Products
  • Products
  • Cas lib
  • Buy offers
  • Encyclopedia
  • Msds lib
  • Synthesis
  • Reach Info
  • Suppliers
Home> Hot Product Listed 2   > 2-Propenoic acid, homopolymer

2-Propenoic acid, homopolymer

CAS No.:9003-01-4
EINECS(EC#):202-415-4
Molecular Weight:72.06
Molecular Formula:(C3H4O2)n (Products with the same molecular formula)
MOL File:9003-01-4.mol
Names and Identifiers
Synonyms

Jurymer AC 10SHPGood-rite K 700Cyagard 266Gran Up PC 121Arasorb 750Eulysine SGood-rite K 702Jurymer AC 103APJurymer AC 10A 10HJunlon AC 10SHGood-rite 732Acrylic acid homopolymerJunlon 110Aquafeed 600JIP500Jurymer AC 10LHJunlon 10LGlascol E 15HydroplusJurymer AC 10LPBS 960Carbopol EX 473HL 415Jurymer 10SHPGood-rite K722F 443HF05 (acrylic polymer)AW 36Aron A 10LLCarbopol 9420Alcosperse 602TGAcryl AG 1100Alcosperse 465Euderm Grund 25AAquatreat AR 7HGood-rite K-XP 10Jurymer AC 10CSHCrilat X1815AZGood-rite K-XP 11HM 10AAqualic HL 321Acumer 1540Glascol E 5Good-rite XP 97Carbopol ISX 1794Glascol E 7Dispex C 40Bevaloid 6778Alcosperse 630BS 2150GE 1903Good-rite K 37Acrylic acid resinJurymerAC 106Carbochelate HM 10AAcrysol A 5Alcosperse 409Aron A 10UAcrysol A 3Junlon PW 110Acrysol A 1Glascol D 15C 480HF 05Junlon PW 111AqualicR-HLAS 7503Aqualic AS 58Arasorb S 100FAcrytex W 240Acrylic acidpolymerAron A 10AC 10LPCoatex DE 185AC 10LHPAqualic HL 580Aron HM 110ASS 2Acryl AG1000Geropon DAAcrysol LMW 20XAC 45CarboxypolymethyleneAcusol 445Aquatreat AR 6BS 9960Dispersant 5027Aron A 10HA 10LLJurymer AC 10HPAQ 2559Diper 1227AC 10HAcumer 9932Jurymer AC 10PAC 10LCarboset GA 1594Jurymer AC 10MJurymer AC 10LJurymer AC10MPGood-rite K 752Jurymer AC 10HAcumer 1530Acrysol AC5Carbopol 3402-Propenoic acid, homopolymerAcrylicacid, polymers (8CI)AQ 3930Good-rite K-XP 18Hiprint DAGlascol S 19Aqualic H-ASGR-FJunlon PW 10Good-rite XP 44Jurymer AC 10SLGC ConditionerHiviswako 304Jurymer AC 10SHAron A30LLJurymer 108HaJurymer AC 10LHPAccusol 440Carboset 515Aron 10HGood-rite WS 801Jurymer A 10SLBS 985Carbopol 9402AS 58ArespolAqualic HL 415Carbopol 679Colloids 119/50A 10SLDeoxylyte DY-ADuraconeCSPAlcoprint PTF-Z 328Alcosperse602AColloid 209Aqualic DL400Acryl AG 1200Aron 104

Inchi
InChI=1/C3H4O2/c1-2-3(4)5/h2H,1H2,(H,4,5)
InChkey
NIXOWILDQLNWCW-UHFFFAOYSA-N
Canonical Smiles
C=CC(=O)O
Properties
Appearance
Colorless viscous liquid.
Density
1.09 (30% aq.)
Melting Point
106
Boiling Point
116 °C
Refractive Index
n20/D 1.442
Flash Point
61.6 oC
Solubilities
Miscible with alcohol, and ether
Miscible with ethanol, ethyl ether; soluble in acetone, benzene, carbon tetrachloride
Miscible with chloroform
Miscible with water /1X10+6 mg/L/ at 25 deg C
Color/Form
Volatile liquid
Colorless liquid
Colorless liquid or solid (below 55 degrees F)
Stability
Stable under normal temperatures and pressures.
Storage temp
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
Spectral properties
Index of refraction: 1.4224 at 20 deg C/D
Index of refraction: 1.4185 at 25 deg C
SADTLER REFERENCE NUMBER: 11017 (IR, PRISM); MAX ABSORPTION (METHANOL): 252 NM (LOG E= 1.96)
IR: 4287 (Coblentz Society Spectral Collection)
UV: 2994 (Sadtler Research Laboratories Spectral Collection)
Raman: 11 (Sadtler Research Laboratories Spectral Collection)
1H NMR: 5298 (Sadtler Research Laboratories Spectral Collection)
MASS: 302 (NIST/EPA/MSDC Mass Spectral Database, 1990 version)
Safety and Handling
Hazard Codes
C; T; Xi
Risk Statements
45-46-34-36/37/38
Safety Statements
S24/25
Safety

