White camphor oil
- Iupac Name：(1R,4R)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-one
- CAS No.: 8008-51-3
- Molecular Weight：152.23
- Modify Date.: 2022-11-11 22:52
- Introduction: Camphor is a colorless glassy solid. Penetrating, characteristic odor. White camphor oil is the first distillation fraction (about 20% of thecrude camphor oil). It is a colorless or almost colorless liquid with acineole-like odor.d2525 0.855–0.875; n20D 1.4670–1.4720; αD +16° to +28°; solubility: 1 volin 1 vol of 95% ethanol; solutions usually become cloudy on further dilution. In addition to monoterpene hydrocarbons, this oil contains up to 35%1,8-c
View more+
1. Names and Identifiers
- 1.1 Name
- White camphor oil
- 1.2 Synonyms
Camphor oil Camphor oil white CAMPHOR, JAPANESE, WHITE, OIL (CINNAMOMUM CAMPHORA (L.) NEES ET EBERM.) camphoraoilfromcinnamomumcamphora camphoroil,rectified camphoroilyellow Formosa camphor oil formosacamphoroil formoseoilofcamphor Japanese camphor oil japanese,oilofcamphor japanesecamphoroil Light camphor oil Light oil of camphor MFCD01770588 Oil of Camphor Oils, camphor
- 1.3 CAS No.
- 8008-51-3
- 1.4 CID
- 159055
- 1.5 EINECS(EC#)
- 295-980-1
- 1.6 Molecular Formula
- C10H16O (isomer)
- 1.7 Inchi
- InChI=1S/C10H16O/c1-9(2)7-4-5-10(9,3)8(11)6-7/h7H,4-6H2,1-3H3/t7-,10+/m1/s1
- 1.8 InChkey
- DSSYKIVIOFKYAU-XCBNKYQSSA-N
- 1.9 Canonical Smiles
- CC1(C2CCC1(C(=O)C2)C)C
- 1.10 Isomers Smiles
- C[C@@]12CC[C@@H](C1(C)C)CC2=O
2. Properties
- 2.1 Density
- 0.923 at 77 °F (USCG, 1999)
- 2.1 Melting point
- 353.8 °F (NTP, 1992)
- 2.1 Boiling point
- 171 °C(lit.)
- 2.1 Refractive index
- n20/D 1.468(lit.)
- 2.1 Flash Point
- 110 °F
- 2.2 VaporPhaseIRSpectra
- DIGILAB FTS-14
- 2.3 VaporDensity
- 5.24 (NTP, 1992) (Relative to Air)
- 2.4 Storage
- 2-8°C
- 2.5 Autoignition Temperature
- 870.8 °F (USCG, 1999)
- 2.6 Chemical Properties
- Camphor is a colorless glassy solid. Penetrating, characteristic odor.
- 2.7 Physical Properties
- A white viscous liquid.
- 2.8 Ionization Potential
- 8.76 eV
- 2.9 Odor Threshold
- Odor Threshold Low: 0.0026 [mmHg]
- 2.10 Water Solubility
- less than 1 mg/mL at 59° F (NTP, 1992)
- 2.11 StorageTemp
- 2-8°C
3. Use and Manufacturing
- 3.1 Potential Exposure
- Camphor, a natural product, is used asa plasticizer for cellulose esters and ethers; it is used in lacquers and varnishes; and in explosives and pyrotechnics formulations. It is used as a moth repellent and as a medicinal.
- 3.2 Shipping
- UN2717 Camphor, synthetic, Hazard Class: 4.1;Labels: 4.1-Flammable solid. UN1130 camphor oil, HazardClass: 3; Labels: 3-Flammable liquid
- 3.3 Waste Disposal
- ncineration of a solution in aflammable solven. White camphor oil Preparation Products And Raw materials Preparation Products
4. Safety and Handling
- 4.1 Symbol
- GHS02, GHS07
- 4.1 Hazard Codes
- Xi
- 4.1 Signal Word
- Warning
- 4.1 Risk Statements
- 10-36/38-38
- 4.1 Safety Statements
- A human poison by ingestion. Human systemic effects by ingestion: convulsions, tremors, and unspecified respiratory system effects. A skin irritant. Flammable liquid when exposed to heat or flame; can react with oxidizing materials. To fight fire, use foam, CO2, dry chemical, mist, fog. See also SAFROL and CAMPHOR.
