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Home> Hot Product Listed M   > Myclobutanil (.alpha.-Butyl-.alpha.-(4-chlorophenyl)-1H- 1,2,4-triazole-1-propanenitrile)

Myclobutanil (.alpha.-Butyl-.alpha.-(4-chlorophenyl)-1H- 1,2,4-triazole-1-propanenitrile)

CAS No.:88671-89-0
EINECS(EC#):410-400-0
Molecular Weight:288.77528
Molecular Formula:C15H17ClN4 (Products with the same molecular formula)
MOL File:88671-89-0.mol
Names and Identifiers
Synonyms

Nova (pesticide)1H-1,2,4-Triazole-1-propanenitrile,R-butyl- R-(4-chlorophenyl)-SysthaneNu-Flow MSysthane 6 FloMyclobutanil (.alpha.-Butyl-.alpha.-(4-chlorophenyl)-1H- 1,2,4-triazole-1-propanenitrile)NOVA WNOVARH 3866Rallyα-BUTYL-α(4-CHLOROPHENYL)-1H-1,2,4-THIAZOLE-1-PROPANENITRILERH-53,866

Inchi
InChI=1S/C15H17ClN4/c1-2-3-8-15(9-17,10-20-12-18-11-19-20)13-4-6-14(16)7-5-13/h4-7,11-12H,2-3,8,10H2,1H3
InChkey
HZJKXKUJVSEEFU-UHFFFAOYSA-N
Canonical Smiles
CCCCC(CN1C=NC=N1)(C#N)C2=CC=C(C=C2)Cl
Properties
Appearance
Pale yellow solid
Density
1.16 g/cm3
Melting Point
63-68℃
Boiling Point
202-208℃
Refractive Index
1.588
Flash Point
235.2 °C
Water
142 mg/L (25℃)
Solubilities
142 mg/L (25 oC) in water,Soluble in common organic solvents, e.g. ketones, esters, alcohols and aromatic hydrocarbons, all 50-100 g/l. Insoluble in aliatic hydrocarbons.
Color/Form
Pale yellow solid.
Light yellow crystals
Stability
Stable under normal storage conditions. Aqueous solutions decompose on exposure to light.
Storage temp
0-6°C
Safety and Handling
Hazard Codes
Xn
Risk Statements
R22;R36;R51/53;R63
Safety Statements
S36/37;S46;S61
Safety

Moterately toxic by ingestion, inhalation, and skin contact. Experimental reproductive effects. When heated to decomposition emits toxic fumes of NOx, SOx, Cl?.
The Hazard Codes of Myclobutanil (CAS NO.88671-89-0): ?Xn;? N
The Risk Statements information of Myclobutanil (CAS NO.88671-89-0):
22:? Harmful if swallowed?
36:? Irritating to the eyes?
63:? Possible risk of harm to the unborn child?
51/53:? Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment?
The Safety Statements information of Myclobutanil (CAS NO.88671-89-0):
46:? If swallowed, seek medical advice immediately and show this container or label?
61:? Avoid release to the environment. Refer to special instructions safety data sheet?
36/37:? Wear suitable protective clothing and gloves?
RIDADR: UN 3077
RTECS: XZ5257000

