Zirconium hydroxide
- Iupac Name：zirconium(4+);tetrahydroxide
- CAS No.: 14475-63-9
- Molecular Weight：159.25
- Modify Date.: 2022-11-22 15:41
- Introduction: Zirconium hydroxide is used in glass colorants. The compound also is used to prepare zirconium oxide, sulfate, phosphate, and other salts.
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1. Names and Identifiers
- 1.1 Name
- Zirconium hydroxide
- 1.2 Synonyms
EINECS 238-472-7 MELcat XZO 1662 MELcat XZO 1903 MFCD00049635 R Zirconium Hydroxide XZO 1247/01 XZO 1501/09 XZO 632/03 XZO 681/01 XZO 706/03 XZO 880/01 XZO-632/03 Zirconic acid Zirconium hydroxide (Zr(OH)4) Zirconium hydroxide (Zr(OH)4), (T-4)- Zirconium tetrahydroxide Zirconium(2+) hydroxide (1:2) Zirconium(4+) hydroxide zirconium(4+),tetrahydroxide ZIRCONIUM(IV) HYDROXIDE zirconiumhydroxide(zr(oh)4)
- 1.3 CAS No.
- 14475-63-9
- 1.4 CID
- 84465
- 1.5 EINECS(EC#)
- 238-472-7; 235-770-9
- 1.6 Molecular Formula
- H4O4Zr (isomer)
- 1.7 Inchi
- InChI=1S/4H2O.Zr/h4*1H2;/q;;;;+4/p-4
- 1.8 InChkey
- HAIMOVORXAUUQK-UHFFFAOYSA-J
- 1.9 Canonical Smiles
- [OH-].[OH-].[OH-].[OH-].[Zr+4]
- 1.10 Isomers Smiles
- [OH-].[OH-].[OH-].[OH-].[Zr+4]
2. Properties
- 2.1 Density
- 3.25
- 2.1 Melting point
- 550°C, decomposes
- 2.1 Boiling point
- 100 °C at 760 mmHg
- 2.1 Precise Quality
- 157.91600
- 2.1 PSA
- 80.92000
- 2.1 logP
- -0.70720
- 2.1 Appearance
- DryPowder, WetSolid; WetSolid
- 2.2 Chemical Properties
- White, bulky, amorphous powder.Decomposes to ZrO2 at 550C. Soluble in dilutemineral acids; insoluble in water and alkalies.
- 2.3 Physical
- DryPowder, WetSolid
- 2.4 Water Solubility
- Insoluble in water ,Freely soluble in inorganic acids
3. Use and Manufacturing
- 3.1 GHS Classification
- Signal: Warning
GHS Hazard Statements
Aggregated GHS information provided by 28 companies from 2 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
H315 (100%): Causes skin irritation [Warning Skin corrosion/irritation]
H319 (100%): Causes serious eye irritation [Warning Serious eye damage/eye irritation]
H335 (100%): May cause respiratory irritation [Warning Specific target organ toxicity, single exposure; Respiratory tract irritation]
Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown.
Precautionary Statement Codes
P261, P264, P271, P280, P302+P352, P304+P340, P305+P351+P338, P312, P321, P332+P313, P337+P313, P362, P403+P233, P405, and P501
- 3.2 Usage
- Zirconium hydroxide is used in glass colorants. The compound also is used to prepare zirconium oxide, sulfate, phosphate, and other salts.
4. Safety and Handling
- 4.1 Symbol
- GHS07;
- 4.1 Hazard Codes
- Xi
- 4.1 Signal Word
- Warning
- 4.1 Risk Statements
- 36/37/38
- 4.1 Safety Statements
- 26-36
- 4.1 Hazard Declaration
- H315; H319; H335
- 4.1 RIDADR
- NONH for all modes of transport
- 4.1 Caution Statement
- P261-P305 + P351 + P338
- 4.1 WGK Germany
- 3
- 4.1 Safety
-
Hazard Codes: Xi .gif)
Risk Statements: 36/37/38
R 36/37/38:Irritating to eyes, respiratory system and skin.
Safety Statements: 26-36
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
S36:Wear suitable protective clothing
- 4.2 Specification
-
Zirconium hydroxide , its CAS NO. is 14475-63-9, the synonyms are Zirconiumhydroxide ; Zirconium(IV) hydroxide ; Zirconium tetrahydroxide ; ZirconiumhydroxideX H2O ; XZO-632/03 ; Zirconic acid .
5. MSDS
2.Hazard identification
2.1 Classification of the substance or mixture
Skin irritation, Category 2
Eye irritation, Category 2
Specific target organ toxicity \u2013 single exposure, Category 3
2.2 GHS label elements, including precautionary statements
| Pictogram(s) |  |
| Signal word | Warning |
| Hazard statement(s) | H315 Causes skin irritation H319 Causes serious eye irritation H335 May cause respiratory irritation |
| Precautionary statement(s) | |
| Prevention | P264 Wash ... thoroughly after handling. P280 Wear protective gloves/protective clothing/eye protection/face protection. P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P271 Use only outdoors or in a well-ventilated area. |
| Response | P302+P352 IF ON SKIN: Wash with plenty of water/... P321 Specific treatment (see ... on this label). P332+P313 If skin irritation occurs: Get medical advice/attention. P362+P364 Take off contaminated clothing and wash it before reuse. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337+P313 If eye irritation persists: Get medical advice/attention. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P312 Call a POISON CENTER/doctor/\u2026if you feel unwell. |
| Storage | P403+P233 Store in a well-ventilated place. Keep container tightly closed. P405 Store locked up. |
| Disposal | P501 Dispose of contents/container to ... |
2.3 Other hazards which do not result in classification
none
6. Other Information
- 6.0 Mesh Entry Terms
- zirconium hydroxide
- 6.1 Manufacturing Info
- All other basic inorganic chemical manufacturing|Zirconium hydroxide (Zr(OH)4), (T-4)-: ACTIVE
- 6.2 Uses
- Zirconium hydroxide is used in glass colorants. The compound also is used to prepare zirconium oxide, sulfate, phosphate, and other salts.
- 6.3 Chemical Properties
- White, bulky, amorphous powder.Decomposes to ZrO2 at 550C. Soluble in dilute mineral acids; insoluble in water and alkalies.
- 6.4 Uses
- In the pigment, dye, and glass industries.
7. Computational chemical data
- Molecular Weight: 159.25g/mol
- Molecular Formula: H4O4Zr
- Compound Is Canonicalized: True
- XLogP3-AA: null
- Exact Mass: 157.915657
- Monoisotopic Mass: 157.915657
- Complexity: 0
- Rotatable Bond Count: 0
- Hydrogen Bond Donor Count: 4
- Hydrogen Bond Acceptor Count: 4
- Topological Polar Surface Area: 4
- Heavy Atom Count: 5
- Defined Atom Stereocenter Count: 0
- Undefined Atom Stereocenter Count: 0
- Defined Bond Stereocenter Count: 0
- Undefined Bond Stereocenter Count: 0
- Isotope Atom Count: 0
- Covalently-Bonded Unit Count: 5
- CACTVS Substructure Key Fingerprint: AAADcYAAOAAAAAAAAQAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAACAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAA==
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