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Home> Hot Product Listed M   > Mercury

Mercury

CAS No.:7439-97-6
EINECS(EC#):231-106-7
Molecular Weight:200.59
Molecular Formula:Hg (Products with the same molecular formula)
MOL File:7439-97-6.mol
Names and Identifiers
Properties
Appearance
silver liquid
Density
13.54
Melting Point
-38.9℃
Boiling Point
356.5℃
Flash Point
无意义
Water
insoluble in water
Solubilities
insoluble in water
Stability
Stable. Incompatible with strong acids, sodium thiosulfate, ammonium hydroxide.
Storage temp
Poison room
Safety and Handling
Hazard Codes
T:Toxic
Risk Statements
R23;R33;R50/53
Safety Statements
S45;S60;S61;S7
HazardClass
8
Safety

Poison by inhalation. Human systemic effects by inhalation: wakefulness, muscle weakness, anorexia, headache, tinnitus, hypermotility, diarrhea, liver changes, dermatitis, fever. An experimental teratogen. Experimental reproductive effects. Questionable carcinogen with experimental tumorigenic data. Human mutation data reported. Used in dental applications, electronics, and chemical synthesis.
May explode on contact with 3-bromopropyne, alkynes + silver perchlorate, ethylene oxide, lithium, methylsilane + oxygen (explodes when shaken), peroxyformic acid, chlorine dioxide, tetracarbonylnickel + oxygen. May react with ammonia to form an explosive product. Mixtures with methyl azide are shock- and spark-sensitive explosives. The vapor ignites on contact with boron diiodophosphide. Reacts violently with acetylenic compounds (e.g., acetylene, sodium acetylide, 2-butyne-1,4-diol + acid), metals (e.g., aluminum, calcium, potassium, sodium, rubidium, exothermic formation of amalgams), Cl2, ClO2, CH3N3, Na2C2, nitromethane. Incompatible with methyl azide, oxidants. When heated to decomposition it emits toxic fumes of Hg.
Hazard Codes:? TToxic?,NDangerous?,XnHarmful?,CCorrosive
Risk Statements:? 25-48/21/22-51/53-50/53-33-23-20/21/22-34-36/37/38-23/24/25
R25 :Toxic if swallowed.
R48/21/22:Harmful: danger of serious damage to health by prolonged exposure in contact with skin and if swallowed.
R51/53:Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R50/53:Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.?
R33:Danger of cumulative effects.?
R23 :Toxic by inhalation.?
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed.?
R34:Causes burns.?
R36/37/38:Irritating to eyes, respiratory system and skin.
R23/24/25:Toxic by inhalation, in contact with skin and if swallowed.
Safety Statements:? 7-45-60-61-36-36/37/39-26-36/37?
S7:Keep container tightly closed.?
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)?
S60:This material and its container must be disposed of as hazardous waste.?
S61:Avoid release to the environment. Refer to special instructions / safety data sheets.?
S36:Wear suitable protective clothing.?
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection.?
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.?
S36/37:Wear suitable protective clothing and gloves.
RIDADR:? UN 3289 6.1/PG 2
WGK Germany:? 3
RTECS:? OV4550000
F:? 10
HazardClass:? 8
PackingGroup:? III

PackingGroup
III
Transport
UN2809
Specification

? Mercury (CAS NO.7439-97-6)? can be called for? CCRIS 1578 ; Caswell No. 546 ; Colloidal mercury ; EPA Pesticide Chemical Code 052301 ; HSDB 1208 ; Hydrargyrum ; KWIK ; Liquid silver ; Mercure ; Mercurio ; Mercury vapor ; Mercury, metallic ; Metallic mercury ; NCI-C60399 ; Quecksilber ; Quick silver ; Quicksilver ; RCRA waste number U151 ; UN 2024 (liquid compounds) ; UNII-FXS1BY2PGL and so on. It is silvery liquid metal, insoluble in water.

Report

Mercury and its compounds are on the Community Right-To-Know List.

Reach Info
This substance has been officially registered by enterprises.
ECHA (EU chemicals Management Agency) published the completed registration file as follows:
Completed registration file:
Registered as ubmitted Total tonnage band  
FULL JOINT 100_1000 view >
Registered companies:
Registrant / Supplier details Latest dossier received
DELA GmbH 2010
Kummer:Umweltkommunikation GmbH 2010
more >
MSDS

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SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 15, 2017

Revision Date: Aug 15, 2017

1.Identification

1.1 GHS Product identifier

Product name mercury atom

1.2 Other means of identification

Product number -
Other names Mercure

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only. Inorganic substances
Uses advised against no data available

1.4 Supplier's details

Company WWW.GuideChem.COM
Address 8F, Block C, No.3 Building, Zijin Plaza, No.701, Gudun Road, Hangzhou, Zhejiang 310030, China
Telephone +86-571-89739798
Fax 86(21)54365166