Transport
UN 3077
Formulations/Preparations
ANDERSONS GOLF PRODUCTS GOLDEN EAGLE FUNGICIDE Active Ingredient 1.00% myclobutanil; FERTILIZER PLUS FUNGICIDE XI Active Ingredient 1.00% myclobutanil
CHEMSICO CONCENTRATE Active Ingredients 1.250% Permethrin, mixed cis,trans and 0.78% Myclobutanil; CHEMSICO RTU MP Active Ingredients 0.020% Permethrin, mixed cis,trans and 0.012% Myclobutanil; CHEMSICO AEROSOL MP Active Ingredients 0.020% Permethrin, mixed cis,trans and 0.0120% Myclobutanil; CHEMSICO FUNGICIDE M Active Ingredient 1.550% Myclobutanil; CHEMSICO AEROSOL M Active Ingredient 0.012% Myclobutanil; CHEMSICO RTU M Active Ingredient 0.012% Myclobutanil; CHEMSICO FUNGICIDE CONCENTRATE M6 Active Ingredient 6.00% Myclobutanil; CHEMSICO FUNGICIDE CONCENTRATE 3000 Active Ingredient 2.000% Myclobutanil
MYCLOBUTANIL 40 WP AG Active Ingredient 40.0% Myclobutanil; MYCLOBUTANIL TGAI Active Ingredient 98.0% Myclobutanil; MYCOBUTANIL 40W T&O Active Ingredient 40.0% Myclobutanil; MYCLOBUTANL 20EW AG Active Ingredient 19.7% Myclobutanil; MYCLOBUTANIL 20EW T&O Active Ingredient 19.7% Myclobutanil
RH-3866 TECHNICAL Active Ingredient 95.5% Myclobutanil; RALLY 60 DF FUNGICIDE Active Ingredient 60.0% Myclobutanil; SYSTHANE 40 WP AGRICULTURAL FUNGICIDE Active Ingredient 40.0% Myclobutanil; RALLY 40W AGRICULTURAL FUNGICIDE IN-WATER-SOLUBLE POUCHES Active Ingredient 40.0% Myclobutanil; NOVA 40W AGRICULTURAL FUNGICIDE IN WATER SOLUBLE POUCHES Active Ingredient 40.0% Myclobutanil; NU-FLOW M SEED TREATMENT FUNGICIDE Active Ingredient 25% Myclobutanil; EAGLE WSP FUNGICIDE Active Ingredient 40.0% Myclobutanil; RH-0611 Active Ingredients 60.0% Mancozeb and 2.25% Myclobutanil; SYSTHANE WSP ORNAMENTAL FUNGICIDE Active Ingredient 40.0% Myclobutanil; RH-144228 FUNGICIDE Active Ingredients 96.75% Sulfur and 0.50% Myclobutanil; EAGLE 0.39G SPECIALTY FUNGICIDE Active Ingredient 0.39% Myclobutanil; EAGLE 0.62G Active Ingredient 0.620% Myclobutanil; EAGLE 20EW Active Ingredient 19.7% Myclobutanil; NU-FLOW M-40 Active Ingredient 40.0% Myclobutanil; LAREDO EW Active Ingredient 19.7% Myclobutanil
Emulsifiable concentrate and wettable powder.
Other Preventative Measures
SRP: The scientific literature for the use of contact lenses in industry is conflicting. The benefit or detrimental effects of wearing contact lenses depend not only upon the substance, but also on factors including the form of the substance, characteristics and duration of the exposure, the uses of other eye protection equipment, and the hygiene of the lenses. However, there may be individual substances whose irritating or corrosive properties are such that the wearing of contact lenses would be harmful to the eye. In those specific cases, contact lenses should not be worn. In any event, the usual eye protection equipment should be worn even when contact lenses are in place. /Technical concentrates/
WARNING: Causes substantial but temporary eye injury. Do not get in eyes or on clothing. Wear protective eyewear (goggles, face shield, or safety glasses). Remove contaminated clothing and wash clothing before reuse. Harmful if swallowed. Wash thoroughly with soap and water after handling. /Chemsico Fungicide Concentrate M6/
Avoid contact with skin, eyes or clothing. Wear protective eyewear (goggles, face shield, or safety glasses). Remove contaminated clothing and wash clothing before reuse. Prolonged or frequently repeated skin contact may cause allergic reactions In some individuals. /RH-3866 Technical/
First Aid. If In Eyes: Hold eye open and rinse slowly and gently with water for 15 - 20 minutes. Remove contact lenses, If present, after the first 5 minutes, then continue rinsing eye. Call a Poison Control Center or doctor for treatment advice. If Swallowed: Call a Poison Control Center or doctor immediately for treatment advice. Have person sip a glass of water if able to swallow. Do not induce vomiting unless told to by a Poison Control Center or doctor. Do not give anything by mouth to an unconscious person. Have the product container or label with you when calling the Poison Control Center or doctor, or going for treatment. /Chemsico Fungicide Concentrate M6/
First Aid. If in eyes: Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Call a poison control center or doctor for treatment advice. If on skin or clothing: Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20 minutes. Call a poison control center or doctor for treatment advice. If swallowed: Call a poison control center or doctor immediately for treatment advice. Have a person sip a glass of water if able to swallow. Do not induce vomiting unless told to do so by a poison control center or doctor. Do not give anything by mouth to an unconscious person. If inhaled: Move person to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial respiration ... Call a poison control center or doctor for further treatment advice. /RH-3866 Technical/
Specification