Safety Information of?Poly(acrylic acid) (CAS NO.9003-01-4):
Hazard Codes:C ,T ,Xi
Risk Statements:45-46-34-36/37/38
45:May cause cancer
46:May cause heritable genetic damage
34:Causes burns
36/37/38:Irritating to eyes, respiratory system and skin
Safety Statements:53-45-36-27-26
53:Avoid exposure - obtain special instruction before use
45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible)
36:Wear suitable protective clothing
27:Take off immediately all contaminated clothing
26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
RIDADR:UN 3265 8/PG 3
WGK Germany:3
RTECS:AT4680000

Skin, Eye, and Respiratory Irritations
Irritating to skin, eye, and respiratory system.
Cleanup Methods
SRP: Wastewater from contaminant suppression, cleaning of protective clothing/equipment, or contaminated sites should be contained and evaluated for subject chemical or decomposition product concentrations. Concentrations shall be lower than applicable environmental discharge or disposal criteria. Alternatively, pretreatment and/or discharge to a permitted wastewater treatment facility is acceptable only after review by the governing authority and assurance that "pass through" violations will not occur. Due consideration shall be given to remediation worker exposure (inhalation, dermal and ingestion) as well as fate during treatment, transfer and disposal. If it is not practicable to manage the chemical in this fashion, it must be evaluated in accordance with EPA 40 CFR Part 261, specifically Subpart B, in order to determine the appropriate local, state and federal requirements for disposal.
Spill Handling: Evacuate and restrict persons not wearing protective equipment from area of spill or leak until cleanup is complete. Remove all ignition sources. Cover spill with soda ash or sodium bicarbonate. Mix and add water. Neutralize and flush into sewer. Collect powdered material in the most convenient and safe manner and deposit in sealed containers. Ventilate area of spill or leak after clean-up is complete. Keep acrylic acid out of a confined space, such as a sewer, because of the possibility of an explosion, unless the sewer is designed to prevent the build-up of explosive concentrations. It may be necessary to contain and dispose of this chemical as a hazardous waste. If material or contaminated runoff enters waterways, notify downstream users of potentially contaminated waters.
Wastewater containing acrylic monomers is treated by neutralization and polymerization using hydrogen peroxide as a catalyst. Thus, propylene oxidn wastewater containing 2.75% acrylic acid and 45.1 g chemical oxygen demand/l was heated to 90 degree C, and a 70% aq soln of hydrogen peroxide (hydrogen peroxide - acrylic acid ratio 1:4) was added. After stirring 3 hr, powdered lime was added to pH 8.75. The precipitate was filtered out, and the treated effluent contained 16.2 g chemical oxygen demand/l, a reduction of 64%.
Sizing agents in wastewater are eliminated by either chemical and physical, or biological treatment. Polyacrylates ... in wastewaters are treated by coagulation-flocculation with removal rates of 83.8. ... Natural products, such as maize starch and polyvinyl alcohol (PVA) treated through activated sludge show chemical oxygen demand removal rates > 80 and 42%; biological oxygen demand removal rates > 92.7 and 46.0%, respectively.
Photosensitive waste soln containing poly(vinyl alcohol), acrylic acid monomer and polymer, polyoxyalkylene glycol acrylate resing and a surfactant was treated with potassium persulfate, irradiated, and filtered. The filtrate was flocculated with alum and the sulfate ion SO4(2-) precipitated by barium carbonate and calcium hydroxide.
Transport
UN 3265 8/PG 3
Fire Fighting Procedures
Use dry chemical, carbon dioxide, or alcohol foam extinguishers. Vapors are heavier than air and will collect in low areas. Vapors may travel long distances to ignition sources and flashback. Vapors in confined areas may explode when exposed to fire. Storage containers and parts of containers may rocket great distances, in many directions. In advanced or massive fires, fire fighting should be done from a safe distance or from a protected location. If a leak or spill has not ignited, use water spray to disperse the vapors. Water spray may be used to flush spills away from exposures and to dilute spills to nonflammable mixtures. If material or contaminated runoff enters waterways, notify downstream users of potentially contaminated waters. Notify local health and fire officials and pollution control agencies. From a secure, explosion-proof location, use water spray to cool exposed containers. If cooling streams are ineffective (venting sound increases in volume and pitch, tank discolors or shows any signs of deforming), withdraw immediately to a secure position.
If material on fire or involved in fire: Do not extinguish fire unless flow can be stopped. Use water in flooding quantities as fog. Solid streams of water may be ineffective. Cool all affected containers with flooding quantities of water. Apply water from as far a distance as possible. Use "alcohol" foam, dry chemical or carbon dioxide. Use water spray to knock-down vapors. /Acrylic acid, stabilized/
Evacuation: If fire becomes uncontrollable or container is exposed to direct flame - consider evacuation of one-third (1/3) mile radius. /Acrylic acid, stabilized/