1.5 Emergency phone number

Emergency phone number +86-571-89739798
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

2.Hazard identification

2.1 Classification of the substance or mixture

Acute toxicity - Inhalation, Category 2

Specific target organ toxicity \u2013 repeated exposure, Category 1

Hazardous to the aquatic environment, short-term (Acute) - Category Acute 1

Hazardous to the aquatic environment, long-term (Chronic) - Category Chronic 1

Reproductive toxicity, Category 1B

2.2 GHS label elements, including precautionary statements

Pictogram(s)
Signal word

Danger

Hazard statement(s)

H330 Fatal if inhaled

H372 Causes damage to organs through prolonged or repeated exposure

H410 Very toxic to aquatic life with long lasting effects

H360D

Precautionary statement(s)
Prevention

P260 Do not breathe dust/fume/gas/mist/vapours/spray.

P271 Use only outdoors or in a well-ventilated area.

P284 [In case of inadequate ventilation] wear respiratory protection.

P264 Wash ... thoroughly after handling.

P270 Do not eat, drink or smoke when using this product.

P273 Avoid release to the environment.

P201 Obtain special instructions before use.

P202 Do not handle until all safety precautions have been read and understood.

P280 Wear protective gloves/protective clothing/eye protection/face protection.

Response

P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.

P310 Immediately call a POISON CENTER/doctor/\u2026

P320 Specific treatment is urgent (see ... on this label).

P314 Get medical advice/attention if you feel unwell.

P391 Collect spillage.

P308+P313 IF exposed or concerned: Get medical advice/ attention.

Storage

P403+P233 Store in a well-ventilated place. Keep container tightly closed.

P405 Store locked up.

Disposal

P501 Dispose of contents/container to ...

2.3 Other hazards which do not result in classification

none

3.Composition/information on ingredients

3.1 Substances

Chemical name Common names and synonyms CAS number EC number Concentration
mercury atom mercury atom 7439-97-6 none 100%

4.First-aid measures

4.1 Description of necessary first-aid measures

General advice

Consult a physician. Show this safety data sheet to the doctor in attendance.

If inhaled

Fresh air, rest. Artificial respiration may be needed. Refer for medical attention.

In case of skin contact

Remove contaminated clothes. Rinse and then wash skin with water and soap. Refer for medical attention .

In case of eye contact

First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.

If swallowed

Refer for medical attention .

4.2 Most important symptoms/effects, acute and delayed

No immediate symptoms. As poisoning becomes established, slight muscular tremor, loss of appetite, nausea, and diarrhea are observed. Psychic, kidney, and cardiovascular disturbances may occur. (USCG, 1999)

4.3 Indication of immediate medical attention and special treatment needed, if necessary

Basic Treatment: Establish a patent airway. Suction if necessary. Watch for signs of respiratory insufficiency and assist ventilations if necessary. Administer oxygen by nonrebreather mask at 10 to 15 L/min. Monitor for pulmonary edema and neat if necessary ... . Monitor for shock and treat if necessary ... . Anticipate seizures and treat if necessary ... . For eye contamination, flush eyes immediately with available water. Irrigate each eye continuously with normal saline during transport ... . Do not use emetics. For ingestion, rinse mouth and administer 5 ml/kg up to 200 ml of water for dilution if the patient can swallow, has a strong gag reflex, and does not drool. Administer activated charcoal ... . /Mercury and related compounds/

5.Fire-fighting measures

5.1 Extinguishing media

Suitable extinguishing media

Excerpt from ERG Guide 172 [Gallium and Mercury]: Use extinguishing agent suitable for type of surrounding fire. Do not direct water at the heated metal. (ERG, 2016)

5.2 Specific hazards arising from the chemical

Behavior in Fire: Not flammable (USCG, 1999)

5.3 Special protective actions for fire-fighters

Wear self-contained breathing apparatus for firefighting if necessary.

6.Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

Use personal protective equipment. Avoid dust formation. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust. For personal protection see section 8.

6.2 Environmental precautions

Evacuate danger area! Consult an expert! Personal protection: chemical protection suit including self-contained breathing apparatus. Ventilation. Do NOT let this chemical enter the environment. Collect leaking and spilled liquid in sealable non-metallic containers as far as possible. Do NOT wash away into sewer.

6.3 Methods and materials for containment and cleaning up

The following treatment processes have shown possible applicability for spill countermeasures: clarification/sedimentation >99% removal; clarification/ sedimentation with chemical addition: (alum) >62% removal, (alum, polymer) 88% removal, (lime) >96% removal, (BaCl2) 87% removal, and (polymer) 99% removal.

