3D Mol Similar

Ruthenium(III) chloride

Iupac Name：trichlororuthenium

CAS No.: 14898-67-0

Molecular Weight：207.42

Modify Date.: 2022-12-06 15:48

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1. Names and Identifiers

1.1 Name: Ruthenium(III) chloride
1.2 Synonyms: Active oxidative aluminum RutheniuM(III) chloride hydrate ReagentPlus(R) RUTHENIUM(III) CHLORIDE HYDRATE14898-67-0 Ruthenium(III)-chlorid-hydrat

1.3 CAS No.: 14898-67-0

1.4 EINECS(EC#): 604-667-4

1.5 Molecular Formula: Cl3Ru (isomer)

1.6 Inchi: InChI=1S/3ClH.Ru/h3*1H;/q;;;+3/p-3

1.7 InChkey: YBCAZPLXEGKKFM-UHFFFAOYSA-K

1.8 Canonical Smiles: [Cl-].[Cl-].[Cl-].[Ru+3]

1.9 Isomers Smiles: Cl[Ru](Cl)Cl

2. Properties

2.1 Density: 3.11 g/cm3

2.1 Melting point: >300°C

2.1 StorageTemp: Store at +5°C to +30°C.

3. Safety and Handling

3.1 Hazard Codes: C

3.1 Risk Statements: 34-52/53-22

3.1 Safety Statements: 26-36/37/39-45-61

3.1 Packing Group: III

3.1 Hazard Class: 8

3.1 RIDADR: UN 3260 8/PG 2

3.1 WGK Germany: 2

3.1 RTECS: VM2650000

4. MSDS

2.Hazard identification

2.1 Classification of the substance or mixture

Corrosive to metals, Category 1

Acute toxicity - Oral, Category 4

Skin corrosion, Category 1A

Serious eye damage, Category 1

Hazardous to the aquatic environment, long-term (Chronic) - Category Chronic 3

2.2 GHS label elements, including precautionary statements

Pictogram(s)
Signal word	Danger
Hazard statement(s)	H290 May be corrosive to metals H302 Harmful if swallowed H314 Causes severe skin burns and eye damage H318 Causes serious eye damage H412 Harmful to aquatic life with long lasting effects
Precautionary statement(s)
Prevention	P234 Keep only in original packaging. P264 Wash ... thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P260 Do not breathe dust/fume/gas/mist/vapours/spray. P280 Wear protective gloves/protective clothing/eye protection/face protection. P273 Avoid release to the environment.
Response	P390 Absorb spillage to prevent material damage. P301+P312 IF SWALLOWED: Call a POISON CENTER/doctor/\u2026if you feel unwell. P330 Rinse mouth. P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower]. P363 Wash contaminated clothing before reuse. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P310 Immediately call a POISON CENTER/doctor/\u2026 P321 Specific treatment (see ... on this label). P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Storage	P406 Store in a corrosion resistant/...container with a resistant inner liner. P405 Store locked up.
Disposal	P501 Dispose of contents/container to ...

2.3 Other hazards which do not result in classification

none

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5. Other Information

5.0 Merck: 14,8302

5.1 Chemical Properties: dark brown to black powder

5.2 Uses: Catalyzes the synthesis of 2-ethyl-3-methylquinolines from primary aromatic amines and triallylamine.1

5.3 Uses: Oxidation.Ruthenium(III) chloride hydrate is used as a catalyst for alkyne functionalization and oxidation reactions. It is used as key raw materials for the preparation of various ruthenium-based catalysts, including Grubbs? catalysts. It is utilized in the preparation of nanoparticulate ruthenium-aluminum oxyhydroxide catalyst, which is efficient for dehydrogenation of alcohols to the corresponding aldehydes. It is also involved in the synthesis of 2-ethyl-3-methylquinolines from primary aromatic amines and triallylamine.

5.4 Uses: Catalyzes the synthesis of 2-ethyl-3-methylquinolines from primary aromatic amines and triallylamine.

5.5 General Description: soluble form

5.6 Purification Methods: Dissolve the salt in H2O, filter and concentrate to crystallisation in the absence of air to avoid oxidation. Evaporate the solution in a stream of HCl gas while being heated just below its boiling point until a syrup is formed and finally to dryness at 80-100o and dried in a vacuum over H2SO4. When heated at 700o in the presence of Cl2 the insoluble -form is obtained [Grube in Handbook of Preparative Inorganic Chemistry (Ed. Brauer) Academic Press Vol II p 1598 1965, Carlsen et al. J Org Chem 46 3936 1981].

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CAS 14898-67-0 Ruthenium(III) chloride