Tin(IV) sulfide Lewis Structure

Tin(IV) sulfide Lewis Structure: S₂Sn Lewis Structure, linear Geometry, sp Hybridization & Polarity

Tin(IV) sulfide Key Facts

The Tin(IV) sulfide Lewis structure is Sn–S double bond and Sn–S double bond; the central Sn has 2 electron domains (0 lone pairs), giving a linear electron-domain arrangement and a linear molecular geometry with a 180° bond angle. Sn is best described as sp-hybridized, and Tin(IV) sulfide is nonpolar because the bond dipoles cancel by molecular symmetry.

Figure 1: Lewis Structure of Tin(IV) sulfide (S₂Sn)

Chemical Formula	S₂Sn
CAS Number	1315-01-1
Total Valence Electrons	16
Lewis Structure	Sn–S double bond and Sn–S double bond
Electron-Domain Geometry	linear
Molecular Geometry	linear
Hybridization Model	sp (central Sn)
Bond Angle	180°
Polarity	Nonpolar molecule

PubChem (CID 15238661) and NIST list Tin(IV) sulfide as S ₂Sn with CAS 1315-01-1; molecular weight ≈ 182.8 g/mol. View CAS 1315-01-1 dictionary details on Guidechem →

Applications of Tin(IV) sulfide (CAS 1315-01-1)

Tin(IV) sulfide is encountered as a reagent, intermediate or specialty chemical in inorganic, organometallic and materials synthesis. Confirm grade, purity and supplier documentation (SDS) before specifying for a process.

Reagent / Intermediate Used in synthesis and formulation where the substance's reactivity is required.

Specialty Chemical Specified by grade for the intended process or research use.

Sourcing Verify purity, package and regional availability via the CAS identifier.

Procurement Note "Tin(IV) sulfide" is supplied in multiple commercial grades and package sizes. Specify purity, grade, moisture/impurity limits, package (cylinder, drum or bulk) and intended process, and use CAS 1315-01-1 as the primary identifier when screening suppliers; always confirm regional availability and safety documentation (SDS).

Step 1 - Valence Electrons & Central Atom

To draw the Tin(IV) sulfide Lewis structure we first count the total valence electrons. S₂Sn contains 2×6 (S) + 4 (Sn); the net charge of 0 gives a total of 16 valence electrons to place.

The central atom is Sn. It is the least electronegative atom capable of forming multiple bonds and is surrounded by the more electronegative terminal atom(s); hydrogen, when present, always occupies a terminal position. Electronegativity considerations place the electron density toward the terminal atom(s).

Valence-electron count

Total valence electrons = 2×6 (S) + 4 (Sn) = 16 electrons.

Step 2 - Lewis Structure & Electron Distribution

Place Sn at the center and connect each surrounding atom with a single bond, complete octets on the terminal atoms, and place any remaining electrons on the central atom. The resulting electron distribution is: Sn–S double bond and Sn–S double bond; no lone pairs on Sn.

Counting bonding and nonbonding electrons around Sn therefore satisfies the octet/expanded-octet requirement for the drawn structure.

This species is best represented by resonance structures; the π bonding is delocalized over the equivalent terminal atom(s), so all Sn–terminals bonds are equivalent in the resonance hybrid.

Sn=S Sn=S

Sn: 0 lone pairs, 2 bonding domains

2 bonding domains + 0 lone pairs = 2 electron domains

Octet Rule: Why Sn Has Eight Electrons Sn forms 2 bond(s) and retains 0 nonbonding electron(s), reaching an octet. No expanded octet is required for this second-row (or octet-satisfying) central atom.

Step 3 - VSEPR Theory & Geometry

VSEPR theory states that the 2 electron domains around Sn arrange to minimize mutual repulsion, giving an linear electron-domain geometry.

Because 0 of these domains are lone pair(s) — and lone pairs repel more strongly than bonding pairs — the observed molecular geometry is linear; the Sn bond angle is set to 180° rather than the ideal value for the electron-domain geometry.