7.Handling and storage

7.1 Precautions for safe handling

Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Avoid exposure - obtain special instructions before use.Provide appropriate exhaust ventilation at places where dust is formed. For precautions see section 2.2.

7.2 Conditions for safe storage, including any incompatibilities

Provision to contain effluent from fire extinguishing. Separated from food and feedstuffs. Well closed.Storage temperature: Ambient; Venting: Open

8.Exposure controls/personal protection

8.1 Control parameters

Occupational Exposure limit values

no data available

Biological limit values

no data available

8.2 Appropriate engineering controls

Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday.

8.3 Individual protection measures, such as personal protective equipment (PPE)

Eye/face protection

Safety glasses with side-shields conforming to EN166. Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).

Skin protection

Wear impervious clothing. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique(without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it.

Respiratory protection

Wear dust mask when handling large quantities.

Thermal hazards

no data available

9.Physical and chemical properties

Physical state silver liquid
Colour Silver-white, heavy, mobile, liquid metal; solid mercury is tin-white
Odour Odorless
Melting point/ freezing point -38.9\u00baC
Boiling point or initial boiling point and boiling range 356.5\u00baC
Flammability Not combustible. Gives off irritating or toxic fumes (or gases) in a fire.
Lower and upper explosion limit / flammability limit no data available
Flash point no data available
Auto-ignition temperature Not flammable (USCG, 1999)
Decomposition temperature no data available
pH no data available
Kinematic viscosity 1.55 mPa.sec (15.5 millipoise) at 20\u00b0C
Solubility Insoluble (NIOSH, 2016)
Partition coefficient n-octanol/water (log value) 0.62
Vapour pressure <0.01 mm Hg ( 20 \u00b0C)
Density and/or relative density 13.54
Relative vapour density 7 (vs air)
Particle characteristics no data available

10.Stability and reactivity

10.1 Reactivity

no data available

10.2 Chemical stability

SLIGHTLY VOLATILE AT ORDINARY TEMP; WHEN PURE, DOES NOT TARNISH ON EXPOSURE TO AIR AT ORDINARY TEMP, BUT WHEN HEATED TO NEAR BOILING POINT, SLOWLY OXIDIZES TO MERCURIC OXIDE (HGO)

10.3 Possibility of hazardous reactions

Vapors are heavier than air and will collect and stay in poorly-ventilated or low-lying areas.Hazardous concentrations may develop quickly in enclosed, poorly-ventilated, or low-lying areas.MERCURY forms an explosive acelylide when mixed with acetylene. Can form explosive compounds with ammonia (a residue resulting from such a reaction exploded when an attempt was made to clean it off a steel rod [Chem. Eng. News 25:2138. 1947]. Chlorine dioxide (also other oxidants, such as: chlorine, bromine, nitric acid, performic acid), and mercury explode when mixed [Mellor 2, Supp. 1:381. 1956]. Methyl azide in the presence of mercury is potentially explosive [Can. J. Chem. 41:1048. 1963]. Ground mixtures of sodium carbide and mercury can react vigorously [Mellor 5:848. 1946-47]. Ammonia forms explosive compounds with gold, mercury, or silver. (Eggeman, Tim. "Ammonia". Kirk-Othmer Encyclopedia of Chemical Technology. John Wiley & Sons, Inc. 2001.).

10.4 Conditions to avoid

no data available

10.5 Incompatible materials

Ground mixtures of sodium carbide and mercury, aluminum, lead, or iron can react vigorously.

10.6 Hazardous decomposition products

DANGEROUS WHEN HEATED, IT EMITS HIGHLY TOXIC FUMES.

11.Toxicological information

Acute toxicity

  • Oral: no data available
  • Inhalation: no data available
  • Dermal: no data available

Skin corrosion/irritation

no data available

Serious eye damage/irritation

no data available

Respiratory or skin sensitization

no data available

Germ cell mutagenicity

no data available

Carcinogenicity

EPA: Elemental mercury - Not classifiable as to its carcinogenicity. There is inadequate or no human and animal evidence of carcinogenicity. Methyl mercury & mercuric chloride - Possible hum. IARC: Metallic & inorganic mercury - Not classifiable as to carcinogenicity to humans; Methyl mercury - Possibly carcinogenic to humans. NTP: Not evaluated

