Guideview >  Articles >  Property  > Vitamin C (Ascorbic acid) Lewis Structure

Vitamin C (Ascorbic acid) Lewis Structure

Vitamin C (Ascorbic acid) Lewis structure (C6H8O6). C–C single bond, C–O single bond and 2 C–H single bond. It shows a tetrahedral shape, sp3 hybridization on C, 109.5° bond angles. Includes a comparison table and FAQs. Ransom3 MIN READSeptember 30, 2026

Vitamin C (Ascorbic acid) Lewis Structure: C6H8O6 Lewis Structure, tetrahedral Geometry, sp3 Hybridization & Polarity

Vitamin C (Ascorbic acid) Lewis structure Cover

Vitamin C (Ascorbic acid) Key Facts

The Vitamin C (Ascorbic acid) Lewis structure is C–C single bond, C–O single bond and 2 C–H single bond; the central C has 4 electron domains (0 lone pairs), giving a tetrahedral electron-domain arrangement and a tetrahedral molecular geometry with a 109.5° bond angle. C is best described as sp3-hybridized, and Vitamin C (Ascorbic acid) is polar because the tetrahedral shape (and/or unequal terminal atoms) prevents cancellation of the bond dipoles.

Vitamin C (Ascorbic acid) Lewis Structure Figure 1: Lewis Structure of Vitamin C (Ascorbic acid) (C6H8O6)
Chemical Formula C6H8O6
CAS Number 50-81-7
Total Valence Electrons 68
Lewis Structure C–C single bond, C–O single bond and 2 C–H single bond
Electron-Domain Geometry tetrahedral
Molecular Geometry tetrahedral
Hybridization Model sp3 (central C)
Bond Angle 109.5°
Polarity Polar molecule
PubChem (CID 54670067) and NIST list Vitamin C (Ascorbic acid) as C 6H 8O 6 with CAS 50-81-7; molecular weight ≈ 176.12 g/mol. View CAS 50-81-7 dictionary details on Guidechem →

Applications of Vitamin C (Ascorbic acid) (CAS 50-81-7)

Carboxylic acids and esters are flavors, fragrances, polymers (PET, polyesters, alkyds) and solvents/intermediates; acetate and phthalate esters are plasticizers, and acids are precursors to salts, amides and anhydrides.

Polymers & Resins PET, polyesters and alkyd coatings from acid/ester chemistry.
Solvents & Plasticizers Esters as solvents; phthalates/acetates as flexibilizers.
Flavor & Fine Chem Esters in flavors/fragrances and active-ingredient synthesis.
Procurement Note "Vitamin C (Ascorbic acid)" is supplied in multiple commercial grades and package sizes. Specify purity, grade, moisture/impurity limits, package (cylinder, drum or bulk) and intended process, and use CAS 50-81-7 as the primary identifier when screening suppliers; always confirm regional availability and safety documentation (SDS).

Step 1 - Valence Electrons & Central Atom

To draw the Vitamin C (Ascorbic acid) Lewis structure we first count the total valence electrons. C6H8O6 contains 6×4 (C) + 8×1 (H) + 6×6 (O); the net charge of 0 gives a total of 68 valence electrons to place.

The central atom is C. It is the least electronegative atom capable of forming multiple bonds and is surrounded by the more electronegative terminal atom(s); hydrogen, when present, always occupies a terminal position. Electronegativity considerations place the electron density toward the terminal atom(s).

Valence-electron count

Total valence electrons = 6×4 (C) + 8×1 (H) + 6×6 (O) = 68 electrons.

Step 2 - Lewis Structure & Electron Distribution

Place C at the center and connect each surrounding atom with a single bond, complete octets on the terminal atoms, and place any remaining electrons on the central atom. The resulting electron distribution is: C–C single bond, C–O single bond and 2 C–H single bond; no lone pairs on C.

Counting bonding and nonbonding electrons around C therefore satisfies the octet/expanded-octet requirement for the drawn structure.

C–C C–O C–H ×2
C: 0 lone pairs, 4 bonding domains
4 bonding domains + 0 lone pairs = 4 electron domains
Octet Rule: Why C Has Eight Electrons C forms 4 bond(s) and retains 0 nonbonding electron(s), reaching an octet. No expanded octet is required for this second-row (or octet-satisfying) central atom.

Step 3 - VSEPR Theory & Geometry

VSEPR theory states that the 4 electron domains around C arrange to minimize mutual repulsion, giving an tetrahedral electron-domain geometry.

Because 0 of these domains are lone pair(s) — and lone pairs repel more strongly than bonding pairs — the observed molecular geometry is tetrahedral; the C bond angle is set to 109.5° rather than the ideal value for the electron-domain geometry.

