YTTRIUM CHLORIDE

Molecular Weight：195.26485

Modify Date.: 2022-11-22 18:35

Introduction:

Yttrium chloride is the inorganic chloride salt of yttrium(III) It has a role as a catalyst. It is an inorganic chloride and a yttrium molecular entity.

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1. Names and Identifiers

1.1 Name: YTTRIUM CHLORIDE
1.2 Synonyms: EINECS 233-801-0 MFCD00011470 YTTRIUM (III) CHLORIDE Yttrium (III) chloride, anhydrous Yttrium chloride 0.1 M Solution Yttrium chloride(III) Yttrium(Iii) Chloride Yttriumchlorideanhydrous

1.3 CAS No.: 10361-92-9

1.4 EINECS(EC#): 233-801-0

1.5 Molecular Formula: Cl3Y (isomer)

1.6 Inchi: InChI=1/3ClH.Y/h3*1H;/q;;;+3/p-3

1.7 InChIkey: PCMOZDDGXKIOLL-UHFFFAOYSA-K

1.8 Canonical Smiles: O.O.O.O.O.O.[Cl-].[Y+3]

1.9 Isomers Smiles: Cl[Y](Cl)Cl

2. Properties

2.1 Density: 2.18

2.1 Melting point: 100℃

2.1 Boiling point: °Cat760mmHg

2.1 Flash Point: °C

2.1 Precise Quality: 193.81200

2.1 PSA: 0.00000

2.1 logP: 2.06850

2.1 Appearance: White to pale yellow powder

2.2 Storage: Hygroscopic. Ambient temperatures.

2.3 Chemical Properties: Reddish-white, transparent, deliquescentprisms. D 2.18, decomposes at 100C. Solublein water and alcohol; insoluble in ether.

2.4 Color/Form: White to pale yellow

2.5 Water Solubility: soluble in water, ethanol and pyridine.

2.6 Stability: hygroscopic

2.7 StorageTemp: Inert atmosphere,Room Temperature

3. Use and Manufacturing

3.1 Usage: Analytical chemistry

4. Safety and Handling

4.1 Hazard Codes: Xi

4.1 Risk Statements: R36/37/38

4.1 Safety Statements: S26;S37/39

4.1 RIDADR: NONH for all modes of transport

4.1 Safety Profile: Poison byintraperitoneal route. When heated todecomposition it emits toxic fumes of Cl-.See also YTTRIUM and RARE EARTHS. YTTRIUM CHLORIDESupplier

4.2 WGK Germany: 3

4.2 RTECS: ZG3150000

4.2 Report: Reported in EPA TSCA Inventory.

4.3 Safety: Poison by intraperitoneal route. When heated to decomposition it emits toxic fumes of Cl⁻. See also YTTRIUM and RARE EARTHS.Safety information of Yttrium(III) chloride (CAS NO.10361-92-9):
Hazard Codes Xi
Risk Statements
36/37/38 Irritating to eyes, respiratory system and skin
Safety Statements
26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
37/39 Wear suitable gloves and eye/face protection
WGK Germany 3
RTECS ZG3150000

4.4 Sensitive: Hygroscopic

4.5 Specification: Yttrium(III) chloride is an ionic compound of yttrium and chlorine. It is a salt that is solid at room temperature, highly soluble in water, and deliquescent. YCl₃ in the solid state has a crystal structure with cubic close packed chloride ions and yttrium ions filling one third of the octahedral holes and the resulting YCl₆ octahedra sharing three edges with adjacent octahedra give a layer structure. This structure is shared by a range of compounds notably AlCl₃

4.6 Toxicity

1.	ipr-rat LD50:45 mg/kg	AMIHAB AMA Archives of Industrial Health. 16 (1957),475.
2.	ipr-mus LD50:88 mg/kg	AMIHAB AMA Archives of Industrial Health. 16 (1957),475.
3.	ipr-gpg LD50:85 mg/kg	AEHLAU Archives of Environmental Health. 5 (1962),437.

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5. MSDS

2.Hazard identification

2.1 Classification of the substance or mixture

Skin irritation, Category 2

Eye irritation, Category 2

Specific target organ toxicity \u2013 single exposure, Category 3

2.2 GHS label elements, including precautionary statements

Pictogram(s)
Signal word	Warning
Hazard statement(s)	H315 Causes skin irritation H319 Causes serious eye irritation H335 May cause respiratory irritation
Precautionary statement(s)
Prevention	P264 Wash ... thoroughly after handling. P280 Wear protective gloves/protective clothing/eye protection/face protection. P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P271 Use only outdoors or in a well-ventilated area.
Response	P302+P352 IF ON SKIN: Wash with plenty of water/... P321 Specific treatment (see ... on this label). P332+P313 If skin irritation occurs: Get medical advice/attention. P362+P364 Take off contaminated clothing and wash it before reuse. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337+P313 If eye irritation persists: Get medical advice/attention. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P312 Call a POISON CENTER/doctor/\u2026if you feel unwell.
Storage	P403+P233 Store in a well-ventilated place. Keep container tightly closed. P405 Store locked up.
Disposal	P501 Dispose of contents/container to ...

2.3 Other hazards which do not result in classification

none

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6. Synthesis Route

10361-92-9Total: 3 Synthesis Route

84556-33-2

10361-92-9 52 Suppliers

Literatures:
Inorganic Chemistry, , vol. 24, p. 3504 - 3505
Yield: null

84556-33-2

7647-01-0

7664-41-7 248 Suppliers

10361-92-9 52 Suppliers

Literatures:
Zeitschrift fuer Anorganische und Allgemeine Chemie, , vol. 621, p. 665 - 670
Yield: null

13709-49-4 68 Suppliers

7782-50-5

10361-92-9 52 Suppliers

Literatures:
Tr. Tomsk. Univ., , vol. 204, p. 82 - 85 C. A., , vol. 78, p. 131489 Sc: MVol.C3, 6.2.2.9.3.3, page 110 - 110
Yield: null

7. Precursor and Product

precursor:

13709-49-4

84556-33-2

product :

13709-49-4

8. Other Information

8.0 Usage: Yttrium(III) chloride is used as a precursor for titanium-containing ceramics. It is used as an analytical reagent, as a catalyst and in superconductors. It is also used in the production of yttrium alkyl alkoxide complexes.

8.1 Merck: 14,10107

8.2 Chemical Properties: Reddish-white, transparent, deliquescent prisms. D 2.18, decomposes at 100C. Soluble in water and alcohol; insoluble in ether.

8.3 Uses: Analytical chemistry

8.4 Safety Profile: Poison by intraperitoneal route. When heated to decomposition it emits toxic fumes of Cl-. See also YTTRIUM and RARE EARTHS.

8.5 Description: Yttrium(III) chloride is an inorganic compound of yttrium and chloride. It exists in two forms, the hydrate (YCl3(H2O)6) and an anhydrous form (YCl3). Both are colourless solids that are highly soluble in water and deliquescent.
Yttrium(III) chloride is used as a precursor for titanium-containing ceramics. It is used as an analytical reagent, as a catalyst and in superconductors. It is also used in the production of yttrium alkyl alkoxide complexes.

8.6 Acquired resistance: Yttrium(III) chloride, reacting with potassium alkoxotitanates, forms precursors for titanium-containing ceramics, It is used as an analytical reagent, as a catalyst and in superconductors. It is also used in the production of yttrium alkyl alkoxide complexes.

8.7 Uses: Yttrium chloride (YCl3) decomposes at the relatively low temperature of 100°C. This makes it useful as a reagent in chemical laboratories.

9. Recommended Suppliers

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YTTRIUM CHLORIDE