Reproductive toxicity

Elemental mercury Studies on the reproductive and developmental effects of elemental mercury in humans have shown mixed results. One study did not see an association between mercury exposure and miscarriages, while another revealed an increase in the rate of spontaneous abortions. Another study showed a higher than expected frequency of birth defects, which was not confirmed in a fourth study. (1,) Inorganic Mercury No information is available on the reproductive or developmental effects of inorganic mercury in humans. Animal studies have reported effects including alterations in testicular tissue, increased resorption rates, and abnormalities of development. (1,,) Methyl mercury A large number of human studies on the systemic effects of methyl mercury have been carried out. This is the result of two large scale poisoning incidents in Japan and Iraq and several epidemiologic studies investigating populations that consume large quantities of fish. (1,2) Oral exposure to methyl mercury has been observed to produce significant developmental effects in humans. Infants born to women who ingested high concentrations of methyl mercury exhibited CNS effects, such as mental retardation, ataxia, deafness, constriction of the visual field, blindness, and cerebral palsy. At lower methyl mercury concentrations, developmental delays and abnormal reflexes were noted. (1,,) Considerable new data on the health effects of methyl mercury are becoming available. Large studies of fish and marine mammal consuming populations in Seychelles and Faroe Islands are being carried out. Smaller scale studies also describe effects around the U.S. Great Lakes. (1,)

STOT-single exposure

no data available

STOT-repeated exposure

no data available

Aspiration hazard

no data available

12.Ecological information

12.1 Toxicity

  • Toxicity to fish: no data available
  • Toxicity to daphnia and other aquatic invertebrates: no data available
  • Toxicity to algae: no data available
  • Toxicity to microorganisms: no data available

12.2 Persistence and degradability

METHYLMERCURY IS FORMED NATURALLY IN AQUATIC AND TERRESTRIAL ENVIRONMENTS FROM ELEMENTAL MERCURY. ... METHYLATION IS LIKELY TO OCCUR IN UPPER SEDIMENTARY LAYERS OF SEA OR LAKE BOTTOMS.

12.3 Bioaccumulative potential

Upon entering an aqueous system, virtually any mercurial cmpd may be microbially converted to methylmercury. /Mercurial cmpd/

12.4 Mobility in soil

no data available

12.5 Other adverse effects

no data available

13.Disposal considerations

13.1 Disposal methods

Product

The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems.

Contaminated packaging

Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. Controlled incineration with flue gas scrubbing is possible for combustible packaging materials.

14.Transport information

14.1 UN Number

ADR/RID: UN2809 IMDG: UN2809 IATA: UN2809

14.2 UN Proper Shipping Name

ADR/RID: MERCURY
IMDG: MERCURY
IATA: MERCURY

14.3 Transport hazard class(es)

ADR/RID: 6.1 IMDG: 6.1 IATA: 6.1

14.4 Packing group, if applicable

ADR/RID: II IMDG: II IATA: II

14.5 Environmental hazards

ADR/RID: yes IMDG: yes IATA: yes

14.6 Special precautions for user

no data available

14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code

no data available

15.Regulatory information

15.1 Safety, health and environmental regulations specific for the product in question

Chemical name Common names and synonyms CAS number EC number
mercury atom mercury atom 7439-97-6 none
European Inventory of Existing Commercial Chemical Substances (EINECS) Listed.
EC Inventory Listed.
United States Toxic Substances Control Act (TSCA) Inventory Listed.
China Catalog of Hazardous chemicals 2015 Listed.
New Zealand Inventory of Chemicals (NZIoC) Listed.
Philippines Inventory of Chemicals and Chemical Substances (PICCS) Listed.
Vietnam National Chemical Inventory Listed.
Chinese Chemical Inventory of Existing Chemical Substances (China IECSC) Listed.

16.Other information

Information on revision

Creation Date Aug 15, 2017
Revision Date Aug 15, 2017

Abbreviations and acronyms

  • CAS: Chemical Abstracts Service
  • ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
  • RID: Regulation concerning the International Carriage of Dangerous Goods by Rail
  • IMDG: International Maritime Dangerous Goods
  • IATA: International Air Transportation Association
  • TWA: Time Weighted Average
  • STEL: Short term exposure limit
  • LC50: Lethal Concentration 50%
  • LD50: Lethal Dose 50%
  • EC50: Effective Concentration 50%

References

  • IPCS - The International Chemical Safety Cards (ICSC), website: http://www.ilo.org/dyn/icsc/showcard.home
  • HSDB - Hazardous Substances Data Bank, website: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm
  • IARC - International Agency for Research on Cancer, website: http://www.iarc.fr/
  • eChemPortal - The Global Portal to Information on Chemical Substances by OECD, website: http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en
  • CAMEO Chemicals, website: http://cameochemicals.noaa.gov/search/simple
  • ChemIDplus, website: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp
  • ERG - Emergency Response Guidebook by U.S. Department of Transportation, website: http://www.phmsa.dot.gov/hazmat/library/erg
  • Germany GESTIS-database on hazard substance, website: http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp
  • ECHA - European Chemicals Agency, website: https://echa.europa.eu/

Disclaimer: The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. We as supplier shall not be held liable for any damage resulting from handling or from contact with the above product.

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