China, Mexico, and the United States are the leading exporters of hydrogen fluoride, collectively accounting for the majority of global shipments in recent years; major importers include South Korea, Japan, Germany, and Belgium—key hubs for semiconductor and fluoropolymer manufacturing. Imports by South Korea and Japan have remained stable amid tightening environmental regulations and ongoing demand from high-value electronics sectors, while hydrogen fluoride prices have shown moderate upward pressure due to supply constraints and raw material cost fluctuations.
Hydrofluoric Acid (HF) Recent Commodity Market Intelligence Report
I. Price Dynamics
1. Domestic Market Prices
- According to the Business Network (Shengyishe) benchmark price, the HF benchmark price stood at RMB 15,466.67/ton on July 3 and remained stable at RMB 15,467/ton on July 5.
- On July 3, prices for anhydrous HF in the East China region declined to RMB 14,000–14,200/ton; in Shandong Province, the market price for anhydrous HF dropped as low as RMB 13,600–14,300/ton.
- On July 7, industrial-grade HF (HF-55) in Shandong Province was quoted at RMB 6,300/ton, while HF-40 was quoted at RMB 4,400/ton.
- As of July 31, the Business Network HF benchmark price decreased to RMB 10,800/ton, representing a 2.99% decline month-on-month from June.
2. Export Market Prices
- On July 3, the Business Network export benchmark price for HF was RMB 18,133.33/ton, reflecting a notable price premium over the domestic market.
3. Premium Product Prices
- Domestic electronic-grade HF prices show divergence: EL-grade (49% concentration) ranges from RMB 7,000/ton (low-end) to RMB 7,500/ton (high-end).
- G5-grade electronic HF (7N purity, for advanced semiconductor processes) long-term contract (LTC) prices surged by 38%–42% MoM, with an average increase of 40%; the January baseline was RMB 120,000/ton, rising to RMB 168,000/ton in June LTCs. Spot and ultra-high-purity/special-specification grades rose 55%–65% MoM; spot prices were further increased by 20%–30% in late June, with expectations of another 15%–20% rise in July.
II. Supply-Demand Dynamics
1. Supply Situation
- Domestic anhydrous HF capacity continues to expand, with projected total annual capacity reaching 4.1–4.2 million tons in 2026, up 3%–5% YoY.
- In July, the national hydrogen fluoride market operating rate stood at 50.6%, down 3.1 percentage points MoM, indicating reduced supply.
- Leading enterprises—such as Do-Fluoride Chemicals—maintain high utilization rates for their semiconductor-grade HF production capacity, currently at 40,000 tons/year.
2. Demand Situation
- Although the downstream refrigerant market is in its traditional peak season, weak end-market demand has dampened purchasing enthusiasm; buyers are adopting just-in-time procurement strategies for HF.
- Demand for HF from new-energy sectors is surging: global new-energy vehicle sales are expected to drive HF consumption exceeding 400,000 tons annually; photovoltaic applications require ~150,000 tons of electronic-grade HF annually.
- Semiconductor and advanced packaging industries are witnessing explosive growth in demand for high-purity HF, with annual growth rates of 10%–15%.
III. Cost Factors
1. Fluorspar Prices
- Fluorspar prices remain under upward pressure due to tightened mining quotas, yet prices have trended downward throughout July, weakening cost support for HF.
2. Sulfuric Acid Prices
- Sulfuric acid prices have surged significantly, becoming a primary driver of rising production costs for anhydrous HF—and providing strong cost support for electronic-grade HF pricing.
IV. Market Analysis & Outlook
1. Short-Term Outlook
- Amid raw material price volatility and sluggish downstream demand, the HF market faces near-term pricing pressure; prices are expected to continue declining in July.
- Electronic-grade HF remains relatively resilient, buoyed by robust demand from new-energy and semiconductor sectors—particularly G5-grade products, whose price increases may exceed expectations.
2. Medium-to-Long-Term Outlook
- With sustained demand growth from new-energy and semiconductor sectors, the overall HF price floor is expected to gradually shift upward. However, newly commissioned capacities and raw material cost fluctuations may moderate the pace of price increases.
- Supply side: Domestic HF capacity will continue expanding, but supply of high-end products remains tight. Accelerated capacity expansion and vertical integration among leading players will further elevate industry concentration.
- Demand side: New-energy and semiconductor sectors will become the primary growth drivers for HF demand. Traditional applications—e.g., refrigerants—offer limited growth potential, though quota-based management systems will help maintain relatively stable supply-demand dynamics.
