Guidechem | China Chemical Manufacturers,suppliers,B2B Marketplace
Products
  • Products
  • Encyclopedia
  • Buy offers
  • Suppliers

Chemical Risk Phrases

Indication of Particular Risks

  1. R1:

    Explosive when dry

  2. R2:

    Risk of explosion by shock, friction, fire or other sources of ignition

  3. R3:

    Extreme risk of explosion by shock, friction, fire or other sources of ignition

  4. R4:

    Forms very sensitive explosive metallic compounds

  5. R5:

    Heating may cause an explosion

  6. R6:

    Explosive with or without contact with air

  7. R7:

    May cause fire

  8. R8:

    Contact with combustible material may cause fire

  9. R9:

    Explosive when mixed with combustible material

  10. R10:

    Flammable

  11. R11:

    Highly Flammable

  12. R12:

    Extremely Flammable

  13. R14:

    Reacts violently with water

  14. R15:

    Contact with water liberates extremely flammable gases

  15. R16:

    Explosive when mixed with oxidizing substances

  16. R17:

    Spontaneously flammable in air

  17. R18:

    In use may form flammable/explosive vapor-air mixture

  18. R19:

    May form explosive peroxides

  19. R20:

    Harmful by inhalation

  20. R21:

    Harmful in contact with skin

  21. R22:

    Harmful if swallowed

  22. R23:

    Toxic by inhalation

  23. R24:

    Toxic in contact with skin

  24. R25:

    Toxic if swallowed

  25. R26:

    Very Toxic by inhalation

  26. R27:

    Very Toxic in contact with skin

  27. R28:

    Very Toxic if swallowed

  28. R29:

    Contact with water liberates toxic gas

  29. R30:

    Can become highly flammable in use

  30. R31:

    Contact with acids liberates toxic gas

  31. R32:

    Contact with acids liberates very toxic gas

  32. R33:

    Danger of cumulative effects

  33. R34:

    Causes burns

  1. R35:

    Causes severe burns

  2. R36:

    Irritating to the eyes

  3. R37:

    Irritating to the respiratory system

  4. R38:

    Irritating to the skin

  5. R39:

    Danger of very serious irreversible effects

  6. R40:

    Limited evidence of a carcinogenic effect

  7. R41:

    Risk of serious damage to eyes

  8. R42:

    May cause sensitization by inhalation

  9. R43:

    May cause sensitization by skin contact

  10. R44:

    Risk of explosion if heated under confinement

  11. R45:

    May cause cancer

  12. R46:

    May cause heritable genetic damage

  13. R48:

    Danger of serious damage to health by prolonged exposure

  14. R49:

    May cause cancer by inhalation

  15. R50:

    Very Toxic to aquatic organisms

  16. R51:

    Toxic to aquatic organisms

  17. R52:

    Harmful to aquatic organisms

  18. R53:

    May cause long-term adverse effects in the aquatic environment

  19. R54:

    Toxic to flora

  20. R55:

    Toxic to fauna

  21. R56:

    Toxic to soil organisms

  22. R57:

    Toxic to bees

  23. R58:

    May cause long-term adverse effects in the environment

  24. R59:

    Dangerous for the ozone layer

  25. R60:

    May impair fertility

  26. R61:

    May cause harm to the unborn child

  27. R62:

    Possible risk of impaired fertility

  28. R63:

    Possible risk of harm to the unborn child

  29. R64:

    May cause harm to breast-fed babies

  30. R65:

    Harmful: May cause lung damage if swallowed

  31. R66:

    Repeated exposure may cause skin dryness or cracking

  32. R67:

    Vapors may cause drowsiness and dizziness

  33. R68:

    Possible risk of irreversible effects

Combination of Particular Risks

  1. R14/15:

    Reacts violently with water, liberating extremely flammable gases

  2. R15/29:

    Contact with water liberates toxic, extremely flammable gas

  3. R20/21:

    Harmful by inhalation and in contact with skin

  4. R20/21/22:

    Harmful by inhalation, in contact with skin and if swallowed

  5. R20/22:

    Harmful by inhalation and if swallowed

  6. R21/22:

    Harmful in contact with skin and if swallowed

  7. R23/24:

    Toxic by inhalation and in contact with skin

  8. R23/24/25:

    Toxic by inhalation, in contact with skin and if swallowed

  9. R23/25:

    Toxic by inhalation and if swallowed