If a fire occurs in or close to a tank farm containing acrylic acid, tanks and pipes should be cooled by spraying with water in order to prevent the acid from polymerizing.
Fire Potential
Flammable liquid. ... A fire hazard when exposed to heat or flame.
Formulations/Preparations
Acrylic acid is commercially available in US in 2 grades: (a) technical grade for esterification and polymerization, and (b) glacial grade for production of water-sol resins. Typical commercial glacial acrylic acid contains 98.0% by wt acrylic acid, max of 0.5% by wt water and 0.045-0.055 mg/kg (ppm) of inhibitor ...
Grade: Technical (esterification and polymerization grades); glacial (97%).
... 200 ppm /monomethyl ether of hydroquinone/ is needed /as inhibitor/ for acrylic acid.
Grades or purity: Technical: 94.0%; glacial: 98.0-99.5%
DOT Emergency Guidelines
/GUIDE 132P: FLAMMABLE LIQUIDS - CORROSIVE/ Fire or Explosion: Flammable/combustible materials. May be ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. Those substances designated with a "P" may polymerize explosively when heated or involved in a fire. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water. /Acrylic acid, stabilized/
/GUIDE 132P: FLAMMABLE LIQUIDS - CORROSIVE/ Health: May cause toxic effects if inhaled or ingested/swallowed. Contact with substance may cause severe burns to skin and eyes. Fire will produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution. /Acrylic acid, stabilized/
/GUIDE 132P: FLAMMABLE LIQUIDS - CORROSIVE/ Public Safety: CALL Emergency Response Telephone Number ... As an immediate precautionary measure, isolate spill or leak area for at least 50 meters (150 feet) in all directions. Keep unauthorized personnel away. Stay upwind. Keep out of low areas. Ventilate closed spaces before entering. /Acrylic acid, stabilized/
/GUIDE 132P: FLAMMABLE LIQUIDS - CORROSIVE/ Protective Clothing: Wear positive pressure self-contained breathing apparatus (SCBA). Wear chemical protective clothing that is specifically recommended by the manufacturer. It may provide little or no thermal protection. Structural firefighters' protective clothing is recommended for fire situations ONLY; it is not effective in spill situations where direct contact with the substance is possible. /Acrylic acid, stabilized/
/GUIDE 132P: FLAMMABLE LIQUIDS - CORROSIVE/ Evacuation: ... Fire: If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. /Acrylic acid, stabilized/
/GUIDE 132P: FLAMMABLE LIQUIDS - CORROSIVE/ Fire: Some of these materials may react violently with water. Small fires: Dry chemical, CO2, water spray or alcohol-resistant foam. Large fires: Water spray, fog or alcohol-resistant foam. Move containers from fire area if you can do it without risk. Dike fire control water for later disposal; do not scatter the material. Do not get water inside containers. Fire involving tanks or car/trailer loads: Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. Cool containers with flooding quantities of water until well after fire is out. Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. ALWAYS stay away from tanks engulfed in fire. For massive fire, use unmanned hose holders or monitor nozzles; if this is impossible, withdraw from area and let fire burn. /Acrylic acid, stabilized/
/GUIDE 132P: FLAMMABLE LIQUIDS - CORROSIVE/ Spill or Leak: Fully encapsulating, vapor protective clothing should be worn for spills and leaks with no fire. ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). All equipment used when handling the product must be grounded. Do not touch or walk through spilled material. Stop leak if you can do it without risk. Prevent entry into waterways, sewers, basements or confined areas. A vapor suppressing foam may be used to reduce vapors. Absorb with earth, sand or other non-combustible material and transfer to containers ... Use clean non-sparking tools to collect absorbed material. Large spills: Dike far ahead of liquid spill for later disposal. Water spray may reduce vapor; but may not prevent ignition in closed spaces. /Acrylic acid, stabilized/
/GUIDE 132P: FLAMMABLE LIQUIDS - CORROSIVE/ First Aid: Move victim to fresh air. Call 911 or emergency medical service. Give artificial respiration if victim is not breathing. Do not use mouth-to-mouth method if victim ingested or inhaled the substance; give artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Administer oxygen if breathing is difficult. Remove and isolate contaminated clothing and shoes. In case of contact with substance, immediately flush skin or eyes with running water for at least 20 minutes. In case of burns, immediately cool affected skin for as long as possible with cold water. Do not remove clothing if adhering to skin. Keep victim warm and quiet. Effects of exposure (inhalation, ingestion or skin contact) to substance may be delayed. Ensure that medical personnel are aware of the material(s) involved and take precautions to protect themselves. /Acrylic acid, stabilized/
Exposure Standards and Regulations
Homopolymers and copolymers of acrylic acid are indirect food additives for use only a component of adhesives.
Reactivities and Incompatibilities