V. Forecasts
1. Price Trends
- Short-term (July–September): Anhydrous HF prices are expected to continue falling due to soft demand; electronic-grade HF prices—supported by costs and driven by demand—will keep rising, especially for G5-grade products, where price gains may surpass expectations.
- Medium-to-long-term (Q4 2024 through 2027): As demand from new-energy and semiconductor sectors grows persistently, the HF market’s overall price center is expected to rise gradually. Yet price appreciation may decelerate due to new capacity releases and raw material cost volatility.
2. Market Structure
- The HF market will evolve toward increasing demand for premium products alongside intensifying competition in lower-tier segments. Enterprises must accelerate technological upgrades and product innovation to meet evolving market requirements.
3. Industry Trends
- Persistently high raw material costs and tightening environmental regulations will propel the HF industry toward greener, higher-value development pathways, further consolidating market share among top-tier players.
Hydrogen fluoride is a colorless, fuming liquid or gas with a sharp, pungent odor and high volatility; it has a boiling point of 19.5 °C and a melting point of –83.6 °C. It is an inorganic acid and one of the strongest known proton donors, though it exists as hydrogen-bonded oligomers in both liquid and aqueous phases. Industrially, hydrogen fluoride serves primarily as a key fluorinating agent and catalyst in organic and inorganic synthesis, notably in the production of fluorocarbons, fluoropolymers (e.g., polytetrafluoroethylene), and refrigerants. It is essential in manufacturing aluminum fluoride for aluminum smelting, uranium hexafluoride for nuclear fuel processing, and high-octane gasoline components via alkylation. Its principal application areas include fluorinated polymers, refrigerants, agrochemicals, pharmaceuticals, and specialty inorganic chemicals.
(1) Hydrofluoric acid is mainly used as the raw materials of fluorine compounds, also used in the manufacture of aluminum fluoride and cryolite. Moreover, it can be applied to semiconductor surface etching and used as alkylation catalyst.In the electronics industry, it can be used as a strong acid corrosion agent, being able to be used in conjunction with nitric acid, acetic acid, ammonia and hydrogen peroxide.(2) It can be used as analytical reagents, but also for the preparation of high purity fluoride.(3) It is the indispensable fluoride source for fluorine salts, fluorine refrigerants, fluorine plastics, fluorine rubber and fluorine medicine and pesticides.(4) It is the raw materials for the production of refrigerants, "Freon", fluorine-containing resins, organic fluoride and fluoride. In chemical production, it can be used as the catalysts of the organic synthesis such as alkylation, polymerization, condensation and isomerization. (5) It can also be used for corrosion of stratum upon the exploitation of certain deposits as well as the extraction of rare earth elements and radioactive elements. In the atomic energy industry and nuclear weapons production, it is the raw materials for the manufacture of uranium hexafluoride. It is also the raw materials for the production of rocket fuel and additives. Moreover, it can also be used for corrosion of glass and impregnation of wood.(6) It is used for the manufacture of organic or inorganic fluoride, such as fluorocarbons, sodium fluoride, aluminum fluoride, uranium hexafluoride and cryolite. It can also be applied to stainless steel, non-ferrous metal pickling, glass instrumentation scale, glassware and the engraving and lettering of mirror as well as glassware polishing, frosted bulb and general bulb treatment, silicon-removing purification of metal graphite, desanding of the metal casting, the removal of the graphite ash and the manufacturing of semiconductor (germanium, silicon) manufacturing. It can also be used for dye synthesis and used as the catalyst for other organic synthesis. It can also used for electroplating, reagents, fermentation, ceramic processing and the manufacturing of fluorine-containing resin and flame retardant.(7) It can be used for etching glass, pickling metal and production of inorganic fluoride products and chemical reagents.(8) It can be applied to the atomic energy industry and the production of fluorine and fluoride. It can also used as catalyst, fluorinating agent for the manufacturing of organic or inorganic fluoride. Moreover, it can be applied to the pickling of stainless steel and non-ferrous metal, the scrub and pickling of glassware as well as the processing of frosted bulb.
It appears as colorless fuming liquid. It is intensively exothermic when being dissolved in water and further become hydrofluoric acid.
This chemical is included in Basic Chemicals - Fluorochemicals. See more about what is Hydrogen fluoride and Hydrogen fluoride SDS information.
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