  10. R24/25:

    Toxic in contact with skin and if swallowed

  11. R26/27:

    Very Toxic by inhalation and in contact with skin

  12. R26/27/28:

    Very Toxic by inhalation, in contact with skin and if swallowed

  13. R26/28:

    Very Toxic by inhalation and if swallowed

  14. R27/28:

    Very Toxic in contact with skin and if swallowed

  15. R36/37:

    Irritating to eyes and respiratory system

  16. R36/37/38:

    Irritating to eyes, respiratory system and skin

  17. R36/38:

    Irritating to eyes and skin

  18. R37/38:

    Irritating to respiratory system and skin

  19. R39/23:

    Toxic: danger of very serious irreversible effects through inhalation

  20. R39/23/24:

    Toxic: danger of very serious irreversible effects through inhalation in contact with skin

  21. R39/23/24/25:

    Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed

  22. R39/23/25:

    Toxic: danger of very serious irreversible effects through inhalation and if swallowed

  23. R39/24:

    Toxic: danger of very serious irreversible effects in contact with skin

  24. R39/24/25:

    Toxic: danger of very serious irreversible effects in contact with skin and if swallowed

  25. R39/25:

    Toxic: danger of very serious irreversible effects if swallowed

  26. R39/26:

    Very Toxic: danger of very serious irreversible effects through inhalation

  27. R39/26/27:

    Very Toxic: danger of very serious irreversible effects through inhalation and in contact with skin

  28. R39/26/27/28:

    Very Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed

  29. R39/26/28:

    Very Toxic: danger of very serious irreversible effects through inhalation and if swallowed

  30. R39/27:

    Very Toxic: danger of very serious irreversible effects in contact with skin

  31. R39/27/28:

    Very Toxic: danger of very serious irreversible effects in contact with skin and if swallowed

  32. R39/28:

    Very Toxic: danger of very serious irreversible effects if swallowed

  33. R42/43:

    May cause sensitization by inhalation and skin contact

  1. R48/20:

    Harmful: danger of serious damage to health by prolonged exposure through inhalation

  2. R48/20/21:

    Harmful: danger of serious damage to health by prolonged exposure through inhalation and in contact with skin

  3. R48/20/21/22:

    Harmful: danger of serious damage to health by prolonged exposure through inhalation, and in contact with skin and if swallowed

  4. R48/20/22:

    Harmful: danger of serious damage to health by prolonged exposure through inhalation and if swallowed

  5. R48/21:

    Harmful: danger of serious damage to health by prolonged exposure in contact with skin

  6. R48/21/22:

    Harmful: danger of serious damage to health by prolonged exposure in contact with skin and if swallowed

  7. R48/22:

    Harmful: danger of serious damage to health by prolonged exposure if swallowed

  8. R48/23:

    Toxic: danger of serious damage to health by prolonged exposure through inhalation

  9. R48/23/24:

    Toxic: danger of serious damage to health by prolonged exposure through inhalation and in contact with skin

  10. R48/23/24/25:

    Toxic: danger of serious damage to health by prolonged exposure through inhalation, in contact with skin and if swallowed

  11. R48/23/25:

    Toxic: danger of serious damage to health by prolonged exposure through inhalation and if swallowed

  12. R48/24:

    Toxic: danger of serious damage to health by prolonged exposure in contact with skin

  13. R48/24/25:

    Toxic: danger of serious damage to health by prolonged exposure in contact with skin and if swallowed

  14. R48/25:

    Toxic: danger of serious damage to health by prolonged exposure if swallowed

  15. R50/53:

    Very Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment

  16. R51/53:

    Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment

  17. R52/53:

    Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment

  18. R68/20:

    Harmful: possible risk of irreversible effects through inhalation

  19. R68/20/21:

    Harmful: possible risk of irreversible effects through inhalation and in contact with skin

