Chlorine atom Lewis Structure

Chlorine atom Lewis Structure: Cl Lewis Structure, see text Geometry, sp3 Hybridization & Polarity

Chlorine atom Key Facts

The Chlorine atom Lewis structure is central Cl bonded; the central Cl has 4 electron domains (3 lone pairs), giving a tetrahedral electron-domain arrangement and a see text molecular geometry with a — bond angle. Cl is best described as sp3-hybridized, and Chlorine atom is polar because the see text shape (and/or unequal terminal atoms) prevents cancellation of the bond dipoles.

Figure 1: Lewis Structure of Chlorine atom (Cl)

Chemical Formula	Cl
CAS Number	22537-15-1
Total Valence Electrons	7
Lewis Structure	central Cl bonded
Electron-Domain Geometry	tetrahedral
Molecular Geometry	see text
Hybridization Model	sp3 (central Cl)
Bond Angle	—
Polarity	Polar molecule

PubChem (CID 5360523) and NIST list Chlorine atom as Cl with CAS 22537-15-1; molecular weight ≈ 35.45 g/mol. View CAS 22537-15-1 dictionary details on Guidechem →

Applications of Chlorine atom (CAS 22537-15-1)

This organic compound is used as a solvent, intermediate or specialty reagent in fine-chemical, pharmaceutical and materials synthesis; specify grade and impurity profile when sourcing.

Solvent / Reagent Medium for reactions, extraction or formulation.

Intermediate Building block for downstream derivatives.

Specialty Use Targeted role in pharma/fragrance/materials.

Procurement Note "Chlorine atom" is supplied in multiple commercial grades and package sizes. Specify purity, grade, moisture/impurity limits, package (cylinder, drum or bulk) and intended process, and use CAS 22537-15-1 as the primary identifier when screening suppliers; always confirm regional availability and safety documentation (SDS).

Step 1 - Valence Electrons & Central Atom

To draw the Chlorine atom Lewis structure we first count the total valence electrons. Cl contains 7 (Cl); the net charge of 0 gives a total of 7 valence electrons to place.

The central atom is Cl. It is the least electronegative atom capable of forming multiple bonds and is surrounded by the more electronegative terminal atom(s); hydrogen, when present, always occupies a terminal position. Electronegativity considerations place the electron density toward the terminal atom(s).

Valence-electron count

Total valence electrons = 7 (Cl) = 7 electrons.

Step 2 - Lewis Structure & Electron Distribution

Place Cl at the center and connect each surrounding atom with a single bond, complete octets on the terminal atoms, and place any remaining electrons on the central atom. The resulting electron distribution is: central Cl bonded; 3 lone pairs on Cl and one unpaired electron on Cl.

Counting bonding and nonbonding electrons around Cl therefore satisfies the octet/expanded-octet requirement for the drawn structure.

Cl: 3 lone pairs, 0 bonding domains

0 bonding domains + 3 lone pairs = 4 electron domains

Octet Rule: Why Cl Has Eight Electrons Cl forms 0 bond(s) and retains 6 nonbonding electron(s), reaching an octet. No expanded octet is required for this second-row (or octet-satisfying) central atom.

Step 3 - VSEPR Theory & Geometry

VSEPR theory states that the 4 electron domains around Cl arrange to minimize mutual repulsion, giving an tetrahedral electron-domain geometry.

Because 3 of these domains are lone pair(s) — and lone pairs repel more strongly than bonding pairs — the observed molecular geometry is see text; the Cl bond angle is set to — rather than the ideal value for the electron-domain geometry.

Repulsion hierarchy

A useful VSEPR approximation is: lone pair–lone pair repulsion > lone pair–bonding pair repulsion > bonding pair–bonding pair repulsion. With 3 lone pair(s) on Cl, the lone-pair domains occupy positions that minimize overall repulsion while pushing the bonding domains (and therefore the bonded atoms) closer together.

