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(TRIFLUOROMETHANE)SULFONYL TRIFLUOROMETHANESULFONATE 7561347, DT: 23.1 1.2016) RE-EXPORT EINECS 206-616-8 Methanesulfonic acid, trifluoro-, anhydride MFCD00000408 triflic anhydride Triflic anhydride solution TRIFLUORO METHANESULFONIC ANHYDRIDE TRIFLUOROMETHANE SULFONIC ANHYDRIDE TRIFLUOROMETHANE SULFONIC ANHYDRIDE(ORIG INAL IMPORT VIDE BE.NO TRIFLUOROMETHANESULFONIC ACID TRIFLUOROMETHANESULFONIC ACID ANHYDRIDE Trifluoromethanesulfonic anhydlladium(0) TRIFLUOROMETHANESULFONIC ANHYDRIDE (10 ML ) TRIFLUOROMETHANESULFONIC ANHYDRIDE (TRIFLIC ANHYDRIDE) TRIFLUOROMETHANESULFONIC ANHYDRIDE FOR SYNTHESIS Trifluoromethanesulfonic anhydride solution Trifluoromethanesulfonic anhydride solution 1 M in methylene chloride Trifluoromethanesulfonicanhydride TRIFLUOROMETHANE-SULFONICANHYDRIDE Trifluoromethanesulphonic acid anhydride Trifluoromethanesulphonic anhydride TRIFLUOROMETHANESULPHONICACIDANHYDRIDE TRIFLUOROMETHYLSULFONIC ANHYDRIDE
The Trifluoromethanesulfonic anhydride, with its?CAS registry number 358-23-6, has its IUPAC name of trifluoromethylsulfonyl trifluoromethanesulfonate. For being a kind of clear colorless to light brown liquid, it is sensitive to moisture and it could react violently with water. Besides, its product categories are including pharmacetical; Organic Fluorides. As to its usage, it is known to one of the strongest organic acids, which is widely used in pharmaceutical, chemical and other industries.
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The physical properties of this chemical are as below: (1)ACD/LogP: 2.12; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): 2.12; (4)ACD/LogD (pH 7.4): 2.12; (5)ACD/BCF (pH 5.5): 24.01; (6)ACD/BCF (pH 7.4): 24.01; (7)ACD/KOC (pH 5.5): 338.59; (8)ACD/KOC (pH 7.4): 338.59; (9)#H bond acceptors: 5; (10)#H bond donors: 0; (11)#Freely Rotating Bonds: 2; (12)Polar Surface Area: 94.27; (13)Index of Refraction: 1.358; (14)Molar Refractivity: 31.41 cm3; (15)Molar Volume: 142.7 cm3; (16)Polarizability: 12.45×10-24 cm3; (17)Surface Tension: 34.1 dyne/cm; (18)Density: 1.976 g/cm3; (19)Enthalpy of Vaporization: 30.98 kJ/mol; (20)Boiling Point: 82.6 °C at 760 mmHg; (21)Vapour Pressure: 86.8 mmHg at 25°C; (22)Exact Mass: 281.909134; (23)MonoIsotopic Mass: 281.909134; (24)Topological Polar Surface Area: 94.3; (25)Heavy Atom Count: 15; (26)Complexity: 370.
Use of this chemical: trifluoro-methanesulfonic acid could react to produce trifluoromethanesulfonic anhydride. This reaction could happen in the presence of the reagent of P2O5.
Production method of this chemical: tetrahydrofuran could react with trifluoromethanesulfonic anhydride to produce 1,4-bis-trifluoromethanesulfonyloxy-butane. This reaction could react in the presence of the solvent of CH2Cl2.
When you are dealing with this chemical, you should be very careful. For being corrosive, this chemical may destroy living tissue on contact and it will be very dangerous if by inhalation and in contact with skin. Besides, it may causes severe burns. Therefore, you should wear suitable protective clothing, gloves and eye/face protection. If in case of contact with eyes, rinse immediately with plenty of water and seek medical advice, and if in case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add - Never use water). And then if in case of accident or if you feel unwell seek medical advice immediately (show the label where possible). When you need to store it, keep this container dry.
In addition, you could convert the following datas into the molecular structure:
(1)Canonical SMILES: C(F)(F)(F)S(=O)(=O)OS(=O)(=O)C(F)(F)F
(2)InChI: InChI=1S/C2F6O5S2/c3-1(4,5)14(9,10)13-15(11,12)2(6,7)8
(3)InChIKey: WJKHJLXJJJATHN-UHFFFAOYSA-N??
Acute toxicity - Oral, Category 4
Skin corrosion, Category 1A
Pictogram(s) | ![]() ![]() |
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Signal word | Danger |
Hazard statement(s) | H302 Harmful if swallowed H314 Causes severe skin burns and eye damage |
Precautionary statement(s) | |
Prevention | P264 Wash ... thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P260 Do not breathe dust/fume/gas/mist/vapours/spray. P280 Wear protective gloves/protective clothing/eye protection/face protection. |
Response | P301+P312 IF SWALLOWED: Call a POISON CENTER/doctor/\u2026if you feel unwell. P330 Rinse mouth. P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower]. P363 Wash contaminated clothing before reuse. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P310 Immediately call a POISON CENTER/doctor/\u2026 P321 Specific treatment (see ... on this label). P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. |
Storage | P405 Store locked up. |
Disposal | P501 Dispose of contents/container to ... |
none
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Literatures:
Gramstad, T.; Haszeldine, R. N. Journal of the Chemical Society, 1957 , p. 4069 - 4079 ![]() Yield: ~1% |