Violent reaction with strong oxidizers. Incompatible with sulfuric acid, caustics, ammonia, amines, isocyanates, alkylene oxides, epichlorohydrin, toluene diamine, oleum, pyridine, methyl pyridine, n-methyl pyrrolidone, 2-methyl-6-ether aniline, aniline, ethylene diamine, ethyleneimine, and 2-aminoethanol. Severely corrodes carbon steel and iron; attacks other metals. May accumulate static electrical charges and may cause ignition of its vapors.
Mixing acrylic acid and oleum in a closed container caused the temp and pressure to increase.
React readily with electrophilic, free-radical, and nucleophilic agent
Acrylic acid is a strong corrosive agent to many metals, such as unalloyed steel, copper, and brass. Frequently the hydrolysis of such metallic materials generates a deep discoloration in acrylic acid. Polyvalent metal salts formed during hydrolytic reactions could also induce polymerization. Therefore, under no circumstances should acrylic acid be stored or transported with equipment which contains the above-mentioned metals. Acrylic acid does not affect stainless steel.
Other Preventative Measures
SRP: The scientific literature for the use of contact lenses by industrial workers is inconsistent. The benefits or detrimental effects of wearing contact lenses depend not only upon the substance, but also on factors including the form of the substance, characteristics and duration of the exposure, the uses of other eye protection equipment, and the hygiene of the lenses. However, there may be individual substances whose irritating or corrosive properties are such that the wearing of contact lenses would be harmful to the eye. In those specific cases, contact lenses should not be worn. In any event, the usual eye protection equipment should be worn even when contact lenses are in place.
SRP: Contaminated protective clothing should be segregated in a manner that results in no direct personal contact by personnel who handle, dispose of, or clean the clothing. Quality assurance procedures to confirm the efficacy of the cleaning procedures should be implemented prior to the decontaminated protective clothing being returned for reuse by the workers. Contaminated clothing (including shoes/socks) should not be taken home at end of shift, but should remain at employee's place of work for cleaning.
If material not on fire and not involved in fire: Keep sparks, flames, and other sources of ignition away. Keep material out of water sources and sewers. Build dikes to contain flow as necessary. Use water spray to knock-down vapors. Neutralize spilled material with crushed limestone, soda ash, or lime. /Acrylic acid, stabilized/
Personnel protection: Avoid breathing vapors. Keep upwind. Avoid bodily contact with the material. ... Do not handle broken packages unless wearing appropriate personal protective equipment. Wash away any material which may have contacted the body with copious amounts of water or soap and water. If contact with the mateial anticipated, wear appropriate chemical protect clothing. Approach fire with caution. /Acrylic acid, stabilized/
Safety shower and/or eye fountain may be required.
... Hazard is the generation of considerable exothermic heat in some of the reactions, so that high pressures & temp may develop. This danger ... should be borne in mind when designing plant. Awareness of the dangers and of good engineering design are essential to safety. Employees should be instructed about the necessity of cleansing the skin if it is contaminated by materials which are irritants or skin-absorbed. With careful design, however, and complete enclosure of those processes where toxic chemicals or intermediates occur, dangerous exposures can be avoided. /Acrylic acid & derivatives/
Contact lenses should not be worn when working with this chemical.
The worker should immediately wash the skin when it becomes contaminated.
Work clothing that becomes wet or significantly contaminated should be removed and replaced.
Protective Equipment and Clothing
Protection required for safe handling of acrylic acid and esters commonly includes use of impervious gloves, shoe soles, and clothing ... .
Suitable protective clothing and self-contained respiratory protective apparatus should be available for use of those who may have to rescue persons overcome by fumes.
/Wear/ rubber gloves if exposed to wet material; acid goggles or face shield for splash exposure ...
Wear appropriate personal protective clothing to prevent skin contact.
Wear appropriate eye protection to prevent eye contact.
Eyewash fountains should be provided in areas where there is any possibility that workers could be exposed to the substance; this is irrespective of the recommendation involving the wearing of eye protection.
Facilities for quickly drenching the body should be provided within the immediate work area for emergency use where there is a possibility of exposure. [Note: It is intended that these facilities should provide a sufficient quantity or flow of water to quickly remove the substance from any body areas likely to be exposed. The actual determination of what constitutes an adequate quick drench facility depends on the specific circumstances. In certain instances, a deluge shower should be readily available, whereas in others, the availability of water from a sink or hose could be considered adequate.]
Specification