- 4.1 Packing Group
- III
- 4.1 Fire Hazard
- Behavior in Fire: The solid often evaporates without first melting.
- 4.2 Hazard Class
- 3.2
- 4.2 Hazard Declaration
- H226-H315-H319
- 4.2 RIDADR
- UN 1130 3/PG 3
- 4.2 Safety Profile
- A human poison by ingestion. Human systemic effects by ingestion: convulsions, tremors, and unspecified respiratory system effects. A skin irritant. Flammable liquid when exposed to heat or flame; can react with oxidzing materials. To fight fire, use foam, CO2, dry chemical, mist, fog. See also SAFROL and CAMPHOR.
- 4.3 Caution Statement
- P305 + P351 + P338
- 4.3 Incompatibilities
- May form explosive mixture with air.Violent, possibly explosive, reaction with strong oxidizers,especially chromic anhydride, potassium permanganate.May accumulate static electrical charges, and may causeignition of its vapors.
- 4.4 WGK Germany
- 2
- 4.4 RTECS
- EX1490000
- 4.4 Safety
- A human poison by ingestion. Human systemic effects by ingestion: convulsions, tremors, and unspecified respiratory system effects. A skin irritant. Flammable liquid when exposed to heat or flame; can react with oxidizing materials. To fight fire, use foam, CO2, dry chemical, mist, fog. See also SAFROL and CAMPHOR.
- 4.5 Specification
-
Safety Statements:26-36-16
26:In case of contact with eyes, rinse immediately with plenty
of water and seek medical advice
36:Wear suitable protective clothing
16:Keep away from sources of ignition - No smoking
- 4.6 Toxicity
- Within 5 to 90 minutes after swallowing, the following may be noted: nausea and vomiting; feeling of warmth; headache; confusion, vertigo, excitement, restlessness, delirium, and hallucinations; increased muscular excitability, tremors, and jerky movements; epileptiform convulsions, followed by depression (convulsions sometimes occur early in the syndrome and may be severe, but they do not have the grave prognosis of strychnine convulsions); coma; central nervous depression may at times be the primary clinical response; death results from respiratory failure or from status epilepticus; slow convalescence (days or weeks), often with persistent gastric distress.
5. Other Information
- 5.0 Chemical Properties
- Camphor is a colorless glassy solid. Penetrating, characteristic odor.
- 5.1 General Description
- A colorless liquid with a characteristic odor. Flash point 125°F. Insoluble in water and generally less dense than water. Vapors heavier than air.
- 5.2 Air & Water Reactions
- Flammable. Insoluble in water.
- 5.3 Reactivity Profile
- White camphor oil containing ether can act as bases. They form salts with strong acids and addition complexes with Lewis acids. The complex between diethyl ether and boron trifluoride is an example. Ethers may react violently with strong oxidizing agents. In other reactions, which typically involve the breaking of the carbon-oxygen bond, ethers are relatively inert.
- 5.4 Health Hazard
- Within 5 to 90 minutes after swallowing, the following may be noted: nausea and vomiting; feeling of warmth; headache; confusion, vertigo, excitement, restlessness, delirium, and hallucinations; increased muscular excitability, tremors, and jerky movements; epileptiform convulsions, followed by depression (convulsions sometimes occur early in the syndrome and may be severe, but they do not have the grave prognosis of strychnine convulsions); coma; central nervous depression may at times be the primary clinical response; death results from respiratory failure or from status epilepticus; slow convalescence (days or weeks), often with persistent gastric distress.