  20. R68/20/21/22:

    Harmful: possible risk of irreversible effects through inhalation, in contact with skin and if swallowed

  21. R68/20/22:

    Harmful: possible risk of irreversible effects through inhalation and if swallowed

  22. R68/22:

    Harmful: possible risk of irreversible effects if swallowed

  23. R68/21:

    Harmful: possible risk of irreversible effects in contact with skin

  24. R68/21/22:

    Harmful: possible risk of irreversible effects in contact with skin and if swallowed

  25. R68/22:

    Harmful: possible risk of irreversible effects if swallowed

Chemical Safety Phrases

Combination of Safety Precautions

  1. S1:

    Keep locked up

  2. S2:

    Keep out of the reach of children

  3. S3:

    Keep in a cool place

  4. S4:

    Keep away from living quarters

  5. S5:

    Keep contents under ... (appropriate liquid to be specified by the manufacturer)

  6. S6:

    Keep under ... (inert gas to be specified by the manufacturer)

  7. 7:

    Keep container tightly closed

  8. S8:

    Keep container dry

  9. S9:

    Keep container in a well-ventilated place

  10. S12:

    Do not keep the container sealed

  11. S13:

    Keep away from food, drink and animal feeding stuffs

  12. S14:

    Keep away from ... (incompatible materials to be indicated by the manufacturer)

  13. S15:

    Keep away from heat

  14. S16:

    Keep away from sources of ignition - No smoking

  15. S17:

    Keep away from combustible material

  16. S18:

    Handle and open container with care

  17. S20:

    When using, do not eat or drink

  18. S21:

    When using, do not smoke

  19. S22:

    Do not breathe dust

  20. S23:

    Do not breathe gas/fumes/vapor/spray (appropriate wording to be specified by the manufacturer)

  21. S24:

    Avoid contact with skin

  22. S25:

    Avoid contact with eyes

  23. S26:

    In case of contact with eyes, rinse immediately with plenty of water and seek medical advice

  24. S27:

    Take off immediately all contaminated clothing

  25. S28:

    After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer)

  26. S29:

    Do not empty into drains

  27. S30:

    VNever add water to this product

  28. S33:

    Take precautionary measures against static discharges

  29. S35:

    This material and its container must be disposed of in a safe way

  30. S36:

    Wear suitable protective clothing

  1. S37:

    Wear suitable gloves

  2. S38:

    In case of insufficient ventilation, wear suitable respiratory equipment

  3. S39:

    Wear eye/face protection

  4. S40:

    To clean the floor and all objects contaminated by this material use ... (to be specified by the manufacturer)

  5. S41:

    In case of fire and/or explosion do not breathe fumes

  6. S42:

    During fumigation/spraying wear suitable respiratory equipment (appropriate wording to be specified)

  7. S43:

    In case of fire, use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add - Never use water)

  8. S45:

    In case of accident or if you feel unwell, seek medical advice immediately (show label where possible)

  9. S46:

    If swallowed, seek medical advice immediately and show this container or label

  10. S47:

    Keep at temperature not exceeding ... E C (to be specified by the manufacturer)

  11. S48:

    Keep wetted with ... (appropriate material to be specified by the manufacturer)

  12. S49:

    Keep only in the original container

  13. S50:

    Do not mix with ... (to be specified by the manufacturer)

  14. S51:

    Use only in well-ventilated areas

  15. S52:

    Not recommended for interior use on large surface areas

  16. S53:

    Avoid exposure - obtain special instruction before use

  17. S56:

    Dispose of this material and its container to hazardous or special waste collection point

  18. S57:

    Use appropriate container to avoid environmental contamination

  19. S59:

    Refer to manufacturer/supplier for information on recovery/recycling

  20. S60:

    This material and/or its container must be disposed of as hazardous waste

  21. S61:

    Avoid release to the environment. Refer to special instructions safety data sheet

  22. S62:

    If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label

  23. S63:

    In case of accident by inhalation, remove casualty to fresh air and keep at rest

  24. S64:

    If swallowed, rinse mouth with water (only if the person is conscious)