??Myclobutanil ,?its cas register number is 88671-89-0. It also can be called 2-(4-Chlorophenyl)-2-(1H-1,2,4-triazol-1-
ylmethyl)hexanenitrile ; Nova (pesticide) ; Nu-Flow M ; Rally ; Systhane ; alpha-Butyl-alpha-(4-chlorophenyl)-1H-1,2,4-triazole-1-propanenitrile?.

Octanol/Water Partition Coefficient
log Kow = 2.94
Disposal Methods
SRP: The most favorable course of action is to use an alternative chemical product with less inherent propensity for occupational exposure or environmental contamination. Recycle any unused portion of the material for its approved use or return it to the manufacturer or supplier. Ultimate disposal of the chemical must consider: the material's impact on air quality; potential migration in soil or water; effects on animal, aquatic, and plant life; and conformance with environmental and public health regulations.
Do not discharge effluent containing this product into lakes, streams, ponds, estuaries, occans or other waters unless in accordance with the requirements of a National Pollutant Discharge Elimination System (NPDES) permit and the permitting authority has been notified in writing prior to dischape. Do not discharge effluent containing this product to sewer systems without previously notifying the local sewage treatment plant authority. For guidance contact your State Water Board or Regional Office of the EPA. /RH-3866 Technical/
Do not apply directly to water. Do not contaminate water when disposing of equipment washwaters. /Chemsico Fungicide Concentrate M6/
Do not contaminate water, food, or feed by ... disposal. ... Pesticide Disposal: Securely wrap original container in several layers of newspaper and discard in trash. Container DIsposal: Do not reuse container. Rinse thoroughly before discarding in trash. /Chemsico Fungicide Concentrate M6/
Reach Info
MSDS

Download/Modify | Technical supported by XiXisys.com. For US version, EU version (23 languages) and more, please refer to xixisys.com/en/sds/search

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 15, 2017

Revision Date: Aug 15, 2017

1.Identification

1.1 GHS Product identifier

Product name myclobutanil

1.2 Other means of identification

Product number -
Other names Systhane

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

Company WWW.GuideChem.COM
Address 8F, Block C, No.3 Building, Zijin Plaza, No.701, Gudun Road, Hangzhou, Zhejiang 310030, China
Telephone +86-571-89739798
Fax 86(21)54365166

1.5 Emergency phone number

Emergency phone number +86-571-89739798
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

2.Hazard identification

2.1 Classification of the substance or mixture

Acute toxicity - Oral, Category 4

Eye irritation, Category 2

Hazardous to the aquatic environment, long-term (Chronic) - Category Chronic 2

Reproductive toxicity, Category 2

2.2 GHS label elements, including precautionary statements

Pictogram(s)
Signal word

Warning

Hazard statement(s)

H302 Harmful if swallowed

H319 Causes serious eye irritation

H411 Toxic to aquatic life with long lasting effects

H361d

Precautionary statement(s)
Prevention

P264 Wash ... thoroughly after handling.

P270 Do not eat, drink or smoke when using this product.

P280 Wear protective gloves/protective clothing/eye protection/face protection.

P273 Avoid release to the environment.

P201 Obtain special instructions before use.

P202 Do not handle until all safety precautions have been read and understood.

Response

P301+P312 IF SWALLOWED: Call a POISON CENTER/doctor/\u2026if you feel unwell.

P330 Rinse mouth.