Repulsion hierarchy

A useful VSEPR approximation is: lone pair–lone pair repulsion > lone pair–bonding pair repulsion > bonding pair–bonding pair repulsion. With 0 lone pair(s) on Sn, the lone-pair domains occupy positions that minimize overall repulsion while pushing the bonding domains (and therefore the bonded atoms) closer together.

Hybridization & Formal Charge

In the conventional localized-bond model, Sn uses sp hybrid orbitals to form the 2 equivalent electron-domain directions (2 bonding + 0 lone pair).

Formal-charge check

Formal charge on central Sn = V − N − ½B = 4 − 0 − ½×8 = 0. The preferred Lewis structure carries zero formal charge on the central atom (and on the terminals), so it is the dominant contributor.

Modeling Note Modeling Note: sp is a compact model for the 2 electron-domain directions around Sn; full quantum-chemical treatments use molecular orbitals.

Is Tin(IV) sulfide Polar or Nonpolar?

Tin(IV) sulfide is nonpolar. Although individual Sn–terminal bonds are polar when the atoms differ in electronegativity, the linear geometry makes their vector sum zero, so there is no net molecular dipole.

Expert Quote — Structural Chemistry Perspective

A common misconception is that polar bonds guarantee a polar molecule. Tin(IV) sulfide shows the opposite: identical bond dipoles arranged with linear symmetry cancel exactly, yielding a nonpolar species.

Interpretation consistent with standard VSEPR / molecular-geometry references.

Its nonpolar character governs solvation and intermolecular behavior; specify grade and handling when sourcing.

Structural Comparison Table

Species	Formula	Central Atom	Electron Domains	Molecular Geometry	Polarity
Tin(IV) sulfide	S₂Sn	Sn	2	linear	Nonpolar
Carbon dioxide	CO₂	C	2	linear	Nonpolar
Carbon monoxide	CO	C	2	linear (diatomic)	Polar
Carbon disulfide	CS₂	C	2	linear	Nonpolar

Practice question Starting from the 16 valence electrons of S₂Sn, draw the Lewis structure and confirm the central Sn atom is sp-hybridized with linear geometry. What happens to the bond angle if one terminal atom is replaced by a more electronegative substituent?

Looking for industrial bulk or specified-grade supplies of Tin(IV) sulfide (CAS 1315-01-1)? Browse Supplier on Guidechem →

FAQs

Is S₂Sn polar or nonpolar?

Tin(IV) sulfide is nonpolar. Its linear symmetry cancels the bond dipoles exactly.

What is the Lewis structure of Tin(IV) sulfide?

Sn–S double bond and Sn–S double bond; no lone pairs on Sn. It uses all 16 valence electrons and the preferred structure carries zero formal charge on the central atom.

What is the bond angle in Tin(IV) sulfide?

The Sn angle is about 180°. Lone-pair repulsion compresses the angle from the ideal linear value.

What is the hybridization of Sn in Tin(IV) sulfide?

The conventional model is sp. Tin(IV) sulfide has 2 electron domains around the central Sn.

What is the CAS number of Tin(IV) sulfide?

The CAS number is 1315-01-1. PubChem (CID 15238661) and NIST identify this with S₂Sn; use it to locate suppliers and database records.

References

PubChem CID 15238661, Tin(IV) sulfide. Molecular formula, CAS number, molecular weight and chemical identity.
NIST Chemistry WebBook, SRD 69, Tin(IV) sulfide. Formula, CAS Registry Number and thermochemical / spectroscopic data.
IUPAC Gold Book. Definitions for "lone pair", "VSEPR", "hybridization" and "formal charge".
Atkins, P. & de Paula, J., Physical Chemistry. VSEPR, molecular geometry and dipole moments.
Guidechem supplier & dictionary records. Commercial sourcing and CAS-linked property pages for Tin(IV) sulfide (CAS 1315-01-1).

Technical scope: Lewis structures, VSEPR and hybridization are model-based descriptions for chemical communication and structure prediction; actual molecular electronic structure is more accurately represented by molecular-orbital and quantum-chemical methods. Commercial grades vary substantially by supplier and intended use; CAS 1315-01-1 identifies the substance, not a universal purity specification.

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Tin(IV) sulfide Lewis Structure