Indication of Safety Precautions

  1. S1/2:

    Keep locked up and out of the reach of children

  2. S3/7:

    Keep container tightly closed in a cool place

  3. S3/9/14:

    Keep in a cool well-ventilated place away from ... (incompatible materials to be indicated by manufacturer)

  4. S3/9/14/49:

    Keep only in the original container in a cool well-ventilated place away from ... (incompatible materials to be indicated by manufacturer)

  5. S3/9/49:

    Keep only in the original container in a cool well-ventilated place

  6. S3/14:

    Keep in a cool place away from ... (incompatible materials to be indicated by the manufacturer)

  7. S7/8:

    Keep container tightly closed and dry

  8. S7/9:

    Keep container tightly closed and at a temperature not exceeding ... °C (to be specified by manufacturer)

  9. S20/21:

    When using, do not eat, drink or smoke

  1. S24/25:

    Avoid contact with skin and eyes

  2. S27/28:

    After contact with skin, take off immediately all contaminated clothing and wash imediately with plenty of.... (to be specified by the manufacturer)

  3. S29/35:

    Do not empty into drains, dispose of this container and it's material in a safe way

  4. S29/56:

    Do not empty into drains, dispose of this material and its container to hazardous or special waste-collection point

  5. S36/37:

    Wear suitable protective clothing and gloves

  6. S36/37/39:

    Wear suitable protective clothing, gloves and eye/face protection

  7. S36/39:

    Wear suitable protective clothing and eye/face protection

  8. S37/39:

    Wear suitable gloves and eye/face protection

  9. S47/49:

    Keep only in the original container at temperature not exceeding ... °C (to be specified by manufacturer)

FLUKA BRAND F CODES

  1. F 1 Sensitive to air and humidity.
  2. F 2 Sensitive to air and CO2.
  3. F 3 Hygroscopic.
  4. F 4 Do not heat over …°C.
  5. 1 = 10 °C
  6. 2 = 20 °C
  7. 3 = 30 °C
  8. 4 = 40 °C
  9. 5 = 50 °C
  10. 6 = 60 °C
  11. 7 = 70 °C
  12. 8 = 80 °C
  13. 9 = 90 °C
  14. 10 = 100 °C
  15. 11 = 110 °C
  16. 12 = 120 °C
  17. 13 = 130 °C
  18. 14 = 140 °C
  19. 15 = 150 °C
  1. F 5 Dry material may explode.
  2. F 6 Reacts with acids.
  3. F 7 Keep under CO2.
  4. F 8 Photosensitive.
  5. F 9 Keep under nitrogen.
  6. F 10 Keep under argon.
  7. F 11 Keep under inert gas.
  8. F 12 Shake before use.
  9. F 13 Malodorous.
  10. F 14 Carefully observe warning label.
  11. F 15 Limited shelf life.
  12. F 16 Decomposes easily.
  13. F 17 May decompose by explosion.
  14. F 18 Must be handled by instructed people only.
  15. F 19 Lachrymator.
  16. F 20 Not to be swallowed.
  17. F 21 Sensitive to humidity.
  18. F 22 Keep dust-free in the dark.
  19. F 23 Sensitive to air.
  1. F 24 Spontaneously flammable with alcohol.
  2. F 25 Keep under CO.
  3. F 26 Before distillation test for absence of peroxides.
  4. F 27 Cool before opening.
  5. F 28 May become cloudy (Polyformaldehyde).
  6. F 29 Spontaneously flammable when dry.
  7. F 30 Sediment unavoidable.
  8. F 31 Do not puncture.
  9. F 32 Avoid contact with heavy metal salts especially iron salts.
  10. F 33 Causes fall in blood pressure.
  11. F 34 Sensitive to CO2.
  12. F 35 Narcotic effects.
  13. F 36 Extremely sensitive to air.

PICTOGRAMS AND HAZARD CODES

    • BBiohazard
    • CCorrosive
    • EExplosive
    • FHighly Flammable
    • F+Extremely Flammable
    • XnHarmful
    • XiIrritant
    • NDangerous for the environment
    • OOxidizing
    • RRadioactive
    • TToxic
    • T+Very Toxic