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ZIRCONIUM SILICATE structure
ZIRCONIUM SILICATE structure

ZIRCONIUM SILICATE

Iupac Name:zirconium(4+);silicate
CAS No.: 10101-52-7
Molecular Weight:183.305
Modify Date.: 2022-11-25 02:15
Introduction: Zirconium silicate (ZrSiO4) is one form of the mineral whose crystals when polished areknown as cubic zircons, which resemble diamond gemstones. View more+
1. Names and Identifiers
1.1 Name
ZIRCONIUM SILICATE
1.2 Synonyms

acorite auerbachite azorite=acorite EINECS 233-252-7 MFCD00085353 Silicic acid (H4-SiO4), zirconium(4+) salt (1:1) Silicicacid(H4SiO4),zirconium(4+)salt(1:1) ZIRCON Zirconium silicate: (Zirconium silicon oxide) ZIRCONIUM(+4)SILICATE Zirconium(4+) orthosilicate

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1.3 CAS No.
10101-52-7
1.4 CID
61775
1.5 EINECS(EC#)
233-252-7; 239-019-6
1.6 Molecular Formula
O4SiZr (isomer)
1.7 Inchi
InChI=1S/O4Si.Zr/c1-5(2,3)4;/q-4;+4
1.8 InChIkey
GFQYVLUOOAAOGM-UHFFFAOYSA-N
1.9 Canonical Smiles
[O-][Si]([O-])([O-])[O-].[Zr+4]
1.10 Isomers Smiles
[O-][Si]([O-])([O-])[O-].[Zr+4]
2. Properties
2.1 Density
4,56
2.1 Melting point
2550oC
2.1 Boiling point
oCat760mmHg
2.1 Refractive index
1.78-1.99
2.1 Flash Point
oC
2.1 Precise Quality
181.86100
2.1 PSA
92.24000
2.1 logP
-0.85600
2.1 Appearance
grey powder
2.2 Storage


2.3 Chemical Properties
grey powder
2.4 Physical Properties
Colorless tetragonal crystals (when pure); presence of impurities forms various colors; density 4.56 g/cm3; hardness 7.5 Mohs; dissociates to ZrO2 and SiO2 above 1,540°C; melts at 2,550°C; insoluble in water, acids, aqua regia, and alkalies; inert in most chemicals.
2.5 Color/Form
Yellow to orange
2.6 Odor
Odorless
2.7 Water Solubility
Insoluble in water, acids, alkali and aqua regia.
2.8 Stability
Stable.
3. Use and Manufacturing
3.1 Usage
Zirconium silicate (ZrSiO4) is one form of the mineral whose crystals when polished areknown as cubic zircons, which resemble diamond gemstones.
4. Safety and Handling
4.1 Symbol
GHS07
4.1 Hazard Codes
Xn
4.1 Signal Word
Warning
4.1 Risk Statements
R20;R36/37/38
4.1 Safety Statements
S26;S36
4.1 Hazard Declaration
H315-H319-H332-H335
4.1 RIDADR
NONH for all modes of transport
4.1 Caution Statement
P261-P305 + P351 + P338
4.1 WGK Germany
3
4.1 Safety

Hazard Codes?Zirconium silicate (CAS NO.10101-52-7): Xn
Risk Statements: 20-36/37/38
R20: Harmful by inhalation
R36/37/38: Irritating to eyes, respiratory system and skin.
Safety Statements: 26-36
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
S36: Wear suitable protective clothing
WGK Germany: 3

?

5. MSDS

2.Hazard identification

2.1 Classification of the substance or mixture

Not classified.

2.2 GHS label elements, including precautionary statements

Pictogram(s) No symbol.
Signal word

No signal word.

Hazard statement(s)

none

Precautionary statement(s)
Prevention

none

Response

none

Storage

none

Disposal

none

2.3 Other hazards which do not result in classification

none

6. Other Information
6.0 Usage
Zirconium silicate is used for manufacturing refractory materials for applications where resistance to corrosion by alkali materials is required. It is also used in production of some ceramics, enamels, and ceramic glazes. In enamels and glazes it serves as an opacifier. It can be also present in some cements. Another use of zirconium silicate is as beads for milling and grinding. Thin films of zirconium silicate and hafnium silicate produced by chemical vapor deposition. Potential alternative gate dielectric to silica.
6.1 Merck
14,10181
6.2 Physical Properties
Colorless tetragonal crystals (when pure); presence of impurities forms various colors; density 4.56 g/cm3; hardness 7.5 Mohs; dissociates to ZrO2 and SiO2 above 1,540°C; melts at 2,550°C; insoluble in water, acids, aqua regia, and alkalies; inert in most chemicals.
6.3 Production
Zirconium silicate occurs in nature as mineral zircon. Ore is mined from natural deposits and concentrated by various techniques (See Zirconium, Recovery). It is separated from sand by electrostatic and electromagnetic methods.
Also, the compound can be made by fusion of SiO2 and ZrO2 in an arc furnace, or by reacting a zirconium salt with sodium silicate in aqueous solution.
6.4 Chemical Properties
grey powder
6.5 Uses
In refractories, ceramics, glazes, cements, coatings for casting molds, polishing materials, gem stones, catalyst in alkyl and alkenyl hydrocarbon manufacture, in fritted glass filters, as stabilizer in silicone rubbers. In Europe in cosmetic creams and powders.
7. Computational chemical data
  • Molecular Weight: 183.305g/mol
  • Molecular Formula: O4SiZr
  • Compound Is Canonicalized: True
  • XLogP3-AA: null
  • Exact Mass: 181.861284
  • Monoisotopic Mass: 181.861284
  • Complexity: 19.1
  • Rotatable Bond Count: 0
  • Hydrogen Bond Donor Count: 0
  • Hydrogen Bond Acceptor Count: 4
  • Topological Polar Surface Area: 92.2
  • Heavy Atom Count: 6
  • Defined Atom Stereocenter Count: 0
  • Undefined Atom Stereocenter Count: 0
  • Defined Bond Stereocenter Count: 0
  • Undefined Bond Stereocenter Count: 0
  • Isotope Atom Count: 0
  • Covalently-Bonded Unit Count: 2
  • CACTVS Substructure Key Fingerprint: AAADcQAAOAgAAAAAAQAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAEAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAA==
8. Question & Answer
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10. Realated Product Infomation