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

P337+P313 If eye irritation persists: Get medical advice/attention.

P391 Collect spillage.

P308+P313 IF exposed or concerned: Get medical advice/ attention.

Storage

P405 Store locked up.

Disposal

P501 Dispose of contents/container to ...

2.3 Other hazards which do not result in classification

none

3.Composition/information on ingredients

3.1 Substances

Chemical name Common names and synonyms CAS number EC number Concentration
myclobutanil myclobutanil 88671-89-0 none 100%

4.First-aid measures

4.1 Description of necessary first-aid measures

General advice

Consult a physician. Show this safety data sheet to the doctor in attendance.

If inhaled

If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.

In case of skin contact

Wash off with soap and plenty of water. Consult a physician.

In case of eye contact

Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.

If swallowed

Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.

4.2 Most important symptoms/effects, acute and delayed

no data available

4.3 Indication of immediate medical attention and special treatment needed, if necessary

no data available

5.Fire-fighting measures

5.1 Extinguishing media

Suitable extinguishing media

Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.

5.2 Specific hazards arising from the chemical

no data available

5.3 Special protective actions for fire-fighters

Wear self-contained breathing apparatus for firefighting if necessary.

6.Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

Use personal protective equipment. Avoid dust formation. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust. For personal protection see section 8.

6.2 Environmental precautions

Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided.

6.3 Methods and materials for containment and cleaning up

Pick up and arrange disposal. Sweep up and shovel. Keep in suitable, closed containers for disposal.

7.Handling and storage

7.1 Precautions for safe handling

Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Avoid exposure - obtain special instructions before use.Provide appropriate exhaust ventilation at places where dust is formed. For precautions see section 2.2.

7.2 Conditions for safe storage, including any incompatibilities

Store in cool place. Keep container tightly closed in a dry and well-ventilated place.

8.Exposure controls/personal protection

8.1 Control parameters

Occupational Exposure limit values

no data available

Biological limit values

no data available

8.2 Appropriate engineering controls

Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday.

8.3 Individual protection measures, such as personal protective equipment (PPE)

Eye/face protection

Safety glasses with side-shields conforming to EN166. Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).

Skin protection

Wear impervious clothing. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique(without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it.

Respiratory protection

Wear dust mask when handling large quantities.

Thermal hazards

no data available

9.Physical and chemical properties

Physical state Pale yellow solid
Colour no data available
Odour no data available
Melting point/ freezing point 63-68\u00baC
Boiling point or initial boiling point and boiling range 202-208\u00baC
Flammability no data available
Lower and upper explosion limit / flammability limit no data available
Flash point 235.2\u00baC
Auto-ignition temperature no data available
Decomposition temperature no data available
pH no data available
Kinematic viscosity no data available
Solubility In water:142 mg/L (25 \u00baC)
Partition coefficient n-octanol/water (log value) no data available
Vapour pressure no data available
Density and/or relative density 1.16 g/cm3
Relative vapour density no data available
Particle characteristics no data available

10.Stability and reactivity

10.1 Reactivity

no data available

10.2 Chemical stability

Stable under recommended storage conditions.

10.3 Possibility of hazardous reactions

no data available

10.4 Conditions to avoid

no data available

10.5 Incompatible materials

no data available

10.6 Hazardous decomposition products

no data available

11.Toxicological information

Acute toxicity

  • Oral: no data available
  • Inhalation: no data available
  • Dermal: no data available

Skin corrosion/irritation

no data available

Serious eye damage/irritation

no data available

Respiratory or skin sensitization

no data available

Germ cell mutagenicity

no data available

Carcinogenicity

no data available

Reproductive toxicity

no data available

STOT-single exposure

no data available

STOT-repeated exposure

no data available

Aspiration hazard

no data available

12.Ecological information

12.1 Toxicity

  • Toxicity to fish: no data available
  • Toxicity to daphnia and other aquatic invertebrates: no data available
  • Toxicity to algae: no data available
  • Toxicity to microorganisms: no data available

12.2 Persistence and degradability

no data available

12.3 Bioaccumulative potential

no data available

12.4 Mobility in soil

no data available

12.5 Other adverse effects

no data available

13.Disposal considerations

13.1 Disposal methods

Product

The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems.