First Aid Measures of Poly(acrylic acid)r (CAS NO.9003-01-4):
Eyes:Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:Get medical aid. Wash mouth out with water.
Inhalation:Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Storage of Carbomer (CAS NO.9003-01-4):
Store in a cool, dry place. Store in a tightly closed container.

Octanol/Water Partition Coefficient
log Kow = 0.35
Report

?IARC Cancer Review: Group 3 IMEMDT ?? IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 7 (1987),p. 56.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.:?) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) ; Human No Adequate Data IMEMDT ?? IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 19 (1979),p. 47.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.:?) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) ; Animal No Adequate Data IMEMDT ?? IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 19 (1979),p. 47.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.:?) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) .

Disposal Methods
Generators of waste (equal to or greater than 100 kg/mo) containing this contaminant, EPA hazardous waste number U008, must conform with USEPA regulations in storage, transportation, treatment and disposal of waste.
Incineration. 100-500 ppm potassium permanganate will degrade acrylic acid to a hydroxy acid which can then be disposed of at a sewage treatment.
Burn in approved incinerator. Recommendable methods: Incineration. Not recommendable methods: Landfill and evaporation. Peer-review: Small amounts: Dissolve in large amounts of water and wash down sewer. (Peer-review conclusions of an IRPTC expert consultation (May 1985))
Acrylic acid is a waste chemical stream constituent which may be subjected to ultimate disposal by controlled incineration.
Good candidate for liquid injection incineration, with a temperature range of 650 to 1,600 deg C and a residence time of 0.1 to 2 seconds. A good candidate for rotary kiln incineration, with a temperature range of 820 to 1,600 deg C and a residence time of seconds. Also, it is a good candidate for fluidized bed incineration, with a temperature range of 450 to 980 deg C and a residence time of seconds.
The following wastewater treatment technologies have been investigated for acrylic acid: Concentration process: Biological treatment.
The following wastewater treatment technologies have been investigated for acrylic acid: Concentration process: Activated carbon.
Reach Info
This substance has been officially registered by enterprises.
ECHA (EU chemicals Management Agency) published the completed registration file as follows:
Completed registration file:
Registered as ubmitted Total tonnage band  
FULL JOINT 10_100 view >
Registered companies:
Registrant / Supplier details Latest dossier received
more >
MSDS

Download/Modify | Technical supported by XiXisys.com. For US version, EU version (23 languages) and more, please refer to xixisys.com/en/sds/search

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 17, 2017

Revision Date: Aug 17, 2017

1.Identification

1.1 GHS Product identifier

Product name poly(acrylic acid) macromolecule

1.2 Other means of identification

Product number -
Other names Acrylic acid polymer

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

Company WWW.GuideChem.COM
Address 8F, Block C, No.3 Building, Zijin Plaza, No.701, Gudun Road, Hangzhou, Zhejiang 310030, China
Telephone +86-571-89739798
Fax 86(21)54365166

1.5 Emergency phone number

Emergency phone number +86-571-89739798
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

2.Hazard identification

2.1 Classification of the substance or mixture

Not classified.