- 5.5 Fire Hazard
- Behavior in Fire: The solid often evaporates without first melting.
- 5.6 Safety Profile
- A human poison by ingestion. Human systemic effects by ingestion: convulsions, tremors, and unspecified respiratory system effects. A skin irritant. Flammable liquid when exposed to heat or flame; can react with oxidzing materials. To fight fire, use foam, CO2, dry chemical, mist, fog. See also SAFROL and CAMPHOR.
- 5.7 Potential Exposure
- Camphor, a natural product, is used as a plasticizer for cellulose esters and ethers; it is used in lacquers and varnishes; and in explosives and pyrotechnics formulations. It is used as a moth repellent and as a medicinal.
- 5.8 First aid
- If this chemical gets into the eyes, remove any contact lenses at once and irrigate immediately for at least 15 minutes, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts the skin, remove contaminated clothing and wash immediately with soap and water. Seek medical attention immediately. If this chemical has been inhaled, remove from exposure, begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR if heart action has stopped. Transfer promptly to a medical facility. When this chemical has been swallowed, get medical attention. Give large quantities of water and induce vomiting. Do not make an unconscious person vomit.
- 5.9 Shipping
- UN2717 Camphor, synthetic, Hazard Class: 4.1; Labels: 4.1-Flammable solid. UN1130 camphor oil, Hazard Class: 3; Labels: 3-Flammable liquid
- 5.10 Incompatibilities
- May form explosive mixture with air. Violent, possibly explosive, reaction with strong oxidizers, especially chromic anhydride, potassium permanganate. May accumulate static electrical charges, and may cause ignition of its vapors.
- 5.11 Waste Disposal
- ncineration of a solution in a flammable solven.
6. Computational chemical data
- Molecular Weight: 152.23g/mol
- Molecular Formula: C10H16O
- Compound Is Canonicalized: True
- XLogP3-AA: 2.2
- Exact Mass: 152.120115130
- Monoisotopic Mass: 152.120115130
- Complexity: 217
- Rotatable Bond Count: 0
- Hydrogen Bond Donor Count: 0
- Hydrogen Bond Acceptor Count: 1
- Topological Polar Surface Area: 17.1
- Heavy Atom Count: 11
- Defined Atom Stereocenter Count: 2
- Undefined Atom Stereocenter Count: 0
- Defined Bond Stereocenter Count: 0
- Undefined Bond Stereocenter Count: 0
- Isotope Atom Count: 0
- Covalently-Bonded Unit Count: 1
- CACTVS Substructure Key Fingerprint: AAADceBwIAAAAAAAAAAAAAAAAAAAAYMAAAAwAAAAAAAAAAAAAAAAGgAAAAAADwSAgAACAAAAAAAIAIAQAAAAAAAAAAAAAAEAAAAAABIAAAAAAAAAAAAAAAEIiMCPgAAAAAAAAACAAAAAAAAAAQAACAAAAA==
7. Recommended Suppliers
-
- Products:Cosmetic Raw Materials,solvents,etc.
- Tel:86-311-66562153
- Email:Helen@crovellbio.com
-
- Products:We ZERchem, facing global High-tech pharmaceutical raw materials, high value-added new type intermediates fine chemicals custom synthesis, scale-up production and rare chemicals trade.
- Tel:+86-571-82512721
- Email:sales@zeerrui.com
-
- Products:Our company is an internationally oriented research based pharmaceutical company with headquarters located in Hangzhou,China.
- Tel:86-571-87758773
- Email:balas@utanpharma.com
-
- Products:chemical raw materials, veterinary drug raw materials, animal and plant extracts, pharmaceutical excipients, pharmaceutical products, food additives
- Tel:86-155-03787326
-
- Products:CBD,443998-65-0,16648-44-5,BMK,PMK
- Tel:86-191-31911055
8. Realated Product Infomation
skype
3YRS
