal route. When heated todecomposition it emits very toxic fumes ofF, K2O, and BOx. Used in sand casting ofaluminum and magnesium, grinding, and inresinoid grindmg wheels. See alsoFLUORIDES and BORONCOMPOUNDS.
4.2 Caution Statement
P260, P261, P264, P270, P271, P280, P304+P340, P305+P351+P338, P312, P314, P337+P313, P403+P233, P405, P501
4.2 WGK Germany
1
4.2 RTECS
ED2800000
4.2 Report

Reported in EPA TSCA Inventory.

4.3 Safety

Poison by intraperitoneal route. When heated to decomposition it emits very toxic fumes of F?, K2O, and BOx. Used in sand casting of aluminum and magnesium, grinding, and in resinoid grinding wheels. See also FLUORIDES and BORON COMPOUNDS.
Safety Information of Potassium tetrafluoroborate (CAS NO.14075-53-7):
Hazard Codes: XiIrritant,CCorrosive
Risk Statements: 36/37/38-34?
R36/37/38:Irritating to eyes, respiratory system and skin.?
R34:Causes burns.??
Safety Statements: 37/39-26-45-36/37/39
S37/39:Wear suitable gloves and eye/face protection.?
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.?
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)?
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection.

4.4 Sensitive
Moisture Sensitive
4.5 Specification

?Potassium tetrafluoroborate , its CAS NO. is 14075-53-7, the synonyms are Potassium tetrafluoroborate(1-) ; Borate(1-), tetrafluoro-, potassium ; Avogadrite ; Boron potassium fluoride .

4.6 Toxicity
IPR-RAT LD50 240 mg kg-1
5. MSDS

2.Hazard identification

2.1 Classification of the substance or mixture

Not classified.

2.2 GHS label elements, including precautionary statements

Pictogram(s) No symbol.
Signal word

No signal word.

Hazard statement(s)

none

Precautionary statement(s)
Prevention

none

Response

none

Storage

none

Disposal

none

2.3 Other hazards which do not result in classification

none

8. Other Information
8.0 Production
1,000,000 - 10,000,000 lb
8.1 Manufacturing Info
All other chemical product and preparation manufacturing|Borate(1-), tetrafluoro-, potassium (1:1): ACTIVE|Borate(1-)-11B, tetrafluoro-, potassium (1:1): ACTIVE|PMN - indicates a commenced PMN (Pre-Manufacture Notices) substance.|Borate(1-)-10B, tetrafluoro-, potassium (1:1): ACTIVE
8.2 Usage
Potassium tetrafluoroborate is used as an active filler in the preparation of resin-bonded abrasives. It is also used for extraction, refining and processing of metals in the chemical industry. It finds application as an additive in the alloying industry and welding agent. Further, it is used in the production of fluxing agents for brazing and soldering.
8.3 Usage
Potassium tetrafluoroborate is used as an active filler in the preparation of resin-bonded abrasives. It is also used for extraction, refining and processing of metals in the chemical industry. It finds application as additive in alloying industry and welding agent. Further, it is used in the production of fluxing agents for brazing and soldering.
8.4 Merck
14,7686
8.5 Chemical Properties
It appears as white powder or gelatinous crystals. It has hygroscopicity with bitter taste. It is slightly soluble in water and hot ethanol, insoluble in cold ethanol.
8.6 Application
  • Used as the abrasive material of the thermosetting resin grinding wheel, the raw material of boron alloy, the fluxing agent of heat welding and brazing; it can also be used as the components of low chromic anhydride chrome and lead-tin alloy electrolyte.
  • Used as analytical reagents and fluxes, also for the production of boron trifluoride, abrasive materials for the aluminum and magnesium casting, electrochemical engineering and chemical testing.
  • Used as the fluxing agent of heat flux and brazing, and the raw material for the production of boron alloy using aluminum and magnesium casting; it acts as the filler in the heavy wheel using resin as abrasive adhesive. In the welding and fusion of silver, gold, stainless steel, it can clean up the dross of light metal. It is a raw material for the manufacture of boron trifluoride and other fluorine salts. Also used in electrochemical processes and reagents.
  • Used as fluxing agent; also used for the metallurgical industry and for the preparation of boron trifluoride as well as the raw materials of other fluorine salt.
  • Used as the resin finishing agents for textile printing and dyeing, improving agent of metal particle size and refining fluxes and the casting sand granules of the aluminum and magnesium alloy.
8.7 Chemical Properties
white odourlesss crystalline powder
8.8 Uses
Has been proposed as a flux for soldering and brazing; filler in resin-bonded grinding wheels.
8.9 Hazard
Toxic by ingestion.
8.10 Safety Profile
Poison by intraperitoneal route. When heated to decomposition it emits very toxic fumes of F, K2O, and BOx. Used in sand casting of aluminum and magnesium, grinding, and in resinoid grindmg wheels. See also FLUORIDES and BORON COMPOUNDS.
8.11 Purification Methods
Crystallise it from H2O (solubility% (temperature): 0.3 (3o), 0.45 (20o), 1.4 (40o), 6.27 (100o), and dry it under vacuum. It is a non-hygroscopic salt. A 10% solution is transparent blue at 100o, green at 90o and yellow at 60o. [V.rlander et al. Chem Ber 65 535 1932, Kwasnik in Handbook of Preparative Inorganic Chemistry (Ed. Brauer) Academic Press Vol I p 223 1963.]
9. Computational chemical data
  • Molecular Weight: 125.902g/mol
  • Molecular Formula: BF4K
  • Compound Is Canonicalized: True
  • XLogP3-AA: null
  • Exact Mass: 125.9666243
  • Monoisotopic Mass: 125.9666243
  • Complexity: 23
  • Rotatable Bond Count: 0
  • Hydrogen Bond Donor Count: 0
  • Hydrogen Bond Acceptor Count: 5
  • Topological Polar Surface Area: 0
  • Heavy Atom Count: 6
  • Defined Atom Stereocenter Count: 0
  • Undefined Atom Stereocenter Count: 0
  • Defined Bond Stereocenter Count: 0
  • Undefined Bond Stereocenter Count: 0
  • Isotope Atom Count: 0
  • Covalently-Bonded Unit Count: 2
  • CACTVS Substructure Key Fingerprint: AAADcQIAAcAAQAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAEAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAA==
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