2.2 GHS label elements, including precautionary statements

Pictogram(s) No symbol.
Signal word

No signal word.

Hazard statement(s)

none

Precautionary statement(s)
Prevention

none

Response

none

Storage

none

Disposal

none

2.3 Other hazards which do not result in classification

none

3.Composition/information on ingredients

3.1 Substances

Chemical name Common names and synonyms CAS number EC number Concentration
poly(acrylic acid) macromolecule poly(acrylic acid) macromolecule 9003-01-4 none 100%

4.First-aid measures

4.1 Description of necessary first-aid measures

General advice

Consult a physician. Show this safety data sheet to the doctor in attendance.

If inhaled

If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.

In case of skin contact

Wash off with soap and plenty of water. Consult a physician.

In case of eye contact

Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.

If swallowed

Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.

4.2 Most important symptoms/effects, acute and delayed

no data available

4.3 Indication of immediate medical attention and special treatment needed, if necessary

no data available

5.Fire-fighting measures

5.1 Extinguishing media

Suitable extinguishing media

Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.

5.2 Specific hazards arising from the chemical

no data available

5.3 Special protective actions for fire-fighters

Wear self-contained breathing apparatus for firefighting if necessary.

6.Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

Use personal protective equipment. Avoid dust formation. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust. For personal protection see section 8.

6.2 Environmental precautions

Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided.

6.3 Methods and materials for containment and cleaning up

Pick up and arrange disposal. Sweep up and shovel. Keep in suitable, closed containers for disposal.

7.Handling and storage

7.1 Precautions for safe handling

Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Avoid exposure - obtain special instructions before use.Provide appropriate exhaust ventilation at places where dust is formed. For precautions see section 2.2.

7.2 Conditions for safe storage, including any incompatibilities

Store in cool place. Keep container tightly closed in a dry and well-ventilated place.

8.Exposure controls/personal protection

8.1 Control parameters

Occupational Exposure limit values

no data available

Biological limit values

no data available

8.2 Appropriate engineering controls

Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday.

8.3 Individual protection measures, such as personal protective equipment (PPE)

Eye/face protection

Safety glasses with side-shields conforming to EN166. Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).

Skin protection

Wear impervious clothing. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique(without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it.

Respiratory protection

Wear dust mask when handling large quantities.

Thermal hazards

no data available

9.Physical and chemical properties

Physical state Colorless viscous liquid.
Colour no data available
Odour no data available
Melting point/ freezing point 106\u00baC
Boiling point or initial boiling point and boiling range 116\u00b0C
Flammability no data available
Lower and upper explosion limit / flammability limit no data available
Flash point 100\u00b0C
Auto-ignition temperature no data available
Decomposition temperature no data available
pH no data available
Kinematic viscosity no data available
Solubility no data available
Partition coefficient n-octanol/water (log value) no data available
Vapour pressure no data available
Density and/or relative density 1.15g/mLat 25\u00b0C
Relative vapour density no data available
Particle characteristics no data available

10.Stability and reactivity

10.1 Reactivity

no data available

10.2 Chemical stability

Stable under recommended storage conditions.

10.3 Possibility of hazardous reactions

no data available

10.4 Conditions to avoid

no data available

10.5 Incompatible materials

no data available

10.6 Hazardous decomposition products

no data available

11.Toxicological information

Acute toxicity

  • Oral: no data available
  • Inhalation: no data available
  • Dermal: no data available

Skin corrosion/irritation

no data available

Serious eye damage/irritation

no data available

Respiratory or skin sensitization

no data available

Germ cell mutagenicity

no data available

Carcinogenicity

no data available

Reproductive toxicity

no data available

STOT-single exposure

no data available

STOT-repeated exposure

no data available

Aspiration hazard

no data available

12.Ecological information

12.1 Toxicity

  • Toxicity to fish: no data available
  • Toxicity to daphnia and other aquatic invertebrates: no data available
  • Toxicity to algae: no data available
  • Toxicity to microorganisms: no data available

12.2 Persistence and degradability

no data available

12.3 Bioaccumulative potential

no data available

12.4 Mobility in soil

no data available

12.5 Other adverse effects

no data available

13.Disposal considerations

13.1 Disposal methods

Product

The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems.

