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The Hexafluoroarsenate(V) ion Lewis structure is As–F single bond, As–F single bond, As–F single bond, As–F single bond, As–F single bond and As–F single bond; the central As has 6 electron domains (0 lone pairs), giving a octahedral electron-domain arrangement and a octahedral molecular geometry with a 90° bond angle. As is best described as sp3d2-hybridized, and Hexafluoroarsenate(V) ion is nonpolar because the bond dipoles cancel by molecular symmetry.
Figure 1: Lewis Structure of Hexafluoroarsenate(V) ion (AsF6)
| Chemical Formula | AsF6 |
| CAS Number | 17018-85-8 |
| Net Charge | -1 |
| Total Valence Electrons | 48 |
| Lewis Structure | As–F single bond, As–F single bond, As–F single bond, As–F single bond, As–F single bond and As–F single bond |
| Electron-Domain Geometry | octahedral |
| Molecular Geometry | octahedral |
| Hybridization Model | sp3d2 (central As) |
| Bond Angle | 90° |
| Polarity | Nonpolar molecule |
In aqueous and process chemistry, AsF6 exists as the anion Hexafluoroarsenate(V) ion ion. It is encountered as a counterion and a controlled source of As in salts, buffers, electrochemistry and analytical protocols, and as a reactant in syntheses that require a defined equivalent of As-containing material.
To draw the Hexafluoroarsenate(V) ion Lewis structure we first count the total valence electrons. AsF6 contains 5 (As) + 6×7 (F) − 1 (net anion); the net charge of -1 gives a total of 48 valence electrons to place.
The central atom is As. It is the least electronegative atom capable of forming multiple bonds and is surrounded by the more electronegative terminal atom(s); hydrogen, when present, always occupies a terminal position. Electronegativity considerations place the electron density toward the terminal atom(s).
Total valence electrons = 5 (As) + 6×7 (F) − 1 (net anion) = 48 electrons.
Place As at the center and connect each surrounding atom with a single bond, complete octets on the terminal atoms, and place any remaining electrons on the central atom. The resulting electron distribution is: As–F single bond, As–F single bond, As–F single bond, As–F single bond, As–F single bond and As–F single bond; no lone pairs on As.
Counting bonding and nonbonding electrons around As therefore satisfies the octet/expanded-octet requirement for the drawn structure.
VSEPR theory states that the 6 electron domains around As arrange to minimize mutual repulsion, giving an octahedral electron-domain geometry.
Because 0 of these domains are lone pair(s) — and lone pairs repel more strongly than bonding pairs — the observed molecular geometry is octahedral; the As bond angle is set to 90° rather than the ideal value for the electron-domain geometry.
A useful VSEPR approximation is: lone pair–lone pair repulsion > lone pair–bonding pair repulsion > bonding pair–bonding pair repulsion. With 0 lone pair(s) on As, the lone-pair domains occupy positions that minimize overall repulsion while pushing the bonding domains (and therefore the bonded atoms) closer together.
In the conventional localized-bond model, As uses sp3d2 hybrid orbitals to form the 6 equivalent electron-domain directions (6 bonding + 0 lone pair).
Formal charge on central As = V − N − ½B = 5 − 0 − ½×12 = -1. The nonzero formal charge is distributed by resonance / charge separation; the drawn structure is the lowest-energy contributor.
Hexafluoroarsenate(V) ion is nonpolar. Although individual As–terminal bonds are polar when the atoms differ in electronegativity, the octahedral geometry makes their vector sum zero, so there is no net molecular dipole.
A common misconception is that polar bonds guarantee a polar molecule. Hexafluoroarsenate(V) ion shows the opposite: identical bond dipoles arranged with octahedral symmetry cancel exactly, yielding a nonpolar species.
Interpretation consistent with standard VSEPR / molecular-geometry references.Its nonpolar character governs solvation and intermolecular behavior; specify grade and handling when sourcing.
| Species | Formula | Central Atom | Electron Domains | Molecular Geometry | Polarity |
|---|---|---|---|---|---|
| Hexafluoroarsenate(V) ion | AsF6 | As | 6 | octahedral | Nonpolar |
| Arsenic trifluoride | AsF3 | As | 4 | trigonal pyramidal | Polar |
Hexafluoroarsenate(V) ion is nonpolar. Its octahedral symmetry cancels the bond dipoles exactly.
As–F single bond, As–F single bond, As–F single bond, As–F single bond, As–F single bond and As–F single bond; no lone pairs on As. It uses all 48 valence electrons and the preferred structure carries a formal charge of -1 on the central atom.
The As angle is about 90°. Lone-pair repulsion compresses the angle from the ideal octahedral value.
The conventional model is sp3d2. Hexafluoroarsenate(V) ion has 6 electron domains around the central As.
The CAS number is 17018-85-8. PubChem and NIST identify this with AsF6; use it to locate suppliers and database records.
Technical scope: Lewis structures, VSEPR and hybridization are model-based descriptions for chemical communication and structure prediction; actual molecular electronic structure is more accurately represented by molecular-orbital and quantum-chemical methods. Commercial grades vary substantially by supplier and intended use; CAS 17018-85-8 identifies the substance, not a universal purity specification.
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