Repulsion hierarchy

A useful VSEPR approximation is: lone pair–lone pair repulsion > lone pair–bonding pair repulsion > bonding pair–bonding pair repulsion. With 0 lone pair(s) on C, the lone-pair domains occupy positions that minimize overall repulsion while pushing the bonding domains (and therefore the bonded atoms) closer together.

Hybridization & Formal Charge

In the conventional localized-bond model, C uses sp3 hybrid orbitals to form the 4 equivalent electron-domain directions (4 bonding + 0 lone pair).

Formal-charge check

Formal charge on central C = V − N − ½B = 4 − 0 − ½×8 = 2. The nonzero formal charge is distributed by resonance / charge separation; the drawn structure is the lowest-energy contributor.

Modeling Note Modeling Note: sp3 is a compact model for the 4 electron-domain directions around C; full quantum-chemical treatments use molecular orbitals.

Is Vitamin C (Ascorbic acid) Polar or Nonpolar?

Vitamin C (Ascorbic acid) is polar. The tetrahedral shape prevents cancellation of the bond dipoles. The bond dipoles do not cancel, leaving a net molecular dipole, which strongly influences solvation behavior and intermolecular interactions.

Expert Quote — Structural Chemistry Perspective

The decisive structural fact is not simply that the individual bonds are polar; it is whether molecular symmetry allows their vector sum to vanish. In Vitamin C (Ascorbic acid) the tetrahedral arrangement prevents cancellation, so a permanent dipole remains.

Interpretation consistent with standard VSEPR / molecular-geometry references.

This polarity profile underpins its behavior as a solvent, reactant or process intermediate; when sourcing, specify grade and container compatibility.

Structural Comparison Table

Species Formula Central Atom Electron Domains Molecular Geometry Polarity
Vitamin C (Ascorbic acid) C6H8O6 C 4 tetrahedral Polar
Carbon dioxide CO2 C 2 linear Nonpolar
Carbon monoxide CO C 2 linear (diatomic) Polar
Carbon disulfide CS2 C 2 linear Nonpolar
Methane CH4 C 4 tetrahedral Nonpolar
Ethane C2H6 C 4 tetrahedral Nonpolar
Practice question Starting from the 68 valence electrons of C6H8O6, draw the Lewis structure and confirm the central C atom is sp3-hybridized with tetrahedral geometry. What happens to the bond angle if one terminal atom is replaced by a more electronegative substituent?
Looking for industrial bulk or specified-grade supplies of Vitamin C (Ascorbic acid) (CAS 50-81-7)? Browse Supplier on Guidechem →

FAQs

Is C6H8O6 polar or nonpolar?

Vitamin C (Ascorbic acid) is polar. Its tetrahedral geometry (and/or unequal terminal atoms) stops the bond dipoles from cancelling.

What is the Lewis structure of Vitamin C (Ascorbic acid)?

C–C single bond, C–O single bond and 2 C–H single bond; no lone pairs on C. It uses all 68 valence electrons and the preferred structure carries a formal charge of 2 on the central atom.

What is the bond angle in Vitamin C (Ascorbic acid)?

The C angle is about 109.5°. Lone-pair repulsion compresses the angle from the ideal tetrahedral value.

What is the hybridization of C in Vitamin C (Ascorbic acid)?

The conventional model is sp3. Vitamin C (Ascorbic acid) has 4 electron domains around the central C.

What is the CAS number of Vitamin C (Ascorbic acid)?

The CAS number is 50-81-7. PubChem (CID 54670067) and NIST identify this with C6H8O6; use it to locate suppliers and database records.

References

  1. PubChem CID 54670067, Vitamin C (Ascorbic acid). Molecular formula, CAS number, molecular weight and chemical identity.
  2. NIST Chemistry WebBook, SRD 69, Vitamin C (Ascorbic acid). Formula, CAS Registry Number and thermochemical / spectroscopic data.
  3. IUPAC Gold Book. Definitions for "lone pair", "VSEPR", "hybridization" and "formal charge".
  4. Atkins, P. & de Paula, J., Physical Chemistry. VSEPR, molecular geometry and dipole moments.
  5. Guidechem supplier & dictionary records. Commercial sourcing and CAS-linked property pages for Vitamin C (Ascorbic acid) (CAS 50-81-7).

Technical scope: Lewis structures, VSEPR and hybridization are model-based descriptions for chemical communication and structure prediction; actual molecular electronic structure is more accurately represented by molecular-orbital and quantum-chemical methods. Commercial grades vary substantially by supplier and intended use; CAS 50-81-7 identifies the substance, not a universal purity specification.

Make Guideview Preferred Source on Google
Related News