Hybridization & Formal Charge

In the conventional localized-bond model, Cl uses sp3 hybrid orbitals to form the 4 equivalent electron-domain directions (0 bonding + 3 lone pair).

Formal-charge check

Formal charge on central Cl = V − N − ½B = 7 − 6 − ½×0 = 1. The nonzero formal charge is distributed by resonance / charge separation; the drawn structure is the lowest-energy contributor.

Modeling Note Modeling Note: sp3 is a compact model for the 4 electron-domain directions around Cl; full quantum-chemical treatments use molecular orbitals.

Is Chlorine atom Polar or Nonpolar?

Chlorine atom is polar. The see text shape prevents cancellation of the bond dipoles. The bond dipoles do not cancel, leaving a net molecular dipole, which strongly influences solvation behavior and intermolecular interactions.

Expert Quote — Structural Chemistry Perspective

The decisive structural fact is not simply that the individual bonds are polar; it is whether molecular symmetry allows their vector sum to vanish. In Chlorine atom the see text arrangement prevents cancellation, so a permanent dipole remains.

Interpretation consistent with standard VSEPR / molecular-geometry references.

This polarity profile underpins its behavior as a solvent, reactant or process intermediate; when sourcing, specify grade and container compatibility.

Structural Comparison Table

Species	Formula	Central Atom	Electron Domains	Molecular Geometry	Polarity
Chlorine atom	Cl	Cl	4	see text	Polar
Hydrogen chloride	HCl	Cl	4	linear (diatomic)	Polar
Chlorine	Cl₂	Cl	4	linear (diatomic)	Nonpolar
Chlorine trifluoride	ClF₃	Cl	5	T-shaped	Polar
Chlorine pentafluoride	ClF₅	Cl	6	square pyramidal	Polar
Chlorate	ClO₃	Cl	4	trigonal pyramidal	Polar

Practice question Starting from the 7 valence electrons of Cl, draw the Lewis structure and confirm the central Cl atom is sp3-hybridized with see text geometry. What happens to the bond angle if one terminal atom is replaced by a more electronegative substituent?

Looking for industrial bulk or specified-grade supplies of Chlorine atom (CAS 22537-15-1)? Browse Supplier on Guidechem →

FAQs

Is Cl polar or nonpolar?

Chlorine atom is polar. Its see text geometry (and/or unequal terminal atoms) stops the bond dipoles from cancelling.

What is the Lewis structure of Chlorine atom?

central Cl bonded; 3 lone pairs on Cl and one unpaired electron on Cl. It uses all 7 valence electrons and the preferred structure carries a formal charge of 1 on the central atom.

What is the bond angle in Chlorine atom?

The Cl angle is about —. Lone-pair repulsion compresses the angle from the ideal tetrahedral value.

What is the hybridization of Cl in Chlorine atom?

The conventional model is sp3. Chlorine atom has 4 electron domains around the central Cl.

What is the CAS number of Chlorine atom?

The CAS number is 22537-15-1. PubChem (CID 5360523) and NIST identify this with Cl; use it to locate suppliers and database records.

References

PubChem CID 5360523, Chlorine atom. Molecular formula, CAS number, molecular weight and chemical identity.
NIST Chemistry WebBook, SRD 69, Chlorine atom. Formula, CAS Registry Number and thermochemical / spectroscopic data.
IUPAC Gold Book. Definitions for "lone pair", "VSEPR", "hybridization" and "formal charge".
Atkins, P. & de Paula, J., Physical Chemistry. VSEPR, molecular geometry and dipole moments.
Guidechem supplier & dictionary records. Commercial sourcing and CAS-linked property pages for Chlorine atom (CAS 22537-15-1).

Technical scope: Lewis structures, VSEPR and hybridization are model-based descriptions for chemical communication and structure prediction; actual molecular electronic structure is more accurately represented by molecular-orbital and quantum-chemical methods. Commercial grades vary substantially by supplier and intended use; CAS 22537-15-1 identifies the substance, not a universal purity specification.

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Chlorine atom Lewis Structure