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Zinc gluconate(CAS No. 4468-02-4)

Zinc gluconate C12H22O14Zn (cas 4468-02-4) Molecular Structure

4468-02-4 Structure

Identification and Related Records

【Name】
Zinc gluconate
【CAS Registry number】
4468-02-4
【Synonyms】
(2R,3S,4R,5R)-2,3,4,5,6-pentahydroxyhexanoate
zinc(+2) cation
Zinc,bis(D-gluconato-kO1,kO2)-,(T-4)-
Zinc Gluconate USP Granular
Rubozinc
Zinc gluconate (USP)
Zinc, bis(D-gluconato-kO1,kO2)-
Zinc Gluconate USP / FCC
Zinc Gluconate FCC
Zinc Gluconate (FCC/BP/USP, food grade)
Magnesium Lactate(EP), Zinc Gluconate (USP) food grade
bis(D-gluconato-O1,O2)zinc
Zinc Gluconate (FCCIV, USP28, Food Additive)
Zinc gluconate USP31
Zinc Gluconate USP
【EINECS(EC#)】
224-736-9
【Molecular Formula】
C12H22O14Zn (Products with the same molecular formula)
【Molecular Weight】
455.68
【Inchi】
InChI=1/2C6H12O7.Zn/c2*7-1-2(8)3(9)4(10)5(11)6(12)13;/h2*2-5,7-11H,1H2,(H,12,13);/q;;+2/p-2/t2*2-,3-,4+,5-;/m11./s1
【Canonical SMILES】
C(C(C(C(C(C(=O)O)O)O)O)O)O.C(C(C(C(C(C(=O)O)O)O)O)O)O.[Zn]
【Isomers smiles】
C([C@H]([C@H]([C@@H]([C@H](C(=O)O)O)O)O)O)O.C([C@H]([C@H]([C@@H]([C@H](C
(=O)O)O)O)O)O)O.[Zn]
【MOL File】
4468-02-4.mol

Chemical and Physical Properties

【Appearance】
In its pure form, it is a white to off-white powder
【Melting Point】
131 DEG C
【Boiling Point】
673.6 °C at 760 mmHg
【Flash Point】
375.2 °C
【Solubilities】
100 g/L (20 C)
【Color/Form】
Powder or granular
【Stability】
Stable.
【HS Code】
29181600
【Storage temp】
Keep tightly closed in a cool place in a tightly closed container.
【Spectral properties】
SPECIFIC OPTICAL ROTATION: -3.49 TO +12.95 DEG @ 25 DEG C/D (WATER); MUTAROTATORY; SADTLER REFERENCE NUMBER: 8335 (IR, PRISM)
SPECIFIC OPTICAL ROTATION: -6.7 DEG @ 20 DEG C/D (CONCN= 1 G/100 ML WATER)
IR: 21802 (Sadtler Research Laboratories IR Grating Collection)
NMR: 11270 (Sadtler Research Laboratories Spectral Collection)
【Computed Properties】
Molecular Weight:457.71956 [g/mol]
Molecular Formula:C12H24O14Zn
H-Bond Donor:12
H-Bond Acceptor:14
Rotatable Bond Count:10
Tautomer Count:3
Exact Mass:456.045752
MonoIsotopic Mass:456.045752
Topological Polar Surface Area:277
Heavy Atom Count:27
Formal Charge:0
Complexity:385
Isotope Atom Count:0
Defined Atom Stereocenter Count:8
Undefined Atom Stereocenter Count:0
Defined Bond Stereocenter Count:0
Undefined Bond Stereocenter Count:0
Covalently-Bonded Unit Count:3

Safety and Handling

【Safety】

RTECS: ZH3750000
HS Code: 29181600

【Formulations/Preparations】
Descote zinc gluconate: Microencapsulated beaded powder containing 25% zinc gluconate & 75% edible coating
USP powder, granular & direct compressible grades
USP21 powder & fine granular grades
【Exposure Standards and Regulations】
This substance is generally recognized as safe when used as a nutrient and/or dietary supplement in accordance with good manufacturing or feeding practice.
【Disposal Methods】
SRP: At the time of review, criteria for land treatment or burial (sanitary landfill) disposal practices are subject to significant revision. Prior to implementing land disposal of waste residue (including waste sludge), consult with environmental regulatory agencies for guidance on acceptable disposal practices.

Use and Manufacturing

【Use and Manufacturing】
Methods of Manufacturing

MAY BE PREPARED FROM GLUCOSE BY ELECTROLYTIC OXIDN IN ALKALINE MEDIUM; BY CHEM OXIDN WITH HYPOBROMITES
BY HYDROLYSIS OF ALPHA-D-GLUCOSE WITH BROMINE PLUS H2SO4; BY GAMMA-IRRADIATION OF D-GLUCOSE;
AT PRESENT PRODUCED IN COMMERCIAL QUANTITIES BY FERMENTATIVE OXIDN OF ALDEHYDE GROUP IN GLUCOSE FROM CORN USING ASPERGILLUS NIGER, ASPERGILLUS FUMARICUS, ACETOBACTER ACETI, PENICILLIUM CHRYSOGENUM, & OTHER PENICILLIA.
CANNIZZARO REACTION ON GLUCOSE UNDER ALKALINE CONDITIONS FORMS SORBITOL AND GLUCONIC ACID
GLUCOSE IS REMOVED FROM LIQUID EGG WHITE, BEFORE DRYING /AND/ OXIDIZED TO GLUCONIC ACID USING A GLUCOSE-OXIDASE-CATALASE ENZYME SYSTEM. IN THIS METHOD, OXYGEN IS SUPPLIED BY THE ADDITION OF HYDROGEN PEROXIDE
DIRECT OXIDATION OF GLUCOSE IN THE PRESENCE OF A PALLADIUM CATALYST RESULTS IN THE FORMATION OF GLUCONIC ACID. THE DIRECT OXIDATION OF GLUCOSE TO GLUCONIC ACID BY OXYGEN ALSO TAKES PLACE IN THE PRESENCE OF THE ENZYME GLUCOSE OXIDASE.
U.S. Imports

(1984) 5.44X10+7 g
【Usage】
Dietary supplement and food additive.

Biomedical Effects and Toxicity

【Therapeutic Uses】
MEDICATION (VET): CATTLE DERMATOMYCOSIS, CAUSED BY TRICHOPHYTON VERRUCOSUM (TRICHOPHYTOSIS) WAS TREATED BY ORAL ADMIN OF PREPN CONTAINING 20-70% ZINC GLUCONATE, 2-10% SULFUR, 0.2-1% VITAMIN A (106 IU), 2-6% METHIONINE, & INERT CARRIER SUCH AS CALCIUM CARBONATE OR FLOUR.
DIETARY SUPPLEMENT & FOOD ADDITIVE; VITAMIN TABLETS
EXPTL USE: ZINC GLUCONATE ADDED TO SUBOPTIMAL DOSES OF ORTHO-GYNOL JELLY OR DELFEN CREAM IMPROVES VAGINAL CONTRACEPTIVE EFFICACY OF THESE PRODUCTS. [WILLIAMS WL; CONTRACEPTION 22 (6): 659-72 (1980)]
【Biomedical Effects and Toxicity】
(99)TCM-LABELED GLUCONATE WAS ACCUMULATED RELATIVELY EARLY IN THE KIDNEY, AND ESP IN THE URINARY TRACT.

Supplier Location

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