Contaminated packaging

Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. Controlled incineration with flue gas scrubbing is possible for combustible packaging materials.

14.Transport information

14.1 UN Number

ADR/RID: Not dangerous goods. IMDG: Not dangerous goods. IATA: Not dangerous goods.

14.2 UN Proper Shipping Name

ADR/RID: unknown
IMDG: unknown
IATA: unknown

14.3 Transport hazard class(es)

ADR/RID: Not dangerous goods. IMDG: Not dangerous goods. IATA: Not dangerous goods.

14.4 Packing group, if applicable

ADR/RID: Not dangerous goods. IMDG: Not dangerous goods. IATA: Not dangerous goods.

14.5 Environmental hazards

ADR/RID: no IMDG: no IATA: no

14.6 Special precautions for user

no data available

14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code

no data available

15.Regulatory information

15.1 Safety, health and environmental regulations specific for the product in question

Chemical name Common names and synonyms CAS number EC number
poly(acrylic acid) macromolecule poly(acrylic acid) macromolecule 9003-01-4 none
European Inventory of Existing Commercial Chemical Substances (EINECS) Not Listed.
EC Inventory Not Listed.
United States Toxic Substances Control Act (TSCA) Inventory Listed.
China Catalog of Hazardous chemicals 2015 Not Listed.
New Zealand Inventory of Chemicals (NZIoC) Listed.
Philippines Inventory of Chemicals and Chemical Substances (PICCS) Listed.
Vietnam National Chemical Inventory Listed.
Chinese Chemical Inventory of Existing Chemical Substances (China IECSC) Listed.

16.Other information

Information on revision

Creation Date Aug 17, 2017
Revision Date Aug 17, 2017

Abbreviations and acronyms

  • CAS: Chemical Abstracts Service
  • ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
  • RID: Regulation concerning the International Carriage of Dangerous Goods by Rail
  • IMDG: International Maritime Dangerous Goods
  • IATA: International Air Transportation Association
  • TWA: Time Weighted Average
  • STEL: Short term exposure limit
  • LC50: Lethal Concentration 50%
  • LD50: Lethal Dose 50%
  • EC50: Effective Concentration 50%

References

  • IPCS - The International Chemical Safety Cards (ICSC), website: http://www.ilo.org/dyn/icsc/showcard.home
  • HSDB - Hazardous Substances Data Bank, website: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm
  • IARC - International Agency for Research on Cancer, website: http://www.iarc.fr/
  • eChemPortal - The Global Portal to Information on Chemical Substances by OECD, website: http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en
  • CAMEO Chemicals, website: http://cameochemicals.noaa.gov/search/simple
  • ChemIDplus, website: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp
  • ERG - Emergency Response Guidebook by U.S. Department of Transportation, website: http://www.phmsa.dot.gov/hazmat/library/erg
  • Germany GESTIS-database on hazard substance, website: http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp
  • ECHA - European Chemicals Agency, website: https://echa.europa.eu/

Disclaimer: The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. We as supplier shall not be held liable for any damage resulting from handling or from contact with the above product.

Computational chemical data

Molecular Weight:72.06266 [g/mol]
Molecular Formula:C3H4O2
XLogP3:0.3
H-Bond Donor:1
H-Bond Acceptor:2
Rotatable Bond Count:1
Exact Mass:72.021129
MonoIsotopic Mass:72.021129
Topological Polar Surface Area:37.3
Heavy Atom Count:5
Formal Charge:0
Complexity:55.9
Isotope Atom Count:0
Defined Atom Stereocenter Count:0
Undefined Atom Stereocenter Count:0
Defined Bond Stereocenter Count:0
Undefined Bond Stereocenter Count:0
Covalently-Bonded Unit Count:1
Feature 3D Acceptor Count:2
Feature 3D Anion Count:1
Feature 3D Hydrophobe Count:1
Effective Rotor Count:1
Conformer Sampling RMSD:0.4
CID Conformer Count:1