Contaminated packaging

Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. Controlled incineration with flue gas scrubbing is possible for combustible packaging materials.

14.Transport information

14.1 UN Number

ADR/RID: UN3077 IMDG: UN3077 IATA: UN3077

14.2 UN Proper Shipping Name

ADR/RID: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
IMDG: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
IATA: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.

14.3 Transport hazard class(es)

ADR/RID: unknown IMDG: unknown IATA: unknown

14.4 Packing group, if applicable

ADR/RID: unknown IMDG: unknown IATA: unknown

14.5 Environmental hazards

ADR/RID: yes IMDG: yes IATA: yes

14.6 Special precautions for user

no data available

14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code

no data available

15.Regulatory information

15.1 Safety, health and environmental regulations specific for the product in question

Chemical name Common names and synonyms CAS number EC number
myclobutanil myclobutanil 88671-89-0 none
European Inventory of Existing Commercial Chemical Substances (EINECS) Not Listed.
EC Inventory Not Listed.
United States Toxic Substances Control Act (TSCA) Inventory Not Listed.
China Catalog of Hazardous chemicals 2015 Not Listed.
New Zealand Inventory of Chemicals (NZIoC) Listed.
Philippines Inventory of Chemicals and Chemical Substances (PICCS) Not Listed.
Vietnam National Chemical Inventory Not Listed.
Chinese Chemical Inventory of Existing Chemical Substances (China IECSC) Listed.

16.Other information

Information on revision

Creation Date Aug 15, 2017
Revision Date Aug 15, 2017

Abbreviations and acronyms

  • CAS: Chemical Abstracts Service
  • ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
  • RID: Regulation concerning the International Carriage of Dangerous Goods by Rail
  • IMDG: International Maritime Dangerous Goods
  • IATA: International Air Transportation Association
  • TWA: Time Weighted Average
  • STEL: Short term exposure limit
  • LC50: Lethal Concentration 50%
  • LD50: Lethal Dose 50%
  • EC50: Effective Concentration 50%

References

  • IPCS - The International Chemical Safety Cards (ICSC), website: http://www.ilo.org/dyn/icsc/showcard.home
  • HSDB - Hazardous Substances Data Bank, website: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm
  • IARC - International Agency for Research on Cancer, website: http://www.iarc.fr/
  • eChemPortal - The Global Portal to Information on Chemical Substances by OECD, website: http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en
  • CAMEO Chemicals, website: http://cameochemicals.noaa.gov/search/simple
  • ChemIDplus, website: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp
  • ERG - Emergency Response Guidebook by U.S. Department of Transportation, website: http://www.phmsa.dot.gov/hazmat/library/erg
  • Germany GESTIS-database on hazard substance, website: http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp
  • ECHA - European Chemicals Agency, website: https://echa.europa.eu/

Disclaimer: The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. We as supplier shall not be held liable for any damage resulting from handling or from contact with the above product.

Computational chemical data

Molecular Weight:288.77528 [g/mol]
Molecular Formula:C15H17ClN4
XLogP3:2.9
H-Bond Donor:0
H-Bond Acceptor:1
Rotatable Bond Count:6
Exact Mass:288.114174
MonoIsotopic Mass:288.114174
Topological Polar Surface Area:54.5
Heavy Atom Count:20
Formal Charge:0
Complexity:345
Isotope Atom Count:0
Defined Atom Stereocenter Count:0
Undefined Atom Stereocenter Count:1
Defined Bond Stereocenter Count:0
Undefined Bond Stereocenter Count:0
Covalently-Bonded Unit Count:1
Feature 3D Acceptor Count:1
Feature 3D Cation Count:2
Feature 3D Hydrophobe Count:2
Feature 3D Ring Count:2
Effective Rotor Count:6
Conformer Sampling RMSD:0.8
CID Conformer Count:47

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